Hydrotalcite and Boehmite coatings for increased protection of Aluminum clad spent nuclear fuel
Autor(a) principal: | |
---|---|
Data de Publicação: | 2014 |
Outros Autores: | , , , |
Tipo de documento: | Artigo de conferência |
Título da fonte: | Repositório Institucional do IPEN |
Texto Completo: | http://repositorio.ipen.br/handle/123456789/17701 |
Resumo: | It is essential to increase the corrosion resistance of Al-clad research reactor (RR) spent fuels during long term wet storage. Laboratory and field tests were carried out to evaluate the pitting corrosion resistance of rare earth containing conversion coatings on Al alloys, AA 1100 and AA 6061, used as cladding of RR fuel plates. These investigations were extended to include boehmite and hydrotalcite (HTC) coatings on Al alloy surfaces. Characterization of the coatings was done with the aid of SEM/FEG/EDS and x-ray diffraction analysis. The electrochemical behavior of uncoated and coated specimens was determined in 0.1 M NaCl. Field tests were carried out in which uncoated, lanthanide-based conversion coated, boehmite coated, cerium modified boehmite coated, HTC coated and cerium modified HTC coated Al alloy coupons were exposed to the IEA-R1 reactor spent fuel basin for varying periods and then their corrosion resistance evaluated. Most of the coatings increased the pitting corrosion resistance of the two alloys and among the coatings, the cerium modified HTC coating was the most efficient. |
id |
IPEN_eeebd726acfc52d43575cb651a49bbe6 |
---|---|
oai_identifier_str |
oai:repositorio.ipen.br:123456789/17701 |
network_acronym_str |
IPEN |
network_name_str |
Repositório Institucional do IPEN |
repository_id_str |
4510 |
spelling |
2014-11-17T18:36:42Z2014-11-18T18:54:10Z2015-04-01T22:23:47Z2014-11-17T18:36:42Z2014-11-18T18:54:10Z2015-04-01T22:23:47ZMay 14???18, 2012http://repositorio.ipen.br/handle/123456789/17701It is essential to increase the corrosion resistance of Al-clad research reactor (RR) spent fuels during long term wet storage. Laboratory and field tests were carried out to evaluate the pitting corrosion resistance of rare earth containing conversion coatings on Al alloys, AA 1100 and AA 6061, used as cladding of RR fuel plates. These investigations were extended to include boehmite and hydrotalcite (HTC) coatings on Al alloy surfaces. Characterization of the coatings was done with the aid of SEM/FEG/EDS and x-ray diffraction analysis. The electrochemical behavior of uncoated and coated specimens was determined in 0.1 M NaCl. Field tests were carried out in which uncoated, lanthanide-based conversion coated, boehmite coated, cerium modified boehmite coated, HTC coated and cerium modified HTC coated Al alloy coupons were exposed to the IEA-R1 reactor spent fuel basin for varying periods and then their corrosion resistance evaluated. Most of the coatings increased the pitting corrosion resistance of the two alloys and among the coatings, the cerium modified HTC coating was the most efficient.Made available in DSpace on 2014-11-17T18:36:42Z (GMT). No. of bitstreams: 0Made available in DSpace on 2014-11-18T18:54:10Z (GMT). No. of bitstreams: 1 18561.pdf: 287421 bytes, checksum: dd897ba4e35c7db569c1a81f91992395 (MD5)Made available in DSpace on 2015-04-01T22:23:47Z (GMT). No. of bitstreams: 1 18561.pdf: 287421 bytes, checksum: dd897ba4e35c7db569c1a81f91992395 (MD5)iear-1 reactoraluminiumcladdingcoatingspitting corrosioncorrosion resistancespent fuel storagewet storagerare earthsHydrotalcite and Boehmite coatings for increased protection of Aluminum clad spent nuclear fuelinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/conferenceObjectINTERCORRISalvador, BAFERNANDES, STELA M.C.CORREA, OLANDIR V.SOUZA, JOSE A. deRAMANATHAN, LALGUDI V.CONGRESSO BRASILEIRO DE CORROSAO, 32.; INTERNATIONAL CORROSION MEETING, 4thinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional do IPENinstname:Instituto de Pesquisas Energéticas e Nucleares (IPEN)instacron:IPEN185612012CORREA, OLANDIR V.SOUZA, JOSE A. deRAMANATHAN, LALGUDI V.13-02Proceedings173348819895FERNANDES, STELA M.C.:1733:730:SCORREA, OLANDIR V.:488:730:NSOUZA, JOSE A. DE:198:1131:NRAMANATHAN, LALGUDI V.:95:730:NORIGINAL18561.pdfapplication/pdf287421http://repositorio.ipen.br/bitstream/123456789/17701/1/18561.pdfdd897ba4e35c7db569c1a81f91992395MD51123456789/177012022-04-25 19:15:52.976oai:repositorio.ipen.br:123456789/17701Repositório InstitucionalPUBhttp://repositorio.ipen.br/oai/requestbibl@ipen.bropendoar:45102022-04-25T19:15:52Repositório Institucional do IPEN - Instituto de Pesquisas Energéticas e Nucleares (IPEN)false |
dc.title.pt_BR.fl_str_mv |
Hydrotalcite and Boehmite coatings for increased protection of Aluminum clad spent nuclear fuel |
title |
Hydrotalcite and Boehmite coatings for increased protection of Aluminum clad spent nuclear fuel |
spellingShingle |
Hydrotalcite and Boehmite coatings for increased protection of Aluminum clad spent nuclear fuel FERNANDES, STELA M.C. iear-1 reactor aluminium cladding coatings pitting corrosion corrosion resistance spent fuel storage wet storage rare earths |
title_short |
Hydrotalcite and Boehmite coatings for increased protection of Aluminum clad spent nuclear fuel |
title_full |
Hydrotalcite and Boehmite coatings for increased protection of Aluminum clad spent nuclear fuel |
title_fullStr |
Hydrotalcite and Boehmite coatings for increased protection of Aluminum clad spent nuclear fuel |
title_full_unstemmed |
Hydrotalcite and Boehmite coatings for increased protection of Aluminum clad spent nuclear fuel |
title_sort |
Hydrotalcite and Boehmite coatings for increased protection of Aluminum clad spent nuclear fuel |
author |
FERNANDES, STELA M.C. |
author_facet |
FERNANDES, STELA M.C. CORREA, OLANDIR V. SOUZA, JOSE A. de RAMANATHAN, LALGUDI V. CONGRESSO BRASILEIRO DE CORROSAO, 32.; INTERNATIONAL CORROSION MEETING, 4th |
author_role |
author |
author2 |
CORREA, OLANDIR V. SOUZA, JOSE A. de RAMANATHAN, LALGUDI V. CONGRESSO BRASILEIRO DE CORROSAO, 32.; INTERNATIONAL CORROSION MEETING, 4th |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
FERNANDES, STELA M.C. CORREA, OLANDIR V. SOUZA, JOSE A. de RAMANATHAN, LALGUDI V. CONGRESSO BRASILEIRO DE CORROSAO, 32.; INTERNATIONAL CORROSION MEETING, 4th |
dc.subject.por.fl_str_mv |
iear-1 reactor aluminium cladding coatings pitting corrosion corrosion resistance spent fuel storage wet storage rare earths |
topic |
iear-1 reactor aluminium cladding coatings pitting corrosion corrosion resistance spent fuel storage wet storage rare earths |
description |
It is essential to increase the corrosion resistance of Al-clad research reactor (RR) spent fuels during long term wet storage. Laboratory and field tests were carried out to evaluate the pitting corrosion resistance of rare earth containing conversion coatings on Al alloys, AA 1100 and AA 6061, used as cladding of RR fuel plates. These investigations were extended to include boehmite and hydrotalcite (HTC) coatings on Al alloy surfaces. Characterization of the coatings was done with the aid of SEM/FEG/EDS and x-ray diffraction analysis. The electrochemical behavior of uncoated and coated specimens was determined in 0.1 M NaCl. Field tests were carried out in which uncoated, lanthanide-based conversion coated, boehmite coated, cerium modified boehmite coated, HTC coated and cerium modified HTC coated Al alloy coupons were exposed to the IEA-R1 reactor spent fuel basin for varying periods and then their corrosion resistance evaluated. Most of the coatings increased the pitting corrosion resistance of the two alloys and among the coatings, the cerium modified HTC coating was the most efficient. |
publishDate |
2014 |
dc.date.evento.pt_BR.fl_str_mv |
May 14???18, 2012 |
dc.date.accessioned.fl_str_mv |
2014-11-17T18:36:42Z 2014-11-18T18:54:10Z 2015-04-01T22:23:47Z |
dc.date.available.fl_str_mv |
2014-11-17T18:36:42Z 2014-11-18T18:54:10Z 2015-04-01T22:23:47Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/conferenceObject |
format |
conferenceObject |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://repositorio.ipen.br/handle/123456789/17701 |
url |
http://repositorio.ipen.br/handle/123456789/17701 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.coverage.pt_BR.fl_str_mv |
I |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional do IPEN instname:Instituto de Pesquisas Energéticas e Nucleares (IPEN) instacron:IPEN |
instname_str |
Instituto de Pesquisas Energéticas e Nucleares (IPEN) |
instacron_str |
IPEN |
institution |
IPEN |
reponame_str |
Repositório Institucional do IPEN |
collection |
Repositório Institucional do IPEN |
bitstream.url.fl_str_mv |
http://repositorio.ipen.br/bitstream/123456789/17701/1/18561.pdf |
bitstream.checksum.fl_str_mv |
dd897ba4e35c7db569c1a81f91992395 |
bitstream.checksumAlgorithm.fl_str_mv |
MD5 |
repository.name.fl_str_mv |
Repositório Institucional do IPEN - Instituto de Pesquisas Energéticas e Nucleares (IPEN) |
repository.mail.fl_str_mv |
bibl@ipen.br |
_version_ |
1767254208277381120 |