Correlation between morphological properties and ionic conductivity in an electrolyte based on poly(vinylidene fluoride) and poly (2-hydroxyethyl methacrylate)

Detalhes bibliográficos
Autor(a) principal: Silva, Livio Bruno Jacques da
Data de Publicação: 2014
Outros Autores: Patricio, Patrícia S. de O., Matencio, Tulio, Oréfice, Rodrigo L.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFLA
Texto Completo: http://repositorio.ufla.br/jspui/handle/1/38779
Resumo: Materials based on a mixture of poly(vinylidene fluoride) (PVDF), poly(2-hydroxyethyl methacrylate) (PHEMA) and LiClO4 were produced to evaluate their ionic behavior and morphological structure to determine if they can be used as an electrolyte in electrical devices. FTIR chemical analysis results indicated the presence of interactions between PVDF, PHEMA and LiClO4. MDSC results showed that the transition temperatures of the polymers shifted to higher temperatures for systems containing high concentrations of each polymer. SEM images indicated that there was some miscibility between the polymers especially for the 25 and 75 wt. % compositions. In terms of the electrical performance, the ionic conductivity level of the electrolyte could be controlled by changing the composition of the system.
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spelling Correlation between morphological properties and ionic conductivity in an electrolyte based on poly(vinylidene fluoride) and poly (2-hydroxyethyl methacrylate)BlendsDifferential scanning calorimeterElectrolytesMaterials based on a mixture of poly(vinylidene fluoride) (PVDF), poly(2-hydroxyethyl methacrylate) (PHEMA) and LiClO4 were produced to evaluate their ionic behavior and morphological structure to determine if they can be used as an electrolyte in electrical devices. FTIR chemical analysis results indicated the presence of interactions between PVDF, PHEMA and LiClO4. MDSC results showed that the transition temperatures of the polymers shifted to higher temperatures for systems containing high concentrations of each polymer. SEM images indicated that there was some miscibility between the polymers especially for the 25 and 75 wt. % compositions. In terms of the electrical performance, the ionic conductivity level of the electrolyte could be controlled by changing the composition of the system.ABM, ABC, ABPol2020-01-31T12:46:32Z2020-01-31T12:46:32Z2014info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfSILVA, L. B. J. da et al. Correlation between morphological properties and ionic conductivity in an electrolyte based on poly(vinylidene fluoride) and poly (2-hydroxyethyl methacrylate). Materials Research, São Carlos, v. 17, n. 1, p. 115-120, Jan./Feb. 2014.http://repositorio.ufla.br/jspui/handle/1/38779Materials Researchreponame:Repositório Institucional da UFLAinstname:Universidade Federal de Lavras (UFLA)instacron:UFLAAttribution-NonCommercial 4.0 Internationalhttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccessSilva, Livio Bruno Jacques daPatricio, Patrícia S. de O.Matencio, TulioOréfice, Rodrigo L.eng2023-05-02T19:05:25Zoai:localhost:1/38779Repositório InstitucionalPUBhttp://repositorio.ufla.br/oai/requestnivaldo@ufla.br || repositorio.biblioteca@ufla.bropendoar:2023-05-02T19:05:25Repositório Institucional da UFLA - Universidade Federal de Lavras (UFLA)false
dc.title.none.fl_str_mv Correlation between morphological properties and ionic conductivity in an electrolyte based on poly(vinylidene fluoride) and poly (2-hydroxyethyl methacrylate)
title Correlation between morphological properties and ionic conductivity in an electrolyte based on poly(vinylidene fluoride) and poly (2-hydroxyethyl methacrylate)
spellingShingle Correlation between morphological properties and ionic conductivity in an electrolyte based on poly(vinylidene fluoride) and poly (2-hydroxyethyl methacrylate)
Silva, Livio Bruno Jacques da
Blends
Differential scanning calorimeter
Electrolytes
title_short Correlation between morphological properties and ionic conductivity in an electrolyte based on poly(vinylidene fluoride) and poly (2-hydroxyethyl methacrylate)
title_full Correlation between morphological properties and ionic conductivity in an electrolyte based on poly(vinylidene fluoride) and poly (2-hydroxyethyl methacrylate)
title_fullStr Correlation between morphological properties and ionic conductivity in an electrolyte based on poly(vinylidene fluoride) and poly (2-hydroxyethyl methacrylate)
title_full_unstemmed Correlation between morphological properties and ionic conductivity in an electrolyte based on poly(vinylidene fluoride) and poly (2-hydroxyethyl methacrylate)
title_sort Correlation between morphological properties and ionic conductivity in an electrolyte based on poly(vinylidene fluoride) and poly (2-hydroxyethyl methacrylate)
author Silva, Livio Bruno Jacques da
author_facet Silva, Livio Bruno Jacques da
Patricio, Patrícia S. de O.
Matencio, Tulio
Oréfice, Rodrigo L.
author_role author
author2 Patricio, Patrícia S. de O.
Matencio, Tulio
Oréfice, Rodrigo L.
author2_role author
author
author
dc.contributor.author.fl_str_mv Silva, Livio Bruno Jacques da
Patricio, Patrícia S. de O.
Matencio, Tulio
Oréfice, Rodrigo L.
dc.subject.por.fl_str_mv Blends
Differential scanning calorimeter
Electrolytes
topic Blends
Differential scanning calorimeter
Electrolytes
description Materials based on a mixture of poly(vinylidene fluoride) (PVDF), poly(2-hydroxyethyl methacrylate) (PHEMA) and LiClO4 were produced to evaluate their ionic behavior and morphological structure to determine if they can be used as an electrolyte in electrical devices. FTIR chemical analysis results indicated the presence of interactions between PVDF, PHEMA and LiClO4. MDSC results showed that the transition temperatures of the polymers shifted to higher temperatures for systems containing high concentrations of each polymer. SEM images indicated that there was some miscibility between the polymers especially for the 25 and 75 wt. % compositions. In terms of the electrical performance, the ionic conductivity level of the electrolyte could be controlled by changing the composition of the system.
publishDate 2014
dc.date.none.fl_str_mv 2014
2020-01-31T12:46:32Z
2020-01-31T12:46:32Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv SILVA, L. B. J. da et al. Correlation between morphological properties and ionic conductivity in an electrolyte based on poly(vinylidene fluoride) and poly (2-hydroxyethyl methacrylate). Materials Research, São Carlos, v. 17, n. 1, p. 115-120, Jan./Feb. 2014.
http://repositorio.ufla.br/jspui/handle/1/38779
identifier_str_mv SILVA, L. B. J. da et al. Correlation between morphological properties and ionic conductivity in an electrolyte based on poly(vinylidene fluoride) and poly (2-hydroxyethyl methacrylate). Materials Research, São Carlos, v. 17, n. 1, p. 115-120, Jan./Feb. 2014.
url http://repositorio.ufla.br/jspui/handle/1/38779
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv Attribution-NonCommercial 4.0 International
http://creativecommons.org/licenses/by-nc/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Attribution-NonCommercial 4.0 International
http://creativecommons.org/licenses/by-nc/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv ABM, ABC, ABPol
publisher.none.fl_str_mv ABM, ABC, ABPol
dc.source.none.fl_str_mv Materials Research
reponame:Repositório Institucional da UFLA
instname:Universidade Federal de Lavras (UFLA)
instacron:UFLA
instname_str Universidade Federal de Lavras (UFLA)
instacron_str UFLA
institution UFLA
reponame_str Repositório Institucional da UFLA
collection Repositório Institucional da UFLA
repository.name.fl_str_mv Repositório Institucional da UFLA - Universidade Federal de Lavras (UFLA)
repository.mail.fl_str_mv nivaldo@ufla.br || repositorio.biblioteca@ufla.br
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