Metal nanoparticles/ionic liquid/cellulose: polymeric membrane for hydrogenation reactions
Autor(a) principal: | |
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Data de Publicação: | 2014 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Polímeros (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282014000700002 |
Resumo: | Rhodium and platinum nanoparticles were supported in polymeric membranes with 10, 20 and 40 µm thickness. The polymeric membranes were prepared combining cellulose acetate and the ionic liquid (IL) 1-n-butyl-3-methylimidazolium bis(trifluoromethane sulfonyl)imide (BMI.(NTf)2. The presence of metal nanoparticles induced an increase in the polymeric membrane surface areas. The increase of the IL content resulted in an improvement of elasticity and decrease in tenacity and toughness, whereas the stress at break was not affected. The presence of IL probably causes an increase in the separation between the cellulose molecules that result in a higher flexibility and processability of the polymeric membrane. The CA/IL/M(0) combinations exhibit an excellent synergistic effect that enhances the activity and durability of the catalyst for the hydrogenation of cyclohexene. The CA/IL/M(0) polymeric membrane displays higher catalytic activity (up to 7.353 h-1) for the 20 mm of CA/IL/Pt(0) and stability than the nanoparticles dispersed only in the IL. |
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Metal nanoparticles/ionic liquid/cellulose: polymeric membrane for hydrogenation reactionsHydrogenation reactionsionic liquidnanoparticlespolymeric membraneRhodium and platinum nanoparticles were supported in polymeric membranes with 10, 20 and 40 µm thickness. The polymeric membranes were prepared combining cellulose acetate and the ionic liquid (IL) 1-n-butyl-3-methylimidazolium bis(trifluoromethane sulfonyl)imide (BMI.(NTf)2. The presence of metal nanoparticles induced an increase in the polymeric membrane surface areas. The increase of the IL content resulted in an improvement of elasticity and decrease in tenacity and toughness, whereas the stress at break was not affected. The presence of IL probably causes an increase in the separation between the cellulose molecules that result in a higher flexibility and processability of the polymeric membrane. The CA/IL/M(0) combinations exhibit an excellent synergistic effect that enhances the activity and durability of the catalyst for the hydrogenation of cyclohexene. The CA/IL/M(0) polymeric membrane displays higher catalytic activity (up to 7.353 h-1) for the 20 mm of CA/IL/Pt(0) and stability than the nanoparticles dispersed only in the IL.Associação Brasileira de Polímeros2014-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282014000700002Polímeros v.24 n.spe 2014reponame:Polímeros (São Carlos. Online)instname:Associação Brasileira de Polímeros (ABPol)instacron:ABPO10.4322/polimeros.2014.048info:eu-repo/semantics/openAccessGelesky,Marcos AlexandreScheeren,Carla Webereng2014-07-10T00:00:00Zoai:scielo:S0104-14282014000700002Revistahttp://www.scielo.br/pohttps://old.scielo.br/oai/scielo-oai.php||revista@abpol.org.br1678-51690104-1428opendoar:2014-07-10T00:00Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol)false |
dc.title.none.fl_str_mv |
Metal nanoparticles/ionic liquid/cellulose: polymeric membrane for hydrogenation reactions |
title |
Metal nanoparticles/ionic liquid/cellulose: polymeric membrane for hydrogenation reactions |
spellingShingle |
Metal nanoparticles/ionic liquid/cellulose: polymeric membrane for hydrogenation reactions Gelesky,Marcos Alexandre Hydrogenation reactions ionic liquid nanoparticles polymeric membrane |
title_short |
Metal nanoparticles/ionic liquid/cellulose: polymeric membrane for hydrogenation reactions |
title_full |
Metal nanoparticles/ionic liquid/cellulose: polymeric membrane for hydrogenation reactions |
title_fullStr |
Metal nanoparticles/ionic liquid/cellulose: polymeric membrane for hydrogenation reactions |
title_full_unstemmed |
Metal nanoparticles/ionic liquid/cellulose: polymeric membrane for hydrogenation reactions |
title_sort |
Metal nanoparticles/ionic liquid/cellulose: polymeric membrane for hydrogenation reactions |
author |
Gelesky,Marcos Alexandre |
author_facet |
Gelesky,Marcos Alexandre Scheeren,Carla Weber |
author_role |
author |
author2 |
Scheeren,Carla Weber |
author2_role |
author |
dc.contributor.author.fl_str_mv |
Gelesky,Marcos Alexandre Scheeren,Carla Weber |
dc.subject.por.fl_str_mv |
Hydrogenation reactions ionic liquid nanoparticles polymeric membrane |
topic |
Hydrogenation reactions ionic liquid nanoparticles polymeric membrane |
description |
Rhodium and platinum nanoparticles were supported in polymeric membranes with 10, 20 and 40 µm thickness. The polymeric membranes were prepared combining cellulose acetate and the ionic liquid (IL) 1-n-butyl-3-methylimidazolium bis(trifluoromethane sulfonyl)imide (BMI.(NTf)2. The presence of metal nanoparticles induced an increase in the polymeric membrane surface areas. The increase of the IL content resulted in an improvement of elasticity and decrease in tenacity and toughness, whereas the stress at break was not affected. The presence of IL probably causes an increase in the separation between the cellulose molecules that result in a higher flexibility and processability of the polymeric membrane. The CA/IL/M(0) combinations exhibit an excellent synergistic effect that enhances the activity and durability of the catalyst for the hydrogenation of cyclohexene. The CA/IL/M(0) polymeric membrane displays higher catalytic activity (up to 7.353 h-1) for the 20 mm of CA/IL/Pt(0) and stability than the nanoparticles dispersed only in the IL. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282014000700002 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282014000700002 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.4322/polimeros.2014.048 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Associação Brasileira de Polímeros |
publisher.none.fl_str_mv |
Associação Brasileira de Polímeros |
dc.source.none.fl_str_mv |
Polímeros v.24 n.spe 2014 reponame:Polímeros (São Carlos. Online) instname:Associação Brasileira de Polímeros (ABPol) instacron:ABPO |
instname_str |
Associação Brasileira de Polímeros (ABPol) |
instacron_str |
ABPO |
institution |
ABPO |
reponame_str |
Polímeros (São Carlos. Online) |
collection |
Polímeros (São Carlos. Online) |
repository.name.fl_str_mv |
Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol) |
repository.mail.fl_str_mv |
||revista@abpol.org.br |
_version_ |
1754212588666748928 |