Potential Slow Release Fertilizers and Acid Soil Conditioners Obtained by One-Pot Mechanochemical Activation of Chrysotile:Cement Roofing Sheets with K2HPO4

Bibliographic Details
Main Author: Borges,Roger
Publication Date: 2019
Other Authors: Wypych,Fernando
Format: Article
Language: eng
Source: Journal of the Brazilian Chemical Society (Online)
Download full: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532019000200326
Summary: Chrysotile:cement roofing sheets were milled with and without K2HPO4. As indicated by X-ray diffraction (XRD), the samples crystallinities were reduced with the increasing milling time. The same tendency was observed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), with disaggregation of the chrysotile fiber bundles and formation of non-fibrous micrometric agglomerate particles. After milling for 16 min, most of the phases present in the cement and chrysotile were transformed into amorphous materials, except quartz, in which the structure integrity was preserved, and calcium carbonate, where the particles were reduced to nanometric size. Both milled samples were submitted to release experiments in water, where the characteristics of a potential slow release fertilizer and acid soil conditioner were observed. The process is a viable alternative not only to eliminate the hazard of chrysotile fibers without the need to remove them from the cement matrix, but also as aggregation value to the milled almost amorphous mixture.
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spelling Potential Slow Release Fertilizers and Acid Soil Conditioners Obtained by One-Pot Mechanochemical Activation of Chrysotile:Cement Roofing Sheets with K2HPO4chrysotilecement roofing sheetsmechanochemical activationslow release fertilizerChrysotile:cement roofing sheets were milled with and without K2HPO4. As indicated by X-ray diffraction (XRD), the samples crystallinities were reduced with the increasing milling time. The same tendency was observed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), with disaggregation of the chrysotile fiber bundles and formation of non-fibrous micrometric agglomerate particles. After milling for 16 min, most of the phases present in the cement and chrysotile were transformed into amorphous materials, except quartz, in which the structure integrity was preserved, and calcium carbonate, where the particles were reduced to nanometric size. Both milled samples were submitted to release experiments in water, where the characteristics of a potential slow release fertilizer and acid soil conditioner were observed. The process is a viable alternative not only to eliminate the hazard of chrysotile fibers without the need to remove them from the cement matrix, but also as aggregation value to the milled almost amorphous mixture.Sociedade Brasileira de Química2019-02-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532019000200326Journal of the Brazilian Chemical Society v.30 n.2 2019reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.21577/0103-5053.20180181info:eu-repo/semantics/openAccessBorges,RogerWypych,Fernandoeng2019-01-14T00:00:00Zoai:scielo:S0103-50532019000200326Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2019-01-14T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Potential Slow Release Fertilizers and Acid Soil Conditioners Obtained by One-Pot Mechanochemical Activation of Chrysotile:Cement Roofing Sheets with K2HPO4
title Potential Slow Release Fertilizers and Acid Soil Conditioners Obtained by One-Pot Mechanochemical Activation of Chrysotile:Cement Roofing Sheets with K2HPO4
spellingShingle Potential Slow Release Fertilizers and Acid Soil Conditioners Obtained by One-Pot Mechanochemical Activation of Chrysotile:Cement Roofing Sheets with K2HPO4
Borges,Roger
chrysotile
cement roofing sheets
mechanochemical activation
slow release fertilizer
title_short Potential Slow Release Fertilizers and Acid Soil Conditioners Obtained by One-Pot Mechanochemical Activation of Chrysotile:Cement Roofing Sheets with K2HPO4
title_full Potential Slow Release Fertilizers and Acid Soil Conditioners Obtained by One-Pot Mechanochemical Activation of Chrysotile:Cement Roofing Sheets with K2HPO4
title_fullStr Potential Slow Release Fertilizers and Acid Soil Conditioners Obtained by One-Pot Mechanochemical Activation of Chrysotile:Cement Roofing Sheets with K2HPO4
title_full_unstemmed Potential Slow Release Fertilizers and Acid Soil Conditioners Obtained by One-Pot Mechanochemical Activation of Chrysotile:Cement Roofing Sheets with K2HPO4
title_sort Potential Slow Release Fertilizers and Acid Soil Conditioners Obtained by One-Pot Mechanochemical Activation of Chrysotile:Cement Roofing Sheets with K2HPO4
author Borges,Roger
author_facet Borges,Roger
Wypych,Fernando
author_role author
author2 Wypych,Fernando
author2_role author
dc.contributor.author.fl_str_mv Borges,Roger
Wypych,Fernando
dc.subject.por.fl_str_mv chrysotile
cement roofing sheets
mechanochemical activation
slow release fertilizer
topic chrysotile
cement roofing sheets
mechanochemical activation
slow release fertilizer
description Chrysotile:cement roofing sheets were milled with and without K2HPO4. As indicated by X-ray diffraction (XRD), the samples crystallinities were reduced with the increasing milling time. The same tendency was observed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), with disaggregation of the chrysotile fiber bundles and formation of non-fibrous micrometric agglomerate particles. After milling for 16 min, most of the phases present in the cement and chrysotile were transformed into amorphous materials, except quartz, in which the structure integrity was preserved, and calcium carbonate, where the particles were reduced to nanometric size. Both milled samples were submitted to release experiments in water, where the characteristics of a potential slow release fertilizer and acid soil conditioner were observed. The process is a viable alternative not only to eliminate the hazard of chrysotile fibers without the need to remove them from the cement matrix, but also as aggregation value to the milled almost amorphous mixture.
publishDate 2019
dc.date.none.fl_str_mv 2019-02-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
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status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532019000200326
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532019000200326
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.21577/0103-5053.20180181
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.30 n.2 2019
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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