Aerobic, catalytic oxidation of alcohols in ionic liquids

Detalhes bibliográficos
Autor(a) principal: Souza,Roberto F. de
Data de Publicação: 2006
Outros Autores: Dupont,Jairton, Dullius,Jeane E. de L.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532006000100007
Resumo: An efficient and simple catalytic system based on RuCl3 dissolved in ionic liquids has been developed for the oxidation of alcohols into aldehydes and ketones under mild conditions. A new fluorinated ionic liquid, 1-n-butyl-3-methylimidazolium pentadecafluorooctanoate, was synthesized and demonstrated better performance that the other ionic liquids employed. Moreover this catalytic system utilizes molecular oxygen as an oxidizing agent, producing water as the only by-product.
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spelling Aerobic, catalytic oxidation of alcohols in ionic liquidsbiphasic oxidationionic liquidsalcoholsmolecular oxygenruthenium catalystsAn efficient and simple catalytic system based on RuCl3 dissolved in ionic liquids has been developed for the oxidation of alcohols into aldehydes and ketones under mild conditions. A new fluorinated ionic liquid, 1-n-butyl-3-methylimidazolium pentadecafluorooctanoate, was synthesized and demonstrated better performance that the other ionic liquids employed. Moreover this catalytic system utilizes molecular oxygen as an oxidizing agent, producing water as the only by-product.Sociedade Brasileira de Química2006-02-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532006000100007Journal of the Brazilian Chemical Society v.17 n.1 2006reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532006000100007info:eu-repo/semantics/openAccessSouza,Roberto F. deDupont,JairtonDullius,Jeane E. de L.eng2006-03-14T00:00:00Zoai:scielo:S0103-50532006000100007Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2006-03-14T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Aerobic, catalytic oxidation of alcohols in ionic liquids
title Aerobic, catalytic oxidation of alcohols in ionic liquids
spellingShingle Aerobic, catalytic oxidation of alcohols in ionic liquids
Souza,Roberto F. de
biphasic oxidation
ionic liquids
alcohols
molecular oxygen
ruthenium catalysts
title_short Aerobic, catalytic oxidation of alcohols in ionic liquids
title_full Aerobic, catalytic oxidation of alcohols in ionic liquids
title_fullStr Aerobic, catalytic oxidation of alcohols in ionic liquids
title_full_unstemmed Aerobic, catalytic oxidation of alcohols in ionic liquids
title_sort Aerobic, catalytic oxidation of alcohols in ionic liquids
author Souza,Roberto F. de
author_facet Souza,Roberto F. de
Dupont,Jairton
Dullius,Jeane E. de L.
author_role author
author2 Dupont,Jairton
Dullius,Jeane E. de L.
author2_role author
author
dc.contributor.author.fl_str_mv Souza,Roberto F. de
Dupont,Jairton
Dullius,Jeane E. de L.
dc.subject.por.fl_str_mv biphasic oxidation
ionic liquids
alcohols
molecular oxygen
ruthenium catalysts
topic biphasic oxidation
ionic liquids
alcohols
molecular oxygen
ruthenium catalysts
description An efficient and simple catalytic system based on RuCl3 dissolved in ionic liquids has been developed for the oxidation of alcohols into aldehydes and ketones under mild conditions. A new fluorinated ionic liquid, 1-n-butyl-3-methylimidazolium pentadecafluorooctanoate, was synthesized and demonstrated better performance that the other ionic liquids employed. Moreover this catalytic system utilizes molecular oxygen as an oxidizing agent, producing water as the only by-product.
publishDate 2006
dc.date.none.fl_str_mv 2006-02-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532006000100007
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532006000100007
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532006000100007
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.17 n.1 2006
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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