Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2]
Autor(a) principal: | |
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Data de Publicação: | 2000 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300013 |
Resumo: | The new 5-(n-alkoxyphenyl)-2-n-alkyltetrazole (L¹) and alpha,omega-bis-[5-(4-pentoxyphenyl)-2-alkanetetrazoles] (L²) ligands and their Pd(II) complexes have been synthesized. The X-ray diffraction study of the palladium complex with L¹ reveals a mononuclear structure in which the geometry of the Pd(L¹)2Cl2 chromophore is planar as required by the inversion center at the palladium atom, where each molecule of phenyltetrazole binds to the metal ion in a monodentate fashion via a Pd-N1 sigma-bond. For the palladium complex with L², a dinuclear structure ([Pd2(L²)2Cl4 ]) has been proposed on the basis of NMR and IR spectroscopy. |
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Journal of the Brazilian Chemical Society (Online) |
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Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2]palladiumphenyltetrazolecrystal structure analysisThe new 5-(n-alkoxyphenyl)-2-n-alkyltetrazole (L¹) and alpha,omega-bis-[5-(4-pentoxyphenyl)-2-alkanetetrazoles] (L²) ligands and their Pd(II) complexes have been synthesized. The X-ray diffraction study of the palladium complex with L¹ reveals a mononuclear structure in which the geometry of the Pd(L¹)2Cl2 chromophore is planar as required by the inversion center at the palladium atom, where each molecule of phenyltetrazole binds to the metal ion in a monodentate fashion via a Pd-N1 sigma-bond. For the palladium complex with L², a dinuclear structure ([Pd2(L²)2Cl4 ]) has been proposed on the basis of NMR and IR spectroscopy.Sociedade Brasileira de Química2000-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300013Journal of the Brazilian Chemical Society v.11 n.3 2000reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532000000300013info:eu-repo/semantics/openAccessGallardo,HugoBegnini,Iêda MariaNeves,AdemirVencato,Ivoeng2000-11-06T00:00:00Zoai:scielo:S0103-50532000000300013Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2000-11-06T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2] |
title |
Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2] |
spellingShingle |
Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2] Gallardo,Hugo palladium phenyltetrazole crystal structure analysis |
title_short |
Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2] |
title_full |
Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2] |
title_fullStr |
Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2] |
title_full_unstemmed |
Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2] |
title_sort |
Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2] |
author |
Gallardo,Hugo |
author_facet |
Gallardo,Hugo Begnini,Iêda Maria Neves,Ademir Vencato,Ivo |
author_role |
author |
author2 |
Begnini,Iêda Maria Neves,Ademir Vencato,Ivo |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Gallardo,Hugo Begnini,Iêda Maria Neves,Ademir Vencato,Ivo |
dc.subject.por.fl_str_mv |
palladium phenyltetrazole crystal structure analysis |
topic |
palladium phenyltetrazole crystal structure analysis |
description |
The new 5-(n-alkoxyphenyl)-2-n-alkyltetrazole (L¹) and alpha,omega-bis-[5-(4-pentoxyphenyl)-2-alkanetetrazoles] (L²) ligands and their Pd(II) complexes have been synthesized. The X-ray diffraction study of the palladium complex with L¹ reveals a mononuclear structure in which the geometry of the Pd(L¹)2Cl2 chromophore is planar as required by the inversion center at the palladium atom, where each molecule of phenyltetrazole binds to the metal ion in a monodentate fashion via a Pd-N1 sigma-bond. For the palladium complex with L², a dinuclear structure ([Pd2(L²)2Cl4 ]) has been proposed on the basis of NMR and IR spectroscopy. |
publishDate |
2000 |
dc.date.none.fl_str_mv |
2000-06-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300013 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300013 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0103-50532000000300013 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.11 n.3 2000 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318164128825344 |