Synthesis and characterization of aliphatic polyesters from glycerol, by-product of biodiesel production, and adipic acid

Detalhes bibliográficos
Autor(a) principal: Brioude,Michel de Meireles
Data de Publicação: 2007
Outros Autores: Guimarães,Danilo Hansen, Fiúza,Raigenis da Paz, Prado,Luis Antônio Sanches de Almeida, Boaventura,Jaime Soares, José,Nadia Mamede
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Materials research (São Carlos. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392007000400003
Resumo: In the present work, polyesters were prepared from the polycondensation between glycerol and adipic acid using dibutyltin dilaurate as catalyst. Three glycerol: adipic acid molar ratio were used for the bulk polymerization namely: 2:2; 2:3 and 2:4. FTIR confirmed the esterification of glycerol by the acid for all the polymers. DSC and XRD indicated no crystallinity for all the polymers. The morphology of the materials are characterized by globular structure, which may suggest compositional fluctuations throughout the samples.
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spelling Synthesis and characterization of aliphatic polyesters from glycerol, by-product of biodiesel production, and adipic acidpolyesterglycerolbiodieselIn the present work, polyesters were prepared from the polycondensation between glycerol and adipic acid using dibutyltin dilaurate as catalyst. Three glycerol: adipic acid molar ratio were used for the bulk polymerization namely: 2:2; 2:3 and 2:4. FTIR confirmed the esterification of glycerol by the acid for all the polymers. DSC and XRD indicated no crystallinity for all the polymers. The morphology of the materials are characterized by globular structure, which may suggest compositional fluctuations throughout the samples.ABM, ABC, ABPol2007-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392007000400003Materials Research v.10 n.4 2007reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/S1516-14392007000400003info:eu-repo/semantics/openAccessBrioude,Michel de MeirelesGuimarães,Danilo HansenFiúza,Raigenis da PazPrado,Luis Antônio Sanches de AlmeidaBoaventura,Jaime SoaresJosé,Nadia Mamedeeng2008-02-07T00:00:00Zoai:scielo:S1516-14392007000400003Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2008-02-07T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false
dc.title.none.fl_str_mv Synthesis and characterization of aliphatic polyesters from glycerol, by-product of biodiesel production, and adipic acid
title Synthesis and characterization of aliphatic polyesters from glycerol, by-product of biodiesel production, and adipic acid
spellingShingle Synthesis and characterization of aliphatic polyesters from glycerol, by-product of biodiesel production, and adipic acid
Brioude,Michel de Meireles
polyester
glycerol
biodiesel
title_short Synthesis and characterization of aliphatic polyesters from glycerol, by-product of biodiesel production, and adipic acid
title_full Synthesis and characterization of aliphatic polyesters from glycerol, by-product of biodiesel production, and adipic acid
title_fullStr Synthesis and characterization of aliphatic polyesters from glycerol, by-product of biodiesel production, and adipic acid
title_full_unstemmed Synthesis and characterization of aliphatic polyesters from glycerol, by-product of biodiesel production, and adipic acid
title_sort Synthesis and characterization of aliphatic polyesters from glycerol, by-product of biodiesel production, and adipic acid
author Brioude,Michel de Meireles
author_facet Brioude,Michel de Meireles
Guimarães,Danilo Hansen
Fiúza,Raigenis da Paz
Prado,Luis Antônio Sanches de Almeida
Boaventura,Jaime Soares
José,Nadia Mamede
author_role author
author2 Guimarães,Danilo Hansen
Fiúza,Raigenis da Paz
Prado,Luis Antônio Sanches de Almeida
Boaventura,Jaime Soares
José,Nadia Mamede
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Brioude,Michel de Meireles
Guimarães,Danilo Hansen
Fiúza,Raigenis da Paz
Prado,Luis Antônio Sanches de Almeida
Boaventura,Jaime Soares
José,Nadia Mamede
dc.subject.por.fl_str_mv polyester
glycerol
biodiesel
topic polyester
glycerol
biodiesel
description In the present work, polyesters were prepared from the polycondensation between glycerol and adipic acid using dibutyltin dilaurate as catalyst. Three glycerol: adipic acid molar ratio were used for the bulk polymerization namely: 2:2; 2:3 and 2:4. FTIR confirmed the esterification of glycerol by the acid for all the polymers. DSC and XRD indicated no crystallinity for all the polymers. The morphology of the materials are characterized by globular structure, which may suggest compositional fluctuations throughout the samples.
publishDate 2007
dc.date.none.fl_str_mv 2007-12-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392007000400003
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392007000400003
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S1516-14392007000400003
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv ABM, ABC, ABPol
publisher.none.fl_str_mv ABM, ABC, ABPol
dc.source.none.fl_str_mv Materials Research v.10 n.4 2007
reponame:Materials research (São Carlos. Online)
instname:Universidade Federal de São Carlos (UFSCAR)
instacron:ABM ABC ABPOL
instname_str Universidade Federal de São Carlos (UFSCAR)
instacron_str ABM ABC ABPOL
institution ABM ABC ABPOL
reponame_str Materials research (São Carlos. Online)
collection Materials research (São Carlos. Online)
repository.name.fl_str_mv Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)
repository.mail.fl_str_mv dedz@power.ufscar.br
_version_ 1754212658830114816

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