Cohalogenation of limonene, carvomenthene and related unsaturated monoterpenic alcohols

Detalhes bibliográficos
Autor(a) principal: Sanseverino,Antonio M.
Data de Publicação: 2000
Outros Autores: Silva,Flavia M. da, Jones Jr,Joel, Mattos,Marcio C. S. de
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000400010
Resumo: Cohalogenation of (R)-limonene and (R)-carvomenthene with I2/H2O/Cu(OAc)2·H 2O in aqueous dioxane followed by base treatment produced stereospecifically the corresponding trans-epoxides. Same methodology of cohalogenation applied to related monoterpenic unsaturated alcohols produced pinol derivatives [from (5R)-cis-carveol and (S)-alpha-terpineol] or iodohydrins [from (S)-perillyl alcohol and (5R)-trans-carveol].
id SBQ-2_651f9097d9f4aa98447c7f714d04ee14
oai_identifier_str oai:scielo:S0103-50532000000400010
network_acronym_str SBQ-2
network_name_str Journal of the Brazilian Chemical Society (Online)
repository_id_str
spelling Cohalogenation of limonene, carvomenthene and related unsaturated monoterpenic alcoholscyclisation, halohydrinsterpenes and terpenoidselectrophilic addition reactionCohalogenation of (R)-limonene and (R)-carvomenthene with I2/H2O/Cu(OAc)2·H 2O in aqueous dioxane followed by base treatment produced stereospecifically the corresponding trans-epoxides. Same methodology of cohalogenation applied to related monoterpenic unsaturated alcohols produced pinol derivatives [from (5R)-cis-carveol and (S)-alpha-terpineol] or iodohydrins [from (S)-perillyl alcohol and (5R)-trans-carveol].Sociedade Brasileira de Química2000-08-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000400010Journal of the Brazilian Chemical Society v.11 n.4 2000reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532000000400010info:eu-repo/semantics/openAccessSanseverino,Antonio M.Silva,Flavia M. daJones Jr,JoelMattos,Marcio C. S. deeng2000-11-17T00:00:00Zoai:scielo:S0103-50532000000400010Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2000-11-17T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Cohalogenation of limonene, carvomenthene and related unsaturated monoterpenic alcohols
title Cohalogenation of limonene, carvomenthene and related unsaturated monoterpenic alcohols
spellingShingle Cohalogenation of limonene, carvomenthene and related unsaturated monoterpenic alcohols
Sanseverino,Antonio M.
cyclisation, halohydrins
terpenes and terpenoids
electrophilic addition reaction
title_short Cohalogenation of limonene, carvomenthene and related unsaturated monoterpenic alcohols
title_full Cohalogenation of limonene, carvomenthene and related unsaturated monoterpenic alcohols
title_fullStr Cohalogenation of limonene, carvomenthene and related unsaturated monoterpenic alcohols
title_full_unstemmed Cohalogenation of limonene, carvomenthene and related unsaturated monoterpenic alcohols
title_sort Cohalogenation of limonene, carvomenthene and related unsaturated monoterpenic alcohols
author Sanseverino,Antonio M.
author_facet Sanseverino,Antonio M.
Silva,Flavia M. da
Jones Jr,Joel
Mattos,Marcio C. S. de
author_role author
author2 Silva,Flavia M. da
Jones Jr,Joel
Mattos,Marcio C. S. de
author2_role author
author
author
dc.contributor.author.fl_str_mv Sanseverino,Antonio M.
Silva,Flavia M. da
Jones Jr,Joel
Mattos,Marcio C. S. de
dc.subject.por.fl_str_mv cyclisation, halohydrins
terpenes and terpenoids
electrophilic addition reaction
topic cyclisation, halohydrins
terpenes and terpenoids
electrophilic addition reaction
description Cohalogenation of (R)-limonene and (R)-carvomenthene with I2/H2O/Cu(OAc)2·H 2O in aqueous dioxane followed by base treatment produced stereospecifically the corresponding trans-epoxides. Same methodology of cohalogenation applied to related monoterpenic unsaturated alcohols produced pinol derivatives [from (5R)-cis-carveol and (S)-alpha-terpineol] or iodohydrins [from (S)-perillyl alcohol and (5R)-trans-carveol].
publishDate 2000
dc.date.none.fl_str_mv 2000-08-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000400010
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000400010
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532000000400010
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.11 n.4 2000
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
_version_ 1750318164149796864

Registros relacionados