Derivados organometálicos de estanho(II) - Parte 1. Compostos ciclopentadienílicos
Autor(a) principal: | |
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Data de Publicação: | 2001 |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Química Nova (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422001000400014 |
Resumo: | This paper provides a brief review of the chemistry of cyclopentadienyl Sn(II) derivatives which includes the preparation, the molecular structure and reactivity associated with such bis-sandwich tin(II) species. It is compared structural and spectroscopic results and it is also discussed how the nature of the cyclopentadienyl ring bonded to the Sn centre plays an important role in the structural and stability features of the derivatives. Bulk rings such as C5HPr i4- , C5Bz5-, C5Me4SiMe2Bu t- and C5Ph5- render air-stable and parallel ring-bonded compounds. |
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Derivados organometálicos de estanho(II) - Parte 1. Compostos ciclopentadienílicosorganometallic tin(II) compoundssolid state NMRcyclopentadienyl tin(II) derivativesThis paper provides a brief review of the chemistry of cyclopentadienyl Sn(II) derivatives which includes the preparation, the molecular structure and reactivity associated with such bis-sandwich tin(II) species. It is compared structural and spectroscopic results and it is also discussed how the nature of the cyclopentadienyl ring bonded to the Sn centre plays an important role in the structural and stability features of the derivatives. Bulk rings such as C5HPr i4- , C5Bz5-, C5Me4SiMe2Bu t- and C5Ph5- render air-stable and parallel ring-bonded compounds.Sociedade Brasileira de Química2001-08-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422001000400014Química Nova v.24 n.4 2001reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0100-40422001000400014info:eu-repo/semantics/openAccessLima,Geraldo M. depor2001-08-31T00:00:00Zoai:scielo:S0100-40422001000400014Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2001-08-31T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Derivados organometálicos de estanho(II) - Parte 1. Compostos ciclopentadienílicos |
title |
Derivados organometálicos de estanho(II) - Parte 1. Compostos ciclopentadienílicos |
spellingShingle |
Derivados organometálicos de estanho(II) - Parte 1. Compostos ciclopentadienílicos Lima,Geraldo M. de organometallic tin(II) compounds solid state NMR cyclopentadienyl tin(II) derivatives |
title_short |
Derivados organometálicos de estanho(II) - Parte 1. Compostos ciclopentadienílicos |
title_full |
Derivados organometálicos de estanho(II) - Parte 1. Compostos ciclopentadienílicos |
title_fullStr |
Derivados organometálicos de estanho(II) - Parte 1. Compostos ciclopentadienílicos |
title_full_unstemmed |
Derivados organometálicos de estanho(II) - Parte 1. Compostos ciclopentadienílicos |
title_sort |
Derivados organometálicos de estanho(II) - Parte 1. Compostos ciclopentadienílicos |
author |
Lima,Geraldo M. de |
author_facet |
Lima,Geraldo M. de |
author_role |
author |
dc.contributor.author.fl_str_mv |
Lima,Geraldo M. de |
dc.subject.por.fl_str_mv |
organometallic tin(II) compounds solid state NMR cyclopentadienyl tin(II) derivatives |
topic |
organometallic tin(II) compounds solid state NMR cyclopentadienyl tin(II) derivatives |
description |
This paper provides a brief review of the chemistry of cyclopentadienyl Sn(II) derivatives which includes the preparation, the molecular structure and reactivity associated with such bis-sandwich tin(II) species. It is compared structural and spectroscopic results and it is also discussed how the nature of the cyclopentadienyl ring bonded to the Sn centre plays an important role in the structural and stability features of the derivatives. Bulk rings such as C5HPr i4- , C5Bz5-, C5Me4SiMe2Bu t- and C5Ph5- render air-stable and parallel ring-bonded compounds. |
publishDate |
2001 |
dc.date.none.fl_str_mv |
2001-08-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422001000400014 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422001000400014 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
10.1590/S0100-40422001000400014 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Química Nova v.24 n.4 2001 reponame:Química Nova (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Química Nova (Online) |
collection |
Química Nova (Online) |
repository.name.fl_str_mv |
Química Nova (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
quimicanova@sbq.org.br |
_version_ |
1750318102040543232 |