DEGRADAÇÃO FOTOCATALÍTICA DE ATRAZINA NA PRESENÇA DE CATALISADORES NANOPARTICULADOS
Autor(a) principal: | |
---|---|
Data de Publicação: | 2017 |
Outros Autores: | , , , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Química Nova (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422017000100036 |
Resumo: | Atrazine is a persistent herbicide and several studies have detected their presence in drinking water sources. In this work the atrazine photocatalytic degradation was investigated in aqueous solution using TiO2, ZnO and TiO2/ZnO catalysts. The catalysts were synthesized by Pechini's method and characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The process was monitored using absorption spectroscopy in ultraviolet and visible (UV-vis) region and high performance liquid chromatography (HPLC). The prepared catalysts were used in ultrafine powder form and its characterization showed nanometer order particle sizes. The atrazine absorbance decrease was observed after samples irradiation in catalysts presence and HPLC analysis showed a significant herbicide reduction and other compounds formation as degradation products. The ZnO catalyst use was more effective in atrazine molecule degradation compared to the other nanoparticles. |
id |
SBQ-3_319038e85da2d19b86a63e1c6dce4903 |
---|---|
oai_identifier_str |
oai:scielo:S0100-40422017000100036 |
network_acronym_str |
SBQ-3 |
network_name_str |
Química Nova (Online) |
repository_id_str |
|
spelling |
DEGRADAÇÃO FOTOCATALÍTICA DE ATRAZINA NA PRESENÇA DE CATALISADORES NANOPARTICULADOSatrazinedegradationphotocatalysisAtrazine is a persistent herbicide and several studies have detected their presence in drinking water sources. In this work the atrazine photocatalytic degradation was investigated in aqueous solution using TiO2, ZnO and TiO2/ZnO catalysts. The catalysts were synthesized by Pechini's method and characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The process was monitored using absorption spectroscopy in ultraviolet and visible (UV-vis) region and high performance liquid chromatography (HPLC). The prepared catalysts were used in ultrafine powder form and its characterization showed nanometer order particle sizes. The atrazine absorbance decrease was observed after samples irradiation in catalysts presence and HPLC analysis showed a significant herbicide reduction and other compounds formation as degradation products. The ZnO catalyst use was more effective in atrazine molecule degradation compared to the other nanoparticles.Sociedade Brasileira de Química2017-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422017000100036Química Nova v.40 n.1 2017reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.21577/0100-4042.20160148info:eu-repo/semantics/openAccessCampos,Flávio ArantesAguiar,Ana Carolina RibeiroMedeiros,Victor SouzaBranquinho,Adriene de CássiaSilva,Franco Cesar Belchior daAndrade,Rômulo Davi AlbuquerqueChaves,Andréa Rodriguespor2017-02-24T00:00:00Zoai:scielo:S0100-40422017000100036Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2017-02-24T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
DEGRADAÇÃO FOTOCATALÍTICA DE ATRAZINA NA PRESENÇA DE CATALISADORES NANOPARTICULADOS |
title |
DEGRADAÇÃO FOTOCATALÍTICA DE ATRAZINA NA PRESENÇA DE CATALISADORES NANOPARTICULADOS |
spellingShingle |
DEGRADAÇÃO FOTOCATALÍTICA DE ATRAZINA NA PRESENÇA DE CATALISADORES NANOPARTICULADOS Campos,Flávio Arantes atrazine degradation photocatalysis |
title_short |
DEGRADAÇÃO FOTOCATALÍTICA DE ATRAZINA NA PRESENÇA DE CATALISADORES NANOPARTICULADOS |
title_full |
DEGRADAÇÃO FOTOCATALÍTICA DE ATRAZINA NA PRESENÇA DE CATALISADORES NANOPARTICULADOS |
title_fullStr |
DEGRADAÇÃO FOTOCATALÍTICA DE ATRAZINA NA PRESENÇA DE CATALISADORES NANOPARTICULADOS |
title_full_unstemmed |
DEGRADAÇÃO FOTOCATALÍTICA DE ATRAZINA NA PRESENÇA DE CATALISADORES NANOPARTICULADOS |
title_sort |
DEGRADAÇÃO FOTOCATALÍTICA DE ATRAZINA NA PRESENÇA DE CATALISADORES NANOPARTICULADOS |
author |
Campos,Flávio Arantes |
author_facet |
Campos,Flávio Arantes Aguiar,Ana Carolina Ribeiro Medeiros,Victor Souza Branquinho,Adriene de Cássia Silva,Franco Cesar Belchior da Andrade,Rômulo Davi Albuquerque Chaves,Andréa Rodrigues |
author_role |
author |
author2 |
Aguiar,Ana Carolina Ribeiro Medeiros,Victor Souza Branquinho,Adriene de Cássia Silva,Franco Cesar Belchior da Andrade,Rômulo Davi Albuquerque Chaves,Andréa Rodrigues |
author2_role |
author author author author author author |
dc.contributor.author.fl_str_mv |
Campos,Flávio Arantes Aguiar,Ana Carolina Ribeiro Medeiros,Victor Souza Branquinho,Adriene de Cássia Silva,Franco Cesar Belchior da Andrade,Rômulo Davi Albuquerque Chaves,Andréa Rodrigues |
dc.subject.por.fl_str_mv |
atrazine degradation photocatalysis |
topic |
atrazine degradation photocatalysis |
description |
Atrazine is a persistent herbicide and several studies have detected their presence in drinking water sources. In this work the atrazine photocatalytic degradation was investigated in aqueous solution using TiO2, ZnO and TiO2/ZnO catalysts. The catalysts were synthesized by Pechini's method and characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The process was monitored using absorption spectroscopy in ultraviolet and visible (UV-vis) region and high performance liquid chromatography (HPLC). The prepared catalysts were used in ultrafine powder form and its characterization showed nanometer order particle sizes. The atrazine absorbance decrease was observed after samples irradiation in catalysts presence and HPLC analysis showed a significant herbicide reduction and other compounds formation as degradation products. The ZnO catalyst use was more effective in atrazine molecule degradation compared to the other nanoparticles. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422017000100036 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422017000100036 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
10.21577/0100-4042.20160148 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Química Nova v.40 n.1 2017 reponame:Química Nova (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Química Nova (Online) |
collection |
Química Nova (Online) |
repository.name.fl_str_mv |
Química Nova (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
quimicanova@sbq.org.br |
_version_ |
1750318117953732608 |