Detalhes bibliográficos
| Autor(a) principal: |
Passo, Joel Aparecido |
| Data de Publicação: |
2012 |
| Outros Autores: |
Merlo, Aloir Antonio,
Eccher, Juliana,
Bechtold, Ivan Helmuth,
Kelly, Stephen M. |
| Tipo de documento: |
Artigo
|
| Idioma: |
por |
| Título da fonte: |
Repositório Institucional da UFRGS |
| Texto Completo: |
http://hdl.handle.net/10183/106750
|
Resumo: |
Five monomers 5-[4-(5-cyano-4,5-dihydroisoxazol-3-yl)phenoxy]undecyl acrylate (7a); n-alkyl 3-{4-[5-(acryloyloxyundecyl) oxyphenyl]}-4,5-dihydroisoxazole-5-carboxylate (7b,c for n-butyl and n-hexyl, respectively); 3-{4-[5-(acryloyloxyundecyl) oxyphenyl]}-4,5-dihydroisoxazole-5-carboxylic acid (7d) and (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl acrylate (9) and the corresponding copolymers 10a-d, 11 and homopolymers 12 from 7a and 13 from 9 were designed and synthesized. Except for acrylate 9 which is derived from (-)-menthol, all of the monomers belong to the series containing the isoxazoline ring linked to the acrylate unit by a flexible spacer chain of eleven methylene units. They presented low glass temperature and despite birefringence behavior, these copolymers showed no mesomorphic properties. |