Palladium/Heteropoly Acid Catalyzed Oxidative Coupling of 2-Methoxy-1,4-benzoquinone with Arenes
Autor(a) principal: | |
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Data de Publicação: | 2002 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000100018 |
Resumo: | Oxidative coupling of 2-methoxy-1,4-benzoquinone and arenes in acetic acid gives methoxyaryl-substituted 1,4-benzoquinones. The reaction is effectively catalyzed by a Pd(OAc)2/heteropoly acid (H9PMo6V6O40 ) redox system with dioxygen as the final oxidant. |
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Journal of the Brazilian Chemical Society (Online) |
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Palladium/Heteropoly Acid Catalyzed Oxidative Coupling of 2-Methoxy-1,4-benzoquinone with Arenesoxidative couplingarenesquinonescatalysispalladium/heteropoly acidOxidative coupling of 2-methoxy-1,4-benzoquinone and arenes in acetic acid gives methoxyaryl-substituted 1,4-benzoquinones. The reaction is effectively catalyzed by a Pd(OAc)2/heteropoly acid (H9PMo6V6O40 ) redox system with dioxygen as the final oxidant.Sociedade Brasileira de Química2002-02-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000100018Journal of the Brazilian Chemical Society v.13 n.1 2002reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532002000100018info:eu-repo/semantics/openAccessOliveira,Rosilene A. deGusevskaya,Elena V.Carazza,Fernandoeng2002-06-20T00:00:00Zoai:scielo:S0103-50532002000100018Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2002-06-20T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Palladium/Heteropoly Acid Catalyzed Oxidative Coupling of 2-Methoxy-1,4-benzoquinone with Arenes |
title |
Palladium/Heteropoly Acid Catalyzed Oxidative Coupling of 2-Methoxy-1,4-benzoquinone with Arenes |
spellingShingle |
Palladium/Heteropoly Acid Catalyzed Oxidative Coupling of 2-Methoxy-1,4-benzoquinone with Arenes Oliveira,Rosilene A. de oxidative coupling arenes quinones catalysis palladium/heteropoly acid |
title_short |
Palladium/Heteropoly Acid Catalyzed Oxidative Coupling of 2-Methoxy-1,4-benzoquinone with Arenes |
title_full |
Palladium/Heteropoly Acid Catalyzed Oxidative Coupling of 2-Methoxy-1,4-benzoquinone with Arenes |
title_fullStr |
Palladium/Heteropoly Acid Catalyzed Oxidative Coupling of 2-Methoxy-1,4-benzoquinone with Arenes |
title_full_unstemmed |
Palladium/Heteropoly Acid Catalyzed Oxidative Coupling of 2-Methoxy-1,4-benzoquinone with Arenes |
title_sort |
Palladium/Heteropoly Acid Catalyzed Oxidative Coupling of 2-Methoxy-1,4-benzoquinone with Arenes |
author |
Oliveira,Rosilene A. de |
author_facet |
Oliveira,Rosilene A. de Gusevskaya,Elena V. Carazza,Fernando |
author_role |
author |
author2 |
Gusevskaya,Elena V. Carazza,Fernando |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Oliveira,Rosilene A. de Gusevskaya,Elena V. Carazza,Fernando |
dc.subject.por.fl_str_mv |
oxidative coupling arenes quinones catalysis palladium/heteropoly acid |
topic |
oxidative coupling arenes quinones catalysis palladium/heteropoly acid |
description |
Oxidative coupling of 2-methoxy-1,4-benzoquinone and arenes in acetic acid gives methoxyaryl-substituted 1,4-benzoquinones. The reaction is effectively catalyzed by a Pd(OAc)2/heteropoly acid (H9PMo6V6O40 ) redox system with dioxygen as the final oxidant. |
publishDate |
2002 |
dc.date.none.fl_str_mv |
2002-02-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000100018 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000100018 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0103-50532002000100018 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.13 n.1 2002 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318164594393088 |