Poliuretanos obtidos de fontes renovável para aplicação em produtos capilares

Detalhes bibliográficos
Autor(a) principal: Oliveira, Elisângela Aparecida Scorsato
Data de Publicação: 2015
Tipo de documento: Dissertação
Idioma: por
Título da fonte: Repositório Institucional da UFSCAR
Texto Completo: https://repositorio.ufscar.br/handle/ufscar/8535
Resumo: One of the most remarkable and diverse physical characteristics among human beings - and, thus, fundamental for personal identity - is hair. The search for personal hair care products has been increasing in the last years and Brazil is the third largest consumer market for these products. There is a constant quest for cosmetic products able to align, relax and treat hair fibers. There are some products for this purpose, such as smart brushes, Japanese brushes and definitive brushes, among others. In this context, the aim of this project was to synthesize and characterize polyurethane obtained from a renewable source as well as evaluate its effectiveness as a hair treatment agent. Therefore, scanning electron microscopy (SEM), atomic force microscopy (AFM), Fourier-transform infrared spectroscopy (FTIR), nearinfrared reflectance spectroscopy (NIRS) and mechanical tests for tensile properties were used. The FTIR results confirmed the synthesis of the polyurethane. The polymer was associated with citric acid, glycolic acid, lactic acid, and sodium hydroxide with glycose, in order to increase adhesion of the polymer onto the hair fiber. After application, better hair fiber alignment and increased hair roughness were noticed. Through the spectroscopic analysis it was established that a chemical interaction between the polymer, its associations and hair was present. The micrographs also suggested that there was a deposition of the polymer on the hair fibers. The results indicated that the polyurethane and their associations with citric acid and sodium hydroxide with glycose, are promising for applications in hair care products.
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spelling Oliveira, Elisângela Aparecida ScorsatoDuek, Eliana Aparecida de Rezendehttp://lattes.cnpq.br/4147198882685212http://lattes.cnpq.br/22452988839963972017-02-24T18:40:41Z2017-02-24T18:40:41Z2015-03-19OLIVEIRA, Elisângela Aparecida Scorsato. Poliuretanos obtidos de fontes renovável para aplicação em produtos capilares. 2015. Dissertação (Mestrado em Ciência dos Materiais) – Universidade Federal de São Carlos, Sorocaba, 2015. Disponível em: https://repositorio.ufscar.br/handle/ufscar/8535.https://repositorio.ufscar.br/handle/ufscar/8535One of the most remarkable and diverse physical characteristics among human beings - and, thus, fundamental for personal identity - is hair. The search for personal hair care products has been increasing in the last years and Brazil is the third largest consumer market for these products. There is a constant quest for cosmetic products able to align, relax and treat hair fibers. There are some products for this purpose, such as smart brushes, Japanese brushes and definitive brushes, among others. In this context, the aim of this project was to synthesize and characterize polyurethane obtained from a renewable source as well as evaluate its effectiveness as a hair treatment agent. Therefore, scanning electron microscopy (SEM), atomic force microscopy (AFM), Fourier-transform infrared spectroscopy (FTIR), nearinfrared reflectance spectroscopy (NIRS) and mechanical tests for tensile properties were used. The FTIR results confirmed the synthesis of the polyurethane. The polymer was associated with citric acid, glycolic acid, lactic acid, and sodium hydroxide with glycose, in order to increase adhesion of the polymer onto the hair fiber. After application, better hair fiber alignment and increased hair roughness were noticed. Through the spectroscopic analysis it was established that a chemical interaction between the polymer, its associations and hair was present. The micrographs also suggested that there was a deposition of the polymer on the hair fibers. The results indicated that the polyurethane and their associations with citric acid and sodium hydroxide with glycose, are promising for applications in hair care products.Os cabelos constituem uma das características físicas mais marcante e variável dos seres humanos, tornando-se fundamental para a identidade pessoal. Assim, é cada vez maior a busca por produtos para os cuidados dos mesmos. O Brasil é o terceiro maior mercado consumidor de produtos para os cabelos, e existe uma busca constante pelas empresas do setor de cosméticos por produtos capazes de alinhar, relaxar e tratar os fios. Neste sentido podemos encontrar produtos para essa finalidade, com as mais variadas denominações, como as escovas: inteligente, japonesa, definitiva entre outras. Dentro desse contexto, o objetivo do presente projeto foi sintetizar e caracterizar um poliuretano a partir de um poliol obtido de fonte renovável, e avaliar sua eficácia após aplicação do mesmo visando tratamento capilar. Para tanto, foram utilizadas técnicas de microscopia eletrônica de varredura (MEV), microscopia de força atômica (AFM), espectroscopias de infravermelho por transformada de Fourier (FTIR) e espetroscopia de refletância no infravermelho próximo (NIRS) e ensaios mecânicos pelo módulo de tração. Os resultados de FTIR confirmaram a síntese do poliuretano, o qual foi associado aos Ácidos Cítrico, Glicólico, Lático e Hidróxido de Sódio com Glicose com o intuito de aumentar a aderência do polímero na fibra capilar. Após a aplicação verificou-se um melhor alinhamento dos fios e aumento na rugosidade. Através das análises de espectroscopia foi possível constatar que houve uma interação química entre o polímero, suas associações e os cabelos. As eletromicrografias também sugerem que houve uma deposição do polímero sobre as fibras do cabelo. Os resultados obtidos indicaram que o poliuretano e suas associações com ácido cítrico e hidróxido de sódio e com glicose, são promissores para aplicações em produtos capilares.Não recebi financiamentoporUniversidade Federal de São CarlosCâmpus SorocabaPrograma de Pós-Graduação em Ciência dos Materiais - PPGCM-SoUFSCarCabeloPoliuretanasMamonaHairPolyurethanesCastor beansENGENHARIAS::ENGENHARIA DE MATERIAIS E METALURGICAPoliuretanos obtidos de fontes renovável para aplicação em produtos capilaresinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesisOnlineinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFSCARinstname:Universidade Federal de São Carlos (UFSCAR)instacron:UFSCARORIGINALOLIVEIRA_Elisangela_2015.pdfOLIVEIRA_Elisangela_2015.pdfapplication/pdf17350237https://{{ getenv "DSPACE_HOST" "repositorio.ufscar.br" }}/bitstream/ufscar/8535/1/OLIVEIRA_Elisangela_2015.pdfa1efb77501c4df3e09734ffce33e70c1MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81957https://{{ getenv "DSPACE_HOST" "repositorio.ufscar.br" }}/bitstream/ufscar/8535/2/license.txtae0398b6f8b235e40ad82cba6c50031dMD52TEXTOLIVEIRA_Elisangela_2015.pdf.txtOLIVEIRA_Elisangela_2015.pdf.txtExtracted texttext/plain317200https://{{ getenv "DSPACE_HOST" "repositorio.ufscar.br" }}/bitstream/ufscar/8535/3/OLIVEIRA_Elisangela_2015.pdf.txt0b1f6cbdf25358576d253ab6dcc2125eMD53THUMBNAILOLIVEIRA_Elisangela_2015.pdf.jpgOLIVEIRA_Elisangela_2015.pdf.jpgIM Thumbnailimage/jpeg5843https://{{ getenv "DSPACE_HOST" "repositorio.ufscar.br" }}/bitstream/ufscar/8535/4/OLIVEIRA_Elisangela_2015.pdf.jpg267301f94fb28cec97343c7052577601MD54ufscar/85352019-11-21 15:48:53.056oai:repositorio.ufscar.br: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Repositório InstitucionalPUBhttps://repositorio.ufscar.br/oai/requestopendoar:43222019-11-21T15:48:53Repositório Institucional da UFSCAR - Universidade Federal de São Carlos (UFSCAR)false
dc.title.por.fl_str_mv Poliuretanos obtidos de fontes renovável para aplicação em produtos capilares
title Poliuretanos obtidos de fontes renovável para aplicação em produtos capilares
spellingShingle Poliuretanos obtidos de fontes renovável para aplicação em produtos capilares
Oliveira, Elisângela Aparecida Scorsato
Cabelo
Poliuretanas
Mamona
Hair
Polyurethanes
Castor beans
ENGENHARIAS::ENGENHARIA DE MATERIAIS E METALURGICA
title_short Poliuretanos obtidos de fontes renovável para aplicação em produtos capilares
title_full Poliuretanos obtidos de fontes renovável para aplicação em produtos capilares
title_fullStr Poliuretanos obtidos de fontes renovável para aplicação em produtos capilares
title_full_unstemmed Poliuretanos obtidos de fontes renovável para aplicação em produtos capilares
title_sort Poliuretanos obtidos de fontes renovável para aplicação em produtos capilares
author Oliveira, Elisângela Aparecida Scorsato
author_facet Oliveira, Elisângela Aparecida Scorsato
author_role author
dc.contributor.authorlattes.por.fl_str_mv http://lattes.cnpq.br/2245298883996397
dc.contributor.author.fl_str_mv Oliveira, Elisângela Aparecida Scorsato
dc.contributor.advisor1.fl_str_mv Duek, Eliana Aparecida de Rezende
dc.contributor.advisor1Lattes.fl_str_mv http://lattes.cnpq.br/4147198882685212
contributor_str_mv Duek, Eliana Aparecida de Rezende
dc.subject.por.fl_str_mv Cabelo
Poliuretanas
Mamona
topic Cabelo
Poliuretanas
Mamona
Hair
Polyurethanes
Castor beans
ENGENHARIAS::ENGENHARIA DE MATERIAIS E METALURGICA
dc.subject.eng.fl_str_mv Hair
Polyurethanes
Castor beans
dc.subject.cnpq.fl_str_mv ENGENHARIAS::ENGENHARIA DE MATERIAIS E METALURGICA
description One of the most remarkable and diverse physical characteristics among human beings - and, thus, fundamental for personal identity - is hair. The search for personal hair care products has been increasing in the last years and Brazil is the third largest consumer market for these products. There is a constant quest for cosmetic products able to align, relax and treat hair fibers. There are some products for this purpose, such as smart brushes, Japanese brushes and definitive brushes, among others. In this context, the aim of this project was to synthesize and characterize polyurethane obtained from a renewable source as well as evaluate its effectiveness as a hair treatment agent. Therefore, scanning electron microscopy (SEM), atomic force microscopy (AFM), Fourier-transform infrared spectroscopy (FTIR), nearinfrared reflectance spectroscopy (NIRS) and mechanical tests for tensile properties were used. The FTIR results confirmed the synthesis of the polyurethane. The polymer was associated with citric acid, glycolic acid, lactic acid, and sodium hydroxide with glycose, in order to increase adhesion of the polymer onto the hair fiber. After application, better hair fiber alignment and increased hair roughness were noticed. Through the spectroscopic analysis it was established that a chemical interaction between the polymer, its associations and hair was present. The micrographs also suggested that there was a deposition of the polymer on the hair fibers. The results indicated that the polyurethane and their associations with citric acid and sodium hydroxide with glycose, are promising for applications in hair care products.
publishDate 2015
dc.date.issued.fl_str_mv 2015-03-19
dc.date.accessioned.fl_str_mv 2017-02-24T18:40:41Z
dc.date.available.fl_str_mv 2017-02-24T18:40:41Z
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dc.identifier.citation.fl_str_mv OLIVEIRA, Elisângela Aparecida Scorsato. Poliuretanos obtidos de fontes renovável para aplicação em produtos capilares. 2015. Dissertação (Mestrado em Ciência dos Materiais) – Universidade Federal de São Carlos, Sorocaba, 2015. Disponível em: https://repositorio.ufscar.br/handle/ufscar/8535.
dc.identifier.uri.fl_str_mv https://repositorio.ufscar.br/handle/ufscar/8535
identifier_str_mv OLIVEIRA, Elisângela Aparecida Scorsato. Poliuretanos obtidos de fontes renovável para aplicação em produtos capilares. 2015. Dissertação (Mestrado em Ciência dos Materiais) – Universidade Federal de São Carlos, Sorocaba, 2015. Disponível em: https://repositorio.ufscar.br/handle/ufscar/8535.
url https://repositorio.ufscar.br/handle/ufscar/8535
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dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
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dc.publisher.none.fl_str_mv Universidade Federal de São Carlos
Câmpus Sorocaba
dc.publisher.program.fl_str_mv Programa de Pós-Graduação em Ciência dos Materiais - PPGCM-So
dc.publisher.initials.fl_str_mv UFSCar
publisher.none.fl_str_mv Universidade Federal de São Carlos
Câmpus Sorocaba
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