Synthesis and Characterization of New Diazenecarboxamide Ligands Using a Selective Adduct Formation with B(C6F5)3

Detalhes bibliográficos
Autor(a) principal: Escobar,Manuel A.
Data de Publicação: 2016
Outros Autores: Valderrama,Mauricio, Daniliuc,Constantin G., Rojas,Rene S.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016000100194
Resumo: The synthesis and structure of new N-(2,6-diisopropylphenyl)-2-phenyldiazenecarboxamide (L2) and N-(2,6-diisopropylphenyl)-2 (perfluorophenyl) diazenecarboxamide (L3) ligands are described. The subsequent reactions of ligands L1, L2 and L3 with trispentafluorophenylboron gave rise to new adducts (A1), (A2) and (A3), where B(C6F5)3 is coordinated to the carbonyl group. New ligands and adducts are characterized by nuclear magnetic resonance (NMR), infrared (IR), and elemental analysis techniques. The crystal structures of all compounds are obtained and described.
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spelling Synthesis and Characterization of New Diazenecarboxamide Ligands Using a Selective Adduct Formation with B(C6F5)3diazenecarboxamide ligandsborane adductazo compoundsThe synthesis and structure of new N-(2,6-diisopropylphenyl)-2-phenyldiazenecarboxamide (L2) and N-(2,6-diisopropylphenyl)-2 (perfluorophenyl) diazenecarboxamide (L3) ligands are described. The subsequent reactions of ligands L1, L2 and L3 with trispentafluorophenylboron gave rise to new adducts (A1), (A2) and (A3), where B(C6F5)3 is coordinated to the carbonyl group. New ligands and adducts are characterized by nuclear magnetic resonance (NMR), infrared (IR), and elemental analysis techniques. The crystal structures of all compounds are obtained and described.Sociedade Brasileira de Química2016-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016000100194Journal of the Brazilian Chemical Society v.27 n.1 2016reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0103-5053.20150270info:eu-repo/semantics/openAccessEscobar,Manuel A.Valderrama,MauricioDaniliuc,Constantin G.Rojas,Rene S.eng2016-03-09T00:00:00Zoai:scielo:S0103-50532016000100194Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2016-03-09T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Synthesis and Characterization of New Diazenecarboxamide Ligands Using a Selective Adduct Formation with B(C6F5)3
title Synthesis and Characterization of New Diazenecarboxamide Ligands Using a Selective Adduct Formation with B(C6F5)3
spellingShingle Synthesis and Characterization of New Diazenecarboxamide Ligands Using a Selective Adduct Formation with B(C6F5)3
Escobar,Manuel A.
diazenecarboxamide ligands
borane adduct
azo compounds
title_short Synthesis and Characterization of New Diazenecarboxamide Ligands Using a Selective Adduct Formation with B(C6F5)3
title_full Synthesis and Characterization of New Diazenecarboxamide Ligands Using a Selective Adduct Formation with B(C6F5)3
title_fullStr Synthesis and Characterization of New Diazenecarboxamide Ligands Using a Selective Adduct Formation with B(C6F5)3
title_full_unstemmed Synthesis and Characterization of New Diazenecarboxamide Ligands Using a Selective Adduct Formation with B(C6F5)3
title_sort Synthesis and Characterization of New Diazenecarboxamide Ligands Using a Selective Adduct Formation with B(C6F5)3
author Escobar,Manuel A.
author_facet Escobar,Manuel A.
Valderrama,Mauricio
Daniliuc,Constantin G.
Rojas,Rene S.
author_role author
author2 Valderrama,Mauricio
Daniliuc,Constantin G.
Rojas,Rene S.
author2_role author
author
author
dc.contributor.author.fl_str_mv Escobar,Manuel A.
Valderrama,Mauricio
Daniliuc,Constantin G.
Rojas,Rene S.
dc.subject.por.fl_str_mv diazenecarboxamide ligands
borane adduct
azo compounds
topic diazenecarboxamide ligands
borane adduct
azo compounds
description The synthesis and structure of new N-(2,6-diisopropylphenyl)-2-phenyldiazenecarboxamide (L2) and N-(2,6-diisopropylphenyl)-2 (perfluorophenyl) diazenecarboxamide (L3) ligands are described. The subsequent reactions of ligands L1, L2 and L3 with trispentafluorophenylboron gave rise to new adducts (A1), (A2) and (A3), where B(C6F5)3 is coordinated to the carbonyl group. New ligands and adducts are characterized by nuclear magnetic resonance (NMR), infrared (IR), and elemental analysis techniques. The crystal structures of all compounds are obtained and described.
publishDate 2016
dc.date.none.fl_str_mv 2016-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016000100194
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016000100194
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.5935/0103-5053.20150270
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.27 n.1 2016
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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