Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2]

Detalhes bibliográficos
Autor(a) principal: Gallardo,Hugo
Data de Publicação: 2000
Outros Autores: Begnini,Iêda Maria, Neves,Ademir, Vencato,Ivo
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300013
Resumo: The new 5-(n-alkoxyphenyl)-2-n-alkyltetrazole (L¹) and alpha,omega-bis-[5-(4-pentoxyphenyl)-2-alkanetetrazoles] (L²) ligands and their Pd(II) complexes have been synthesized. The X-ray diffraction study of the palladium complex with L¹ reveals a mononuclear structure in which the geometry of the Pd(L¹)2Cl2 chromophore is planar as required by the inversion center at the palladium atom, where each molecule of phenyltetrazole binds to the metal ion in a monodentate fashion via a Pd-N1 sigma-bond. For the palladium complex with L², a dinuclear structure ([Pd2(L²)2Cl4 ]) has been proposed on the basis of NMR and IR spectroscopy.
id SBQ-2_7fedd4266438cd7ed7b79633e8e8ecf5
oai_identifier_str oai:scielo:S0103-50532000000300013
network_acronym_str SBQ-2
network_name_str Journal of the Brazilian Chemical Society (Online)
repository_id_str
spelling Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2]palladiumphenyltetrazolecrystal structure analysisThe new 5-(n-alkoxyphenyl)-2-n-alkyltetrazole (L¹) and alpha,omega-bis-[5-(4-pentoxyphenyl)-2-alkanetetrazoles] (L²) ligands and their Pd(II) complexes have been synthesized. The X-ray diffraction study of the palladium complex with L¹ reveals a mononuclear structure in which the geometry of the Pd(L¹)2Cl2 chromophore is planar as required by the inversion center at the palladium atom, where each molecule of phenyltetrazole binds to the metal ion in a monodentate fashion via a Pd-N1 sigma-bond. For the palladium complex with L², a dinuclear structure ([Pd2(L²)2Cl4 ]) has been proposed on the basis of NMR and IR spectroscopy.Sociedade Brasileira de Química2000-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300013Journal of the Brazilian Chemical Society v.11 n.3 2000reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532000000300013info:eu-repo/semantics/openAccessGallardo,HugoBegnini,Iêda MariaNeves,AdemirVencato,Ivoeng2000-11-06T00:00:00Zoai:scielo:S0103-50532000000300013Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2000-11-06T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2]
title Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2]
spellingShingle Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2]
Gallardo,Hugo
palladium
phenyltetrazole
crystal structure analysis
title_short Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2]
title_full Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2]
title_fullStr Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2]
title_full_unstemmed Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2]
title_sort Synthesis, characterization and thermal properties of palladium(II) complexes containing phenyltetrazole. Crystal structure of trans-[C40H64N8 O2PdCl2]
author Gallardo,Hugo
author_facet Gallardo,Hugo
Begnini,Iêda Maria
Neves,Ademir
Vencato,Ivo
author_role author
author2 Begnini,Iêda Maria
Neves,Ademir
Vencato,Ivo
author2_role author
author
author
dc.contributor.author.fl_str_mv Gallardo,Hugo
Begnini,Iêda Maria
Neves,Ademir
Vencato,Ivo
dc.subject.por.fl_str_mv palladium
phenyltetrazole
crystal structure analysis
topic palladium
phenyltetrazole
crystal structure analysis
description The new 5-(n-alkoxyphenyl)-2-n-alkyltetrazole (L¹) and alpha,omega-bis-[5-(4-pentoxyphenyl)-2-alkanetetrazoles] (L²) ligands and their Pd(II) complexes have been synthesized. The X-ray diffraction study of the palladium complex with L¹ reveals a mononuclear structure in which the geometry of the Pd(L¹)2Cl2 chromophore is planar as required by the inversion center at the palladium atom, where each molecule of phenyltetrazole binds to the metal ion in a monodentate fashion via a Pd-N1 sigma-bond. For the palladium complex with L², a dinuclear structure ([Pd2(L²)2Cl4 ]) has been proposed on the basis of NMR and IR spectroscopy.
publishDate 2000
dc.date.none.fl_str_mv 2000-06-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300013
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300013
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532000000300013
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.11 n.3 2000
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
_version_ 1750318164128825344