Materiais SIO2 - TIO2 para a degradação fotocatalítica de Diuron

Detalhes bibliográficos
Autor(a) principal: Bernardes, Arthur Alaim
Data de Publicação: 2011
Outros Autores: Bulhosa, Maria Carolina Salum, Gonçalves, Fábio Ferreira, D'Oca, Marcelo Gonçalves Montes, Wolke, Silvana Inês, Santos, João Henrique Zimnoch dos
Tipo de documento: Artigo
Idioma: por
Título da fonte: Repositório Institucional da FURG (RI FURG)
Texto Completo: http://repositorio.furg.br/handle/1/1757
Resumo: SiO2-TiO2 materials prepared by sol-gel method were evaluated in the photocatalytic degradation of diuron. The materials were prepared with and without surfactant cetyltrimethylammonium chloride at different temperatures (25, 50 and 100 oC). The samples were characterized by N2 adsorptiondesorption measurements, scanning electron microscopy, X-ray diffraction, ultraviolet-visible diffuse reflectance spectroscopy and infrared diffuse reflectance spectroscopy. The results showed that the materials synthesized with the surfactant had higher surface areas and band-gap values similar to anatase. All materials were more active than the commercial catalyst P-25 and better performance was achieved using the surfactant in the material synthesis.
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spelling Bernardes, Arthur AlaimBulhosa, Maria Carolina SalumGonçalves, Fábio FerreiraD'Oca, Marcelo Gonçalves MontesWolke, Silvana InêsSantos, João Henrique Zimnoch dos2012-01-17T21:55:37Z2012-01-17T21:55:37Z2011BERNARDES, Arthur Alaím et al. Materiais SIO2 - TIO2 para a degradação fotocatalítica de Diuron. Química Nova, São Paulo, v. 34, n. 8, p.1343-1348, 2011. Disponível em: <www.scielo.br/pdf/qn/v34n8/09.pdf>. Acesso em: 05 jan. 2012.http://repositorio.furg.br/handle/1/1757SiO2-TiO2 materials prepared by sol-gel method were evaluated in the photocatalytic degradation of diuron. The materials were prepared with and without surfactant cetyltrimethylammonium chloride at different temperatures (25, 50 and 100 oC). The samples were characterized by N2 adsorptiondesorption measurements, scanning electron microscopy, X-ray diffraction, ultraviolet-visible diffuse reflectance spectroscopy and infrared diffuse reflectance spectroscopy. The results showed that the materials synthesized with the surfactant had higher surface areas and band-gap values similar to anatase. All materials were more active than the commercial catalyst P-25 and better performance was achieved using the surfactant in the material synthesis.porPhotocatalysisSol-gel methodDiuronMateriais SIO2 - TIO2 para a degradação fotocatalítica de DiuronSIO2-TIO2 materials for Diuron photocatalytic degradationinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da FURG (RI FURG)instname:Universidade Federal do Rio Grande (FURG)instacron:FURGORIGINAL01_Materiais_SIO2.pdf01_Materiais_SIO2.pdfapplication/pdf965846https://repositorio.furg.br/bitstream/1/1757/1/01_Materiais_SIO2.pdf2e9c358eb697f2504e6ae92aa78eb325MD51open accessLICENSElicense.txtlicense.txttext/plain; charset=utf-81724https://repositorio.furg.br/bitstream/1/1757/2/license.txt5b92b9704b4f13242d70e45ddef35a68MD52open access1/17572012-01-17 19:55:37.897open accessoai:repositorio.furg.br:1/1757w4kgbmVjZXNzw6FyaW8gY29uY29yZGFyIGNvbSBhIGxpY2Vuw6dhIGRlIGRpc3RyaWJ1acOnw6NvIG7Do28tZXhjbHVzaXZhLAphbnRlcyBxdWUgbyBkb2N1bWVudG8gcG9zc2EgYXBhcmVjZXIgbm8gUmVwb3NpdMOzcmlvLiBQb3IgZmF2b3IsIGxlaWEgYQpsaWNlbsOnYSBhdGVudGFtZW50ZS4gQ2FzbyBuZWNlc3NpdGUgZGUgYWxndW0gZXNjbGFyZWNpbWVudG8gZW50cmUgZW0KY29udGF0byBhdHJhdsOpcyBkZTogcmVwb3NpdG9yaW9AZnVyZy5iciBvdSAweHggNTMgMzIzMy02NzA2LgoKTElDRU7Dh0EgREUgRElTVFJJQlVJw4fDg08gTsODTy1FWENMVVNJVkEKCkFvIGFzc2luYXIgZSBlbnRyZWdhciBlc3RhIGxpY2Vuw6dhLCBvL2EgU3IuL1NyYS4gKGF1dG9yIG91IGRldGVudG9yIGRvcyBkaXJlaXRvcyBkZSBhdXRvcik6CgphKSBDb25jZWRlIMOgIFVuaXZlcnNpZGFkZSBGZWRlcmFsIGRlIFJpbyBHcmFuZGUgLSAgRlVSRyBvIGRpcmVpdG8gbsOjby1leGNsdXNpdm8gZGUgcmVwcm9kdXppciwgY29udmVydGVyIChjb21vIGRlZmluaWRvIGFiYWl4byksIGNvbXVuaWNhciBlL291IGRpc3RyaWJ1aXIgbyBkb2N1bWVudG8gZW50cmVndWUgKGluY2x1aW5kbyBvIHJlc3Vtby9hYnN0cmFjdCkgZW0KZm9ybWF0byBkaWdpdGFsIG91IGltcHJlc3NvIGUgZW0gcXVhbHF1ZXIgbWVpby4KCmIpIERlY2xhcmEgcXVlIG8gZG9jdW1lbnRvIGVudHJlZ3VlIMOpIHNldSB0cmFiYWxobyBvcmlnaW5hbCwgZSBxdWUKZGV0w6ltIG8gZGlyZWl0byBkZSBjb25jZWRlciBvcyBkaXJlaXRvcyBjb250aWRvcyBuZXN0YSBsaWNlbsOnYS4gRGVjbGFyYSB0YW1iw6ltIHF1ZSBhIGVudHJlZ2EgZG8gZG9jdW1lbnRvIG7Do28gaW5mcmluZ2UsIHRhbnRvIHF1YW50byBsaGUgw6kgcG9zc8OtdmVsIHNhYmVyLCBvcyBkaXJlaXRvcyBkZSBxdWFscXVlciBvdXRyYSBwZXNzb2Egb3UgZW50aWRhZGUuCgpjKSBTZSBvIGRvY3VtZW50byBlbnRyZWd1ZSBjb250w6ltIG1hdGVyaWFsIGRvIHF1YWwgbsOjbyBkZXTDqW0gb3MKZGlyZWl0b3MgZGUgYXV0b3IsIGRlY2xhcmEgcXVlIG9idGV2ZSBhdXRvcml6YcOnw6NvIGRvIGRldGVudG9yIGRvcwpkaXJlaXRvcyBkZSBhdXRvciBwYXJhIGNvbmNlZGVyIMOgIEZVUkcgb3MgZGlyZWl0b3MgcmVxdWVyaWRvcyBwb3IgZXN0YSBsaWNlbsOnYSwgZSBxdWUgZXNzZSBtYXRlcmlhbCBjdWpvcyBkaXJlaXRvcyBzw6NvIGRlIHRlcmNlaXJvcyBlc3TDoSBjbGFyYW1lbnRlIGlkZW50aWZpY2FkbyBlIHJlY29uaGVjaWRvIG5vIHRleHRvIG91IGNvbnRlw7pkbyBkbyBkb2N1bWVudG8gZW50cmVndWUuCgpTZSBvIGRvY3VtZW50byBlbnRyZWd1ZSDDqSBiYXNlYWRvIGVtIHRyYWJhbGhvIGZpbmFuY2lhZG8gb3UgYXBvaWFkbwpwb3Igb3V0cmEgaW5zdGl0dWnDp8OjbyBxdWUgbsOjbyBhIEZVUkcsIGRlY2xhcmEgcXVlIGN1bXByaXUgcXVhaXNxdWVyIG9icmlnYcOnw7VlcyBleGlnaWRhcyBwZWxvIHJlc3BlY3Rpdm8gY29udHJhdG8gb3UgYWNvcmRvLgoKQSBGVVJHIGlkZW50aWZpY2Fyw6EgY2xhcmFtZW50ZSBvKHMpIHNldSAocykgbm9tZSAocykgY29tbyBvIChzKSBhdXRvciAoZXMpIG91IGRldGVudG9yIChlcykgZG9zIGRpcmVpdG9zIGRvIGRvY3VtZW50byBlbnRyZWd1ZSwgZSBuw6NvIGZhcsOhIHF1YWxxdWVyIGFsdGVyYcOnw6NvLCBwYXJhIGFsw6ltIGRhcyBwZXJtaXRpZGFzIHBvciBlc3RhIGxpY2Vuw6dhLgo=Repositório InstitucionalPUBhttps://repositorio.furg.br/oai/request || http://200.19.254.174/oai/requestopendoar:2012-01-17T21:55:37Repositório Institucional da FURG (RI FURG) - Universidade Federal do Rio Grande (FURG)false
dc.title.pt_BR.fl_str_mv Materiais SIO2 - TIO2 para a degradação fotocatalítica de Diuron
dc.title.alternative.pt_BR.fl_str_mv SIO2-TIO2 materials for Diuron photocatalytic degradation
title Materiais SIO2 - TIO2 para a degradação fotocatalítica de Diuron
spellingShingle Materiais SIO2 - TIO2 para a degradação fotocatalítica de Diuron
Bernardes, Arthur Alaim
Photocatalysis
Sol-gel method
Diuron
title_short Materiais SIO2 - TIO2 para a degradação fotocatalítica de Diuron
title_full Materiais SIO2 - TIO2 para a degradação fotocatalítica de Diuron
title_fullStr Materiais SIO2 - TIO2 para a degradação fotocatalítica de Diuron
title_full_unstemmed Materiais SIO2 - TIO2 para a degradação fotocatalítica de Diuron
title_sort Materiais SIO2 - TIO2 para a degradação fotocatalítica de Diuron
author Bernardes, Arthur Alaim
author_facet Bernardes, Arthur Alaim
Bulhosa, Maria Carolina Salum
Gonçalves, Fábio Ferreira
D'Oca, Marcelo Gonçalves Montes
Wolke, Silvana Inês
Santos, João Henrique Zimnoch dos
author_role author
author2 Bulhosa, Maria Carolina Salum
Gonçalves, Fábio Ferreira
D'Oca, Marcelo Gonçalves Montes
Wolke, Silvana Inês
Santos, João Henrique Zimnoch dos
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Bernardes, Arthur Alaim
Bulhosa, Maria Carolina Salum
Gonçalves, Fábio Ferreira
D'Oca, Marcelo Gonçalves Montes
Wolke, Silvana Inês
Santos, João Henrique Zimnoch dos
dc.subject.por.fl_str_mv Photocatalysis
Sol-gel method
Diuron
topic Photocatalysis
Sol-gel method
Diuron
description SiO2-TiO2 materials prepared by sol-gel method were evaluated in the photocatalytic degradation of diuron. The materials were prepared with and without surfactant cetyltrimethylammonium chloride at different temperatures (25, 50 and 100 oC). The samples were characterized by N2 adsorptiondesorption measurements, scanning electron microscopy, X-ray diffraction, ultraviolet-visible diffuse reflectance spectroscopy and infrared diffuse reflectance spectroscopy. The results showed that the materials synthesized with the surfactant had higher surface areas and band-gap values similar to anatase. All materials were more active than the commercial catalyst P-25 and better performance was achieved using the surfactant in the material synthesis.
publishDate 2011
dc.date.issued.fl_str_mv 2011
dc.date.accessioned.fl_str_mv 2012-01-17T21:55:37Z
dc.date.available.fl_str_mv 2012-01-17T21:55:37Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
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dc.identifier.citation.fl_str_mv BERNARDES, Arthur Alaím et al. Materiais SIO2 - TIO2 para a degradação fotocatalítica de Diuron. Química Nova, São Paulo, v. 34, n. 8, p.1343-1348, 2011. Disponível em: <www.scielo.br/pdf/qn/v34n8/09.pdf>. Acesso em: 05 jan. 2012.
dc.identifier.uri.fl_str_mv http://repositorio.furg.br/handle/1/1757
identifier_str_mv BERNARDES, Arthur Alaím et al. Materiais SIO2 - TIO2 para a degradação fotocatalítica de Diuron. Química Nova, São Paulo, v. 34, n. 8, p.1343-1348, 2011. Disponível em: <www.scielo.br/pdf/qn/v34n8/09.pdf>. Acesso em: 05 jan. 2012.
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