Avaliação da auto-associação molecular de complexos metálicos com ligantes triazenidos derivados do 1,3-bis(fenil)triazeno
Autor(a) principal: | |
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Data de Publicação: | 2007 |
Tipo de documento: | Tese |
Idioma: | por |
Título da fonte: | Biblioteca Digital de Teses e Dissertações do UFSM |
Texto Completo: | http://repositorio.ufsm.br/handle/1/4141 |
Resumo: | This work presents the synthesis and the investigation of the crystalline and molecular structure of 1,3-bis(2-methoxy-4-nitrophenyl)triazene ethanol and seventeen new mononuclear or binuclear complexes of Cu(I), Cu(II), Tl(I), Hg(II), Ag(I), Ni(II), Zn (II) with monocatenated triazenide ligands derived from the 1,3-bis(phenyl)triazene. The coordination of metallic ions by triazenido compounds had been studied in the solid state. We studied the relations that make possible the formation of intramoleculares and intermoleculares interactions, that could show supramolecular arrangements unidimensionais, bidimensional and until three-dimensional. Other eight ligands had been synthesized and we investigated its physical and molecular properties: 1,3-bis (3-nitrophenyl)triazene, 1,3-bis(4-methoxycarbonylphenyl)triazene, 1,3-bis(4-ethoxycarbonylphenyl)triazene, 1,3-bis(4-chlorophenyl)-triazene, 1-(phenyl)-3-(4-nitrophenyl)triazene, 1-(4-chlorophenyl)-3-(4-nitrophenyl)triazene, 1-(2-methoxy-4-nitrophenyl)-3-(2,4-dibromophenyl)triazene and 1-(4-nitrophenyl)-3-(2-pyrimidinyl) triazene. We used techniques of Infrared Absorption Spectroscopy, Spectrometry of Nuclear Magnetic Resonance, Melting Point and Elementary Analysis CHN in this study. The variety in the geometry of coordination of the 1,3-bis(2-methoxy-4-nitrophenyl)triazene can be used to depicted its versatility to form complexes with many metallic ions, beyond presenting a variety of chemical and spectroscopic properties. The complexes {Cu[CH3O(NO2)C6H3NNNC6H3(NO2)OCH3]}4(CH3CN)4 (1), {Cu[CH3O(NO2)C6H3NNNC6H3(NO2)OCH3(C5H5N)2(N3)]}(3) and {Cu[CH3O(O2N)C6H3NNNC6H3(NO2)OCH3-(C5H5N)2(CH3COO)]} (4), using the copper ion (I and II) had been characterized by Spectroscopy of Electronic Paramagnetic Resonance, Electronic and Electrochemical Spectroscopy. All these complexes of Cu (II) had presented interesting magnetic and electrochemical properties. |
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2017-05-222017-05-222007-09-13VILLIS, Paulo Cesar Mendes. Evaluation of the molecular autoassociation of metallic complexes with triazenide derived from 1,3-bis (phenyl)triazene. 2007. 370 f. Tese (Doutorado em Química) - Universidade Federal de Santa Maria, Santa Maria, 2007.http://repositorio.ufsm.br/handle/1/4141This work presents the synthesis and the investigation of the crystalline and molecular structure of 1,3-bis(2-methoxy-4-nitrophenyl)triazene ethanol and seventeen new mononuclear or binuclear complexes of Cu(I), Cu(II), Tl(I), Hg(II), Ag(I), Ni(II), Zn (II) with monocatenated triazenide ligands derived from the 1,3-bis(phenyl)triazene. The coordination of metallic ions by triazenido compounds had been studied in the solid state. We studied the relations that make possible the formation of intramoleculares and intermoleculares interactions, that could show supramolecular arrangements unidimensionais, bidimensional and until three-dimensional. Other eight ligands had been synthesized and we investigated its physical and molecular properties: 1,3-bis (3-nitrophenyl)triazene, 1,3-bis(4-methoxycarbonylphenyl)triazene, 1,3-bis(4-ethoxycarbonylphenyl)triazene, 1,3-bis(4-chlorophenyl)-triazene, 1-(phenyl)-3-(4-nitrophenyl)triazene, 1-(4-chlorophenyl)-3-(4-nitrophenyl)triazene, 1-(2-methoxy-4-nitrophenyl)-3-(2,4-dibromophenyl)triazene and 1-(4-nitrophenyl)-3-(2-pyrimidinyl) triazene. We used techniques of Infrared Absorption Spectroscopy, Spectrometry of Nuclear Magnetic Resonance, Melting Point and Elementary Analysis CHN in this study. The variety in the geometry of coordination of the 1,3-bis(2-methoxy-4-nitrophenyl)triazene can be used to depicted its versatility to form complexes with many metallic ions, beyond presenting a variety of chemical and spectroscopic properties. The complexes {Cu[CH3O(NO2)C6H3NNNC6H3(NO2)OCH3]}4(CH3CN)4 (1), {Cu[CH3O(NO2)C6H3NNNC6H3(NO2)OCH3(C5H5N)2(N3)]}(3) and {Cu[CH3O(O2N)C6H3NNNC6H3(NO2)OCH3-(C5H5N)2(CH3COO)]} (4), using the copper ion (I and II) had been characterized by Spectroscopy of Electronic Paramagnetic Resonance, Electronic and Electrochemical Spectroscopy. All these complexes of Cu (II) had presented interesting magnetic and electrochemical properties.Este trabalho apresenta a síntese e a investigação da estrutura cristalina e molecular do préligante 1,3-bis(2-metoxi-4-nitrofenil)triazeno etanol e de dezessete novos complexos mononucleares e binucleares de Cu(I), Cu(II), Tl(I), Hg(II), Ag(I), Ni(II), Zn(II) com ligantes triazenídicos monocatenados derivados do 1,3-bis(fenil)triazeno. Estudou-se compostos triazenídicos coordenados a íons metálicos em estado sólido, avaliando-se as interações que possibilitam a formação de ligações não-clássicas intra e intermoleculares, resultando os arranjos supramoleculares unidimensionais, bidimensionais e até tridimensionais. Outros oito pré-ligantes foram sintetizados e investigados as suas propriedades físicas e moleculares: 1,3-bis(3-nitrofenil)triazeno, 1,3-bis(4-metoxicarbonilfenil)triazeno, 1,3-bis(4-etoxicarbonilfenil)-triazeno, 1,3-bis(4-clorofenil)triazeno, 1-(fenil)-3-(4-nitrofenil)triazeno, 1-(4-clorofenil)-3-(4-nitrofenil)triazeno, 1-(2-metoxi-4-nitrofenil)-3-(2,4-dibromofenil)triazeno e 1-(4-nitrofenil)-3-(2-pirimidinil)triazeno; utilizando técnicas de Espectroscopia de Infravermelho, Espectrometria de Ressonância Magnética Nuclear de Prótons, Ponto de Fusão e Análise Elementar CHN. A variedade de modo de coordenação que o pré-ligante 1,3-bis(2-metoxi-4-nitrofenil)triazeno pode exemplificar, destaca-se pela sua versatilidade de formar complexos com diversos íons metálicos, além de apresentar uma gama de propriedades químicas e espectroscópicas. Os complexos {Cu[CH3O(NO2)C6H3NNNC6H3(NO2)OCH3]}4(CH3CN)4 (1), {Cu[CH3O(NO2)C6H3N-NNC6H3(NO2)OCH3(C5H5N)2(N3)]} (3) e {Cu[CH3O(O2N)C6H3NNNC6H3(NO2)OCH3(C5H5N)2(CH3COO)]} (4) envolvendo o íon de cobre (I e II) foram caracterizados por Espectroscopia de Ressonância Paramagnética Eletrônica, Espectroscopia Eletrônica e Eletroquímica. Todos estes complexos de Cu(II) apresentaram interessantes propriedades magnéticas e eletroquímicas.Coordenação de Aperfeiçoamento de Pessoal de Nível Superiorapplication/pdfporUniversidade Federal de Santa MariaPrograma de Pós-Graduação em QuímicaUFSMBRQuímicaTriazenoComplexos triazenidosDifração de raios-XTriazeneTriazenide complexesX-ray diffractionCNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICAAvaliação da auto-associação molecular de complexos metálicos com ligantes triazenidos derivados do 1,3-bis(fenil)triazenoEvaluation of the molecular autoassociation of metallic complexes with triazenide derived from 1,3-bis (phenyl)triazeneinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesisHörner, Manfredohttp://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4783542Z5Gushikem, Yoshitakahttp://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4788951T6Casagrande Junior, Osvaldo de Lazarohttp://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4782578H1Nakagaki, Shirleyhttp://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4793532Z5Fenner, Hertonhttp://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4785474Z5http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4718935U9Villis, Paulo Cesar Mendes1006000000004003003003003003003007e7796b1-053d-4bbe-8e62-e769f0da5cea0573347b-d4e3-4752-8cde-6a9bb098ae9c5a5eaffd-0399-48e3-a2f0-2913cc22f5eee3814618-6623-47f2-aa82-43758306c30fed641ce8-22d0-4114-a7a1-e5e9c6d4dbe4c032f384-d82f-4f78-a069-dcf4471c7f5dinfo:eu-repo/semantics/openAccessreponame:Biblioteca Digital de Teses e Dissertações do UFSMinstname:Universidade Federal de Santa Maria (UFSM)instacron:UFSMORIGINALPAULO VILLIS 1.pdfapplication/pdf14090056http://repositorio.ufsm.br/bitstream/1/4141/1/PAULO%20VILLIS%201.pdf117884e34ad1b91a11f7b284c86a8e2cMD51PAULO VILLIS 2.pdfPAULO VILLIS 2.pdfapplication/pdf12688408http://repositorio.ufsm.br/bitstream/1/4141/4/PAULO%20VILLIS%202.pdfeb65b8cb8dcab0e5708e8353e87881f8MD54PAULO VILLIS 3.pdfPAULO VILLIS 3.pdfapplication/pdf13559738http://repositorio.ufsm.br/bitstream/1/4141/5/PAULO%20VILLIS%203.pdf8e239b430869cc3be8d7976225a9ef02MD55TEXTPAULO VILLIS 1.pdf.txtPAULO VILLIS 1.pdf.txtExtracted texttext/plain201313http://repositorio.ufsm.br/bitstream/1/4141/2/PAULO%20VILLIS%201.pdf.txt067d5c1446167aeecee8466f711359d9MD52PAULO VILLIS 2.pdf.txtPAULO VILLIS 2.pdf.txtExtracted texttext/plain157426http://repositorio.ufsm.br/bitstream/1/4141/6/PAULO%20VILLIS%202.pdf.txtf38482a880cdfe113a7c646428ca3b7fMD56PAULO VILLIS 3.pdf.txtPAULO VILLIS 3.pdf.txtExtracted texttext/plain144209http://repositorio.ufsm.br/bitstream/1/4141/8/PAULO%20VILLIS%203.pdf.txt155dec8636bb128cfd672ac3ae12ea50MD58THUMBNAILPAULO VILLIS 1.pdf.jpgPAULO VILLIS 1.pdf.jpgIM Thumbnailimage/jpeg5980http://repositorio.ufsm.br/bitstream/1/4141/3/PAULO%20VILLIS%201.pdf.jpga70f62e2e203d5ff772635a99cb3a618MD53PAULO VILLIS 2.pdf.jpgPAULO VILLIS 2.pdf.jpgIM Thumbnailimage/jpeg3273http://repositorio.ufsm.br/bitstream/1/4141/7/PAULO%20VILLIS%202.pdf.jpg3728df2069be65084572136c88648eb5MD57PAULO VILLIS 3.pdf.jpgPAULO VILLIS 3.pdf.jpgIM Thumbnailimage/jpeg6815http://repositorio.ufsm.br/bitstream/1/4141/9/PAULO%20VILLIS%203.pdf.jpge5a16798d9de273587532f0caef10a88MD591/41412022-06-27 12:20:38.188oai:repositorio.ufsm.br:1/4141Biblioteca Digital de Teses e Dissertaçõeshttps://repositorio.ufsm.br/ONGhttps://repositorio.ufsm.br/oai/requestatendimento.sib@ufsm.br||tedebc@gmail.comopendoar:2022-06-27T15:20:38Biblioteca Digital de Teses e Dissertações do UFSM - Universidade Federal de Santa Maria (UFSM)false |
dc.title.por.fl_str_mv |
Avaliação da auto-associação molecular de complexos metálicos com ligantes triazenidos derivados do 1,3-bis(fenil)triazeno |
dc.title.alternative.eng.fl_str_mv |
Evaluation of the molecular autoassociation of metallic complexes with triazenide derived from 1,3-bis (phenyl)triazene |
title |
Avaliação da auto-associação molecular de complexos metálicos com ligantes triazenidos derivados do 1,3-bis(fenil)triazeno |
spellingShingle |
Avaliação da auto-associação molecular de complexos metálicos com ligantes triazenidos derivados do 1,3-bis(fenil)triazeno Villis, Paulo Cesar Mendes Triazeno Complexos triazenidos Difração de raios-X Triazene Triazenide complexes X-ray diffraction CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA |
title_short |
Avaliação da auto-associação molecular de complexos metálicos com ligantes triazenidos derivados do 1,3-bis(fenil)triazeno |
title_full |
Avaliação da auto-associação molecular de complexos metálicos com ligantes triazenidos derivados do 1,3-bis(fenil)triazeno |
title_fullStr |
Avaliação da auto-associação molecular de complexos metálicos com ligantes triazenidos derivados do 1,3-bis(fenil)triazeno |
title_full_unstemmed |
Avaliação da auto-associação molecular de complexos metálicos com ligantes triazenidos derivados do 1,3-bis(fenil)triazeno |
title_sort |
Avaliação da auto-associação molecular de complexos metálicos com ligantes triazenidos derivados do 1,3-bis(fenil)triazeno |
author |
Villis, Paulo Cesar Mendes |
author_facet |
Villis, Paulo Cesar Mendes |
author_role |
author |
dc.contributor.advisor1.fl_str_mv |
Hörner, Manfredo |
dc.contributor.advisor1Lattes.fl_str_mv |
http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4783542Z5 |
dc.contributor.referee1.fl_str_mv |
Gushikem, Yoshitaka |
dc.contributor.referee1Lattes.fl_str_mv |
http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4788951T6 |
dc.contributor.referee2.fl_str_mv |
Casagrande Junior, Osvaldo de Lazaro |
dc.contributor.referee2Lattes.fl_str_mv |
http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4782578H1 |
dc.contributor.referee3.fl_str_mv |
Nakagaki, Shirley |
dc.contributor.referee3Lattes.fl_str_mv |
http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4793532Z5 |
dc.contributor.referee4.fl_str_mv |
Fenner, Herton |
dc.contributor.referee4Lattes.fl_str_mv |
http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4785474Z5 |
dc.contributor.authorLattes.fl_str_mv |
http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4718935U9 |
dc.contributor.author.fl_str_mv |
Villis, Paulo Cesar Mendes |
contributor_str_mv |
Hörner, Manfredo Gushikem, Yoshitaka Casagrande Junior, Osvaldo de Lazaro Nakagaki, Shirley Fenner, Herton |
dc.subject.por.fl_str_mv |
Triazeno Complexos triazenidos Difração de raios-X |
topic |
Triazeno Complexos triazenidos Difração de raios-X Triazene Triazenide complexes X-ray diffraction CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA |
dc.subject.eng.fl_str_mv |
Triazene Triazenide complexes X-ray diffraction |
dc.subject.cnpq.fl_str_mv |
CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA |
description |
This work presents the synthesis and the investigation of the crystalline and molecular structure of 1,3-bis(2-methoxy-4-nitrophenyl)triazene ethanol and seventeen new mononuclear or binuclear complexes of Cu(I), Cu(II), Tl(I), Hg(II), Ag(I), Ni(II), Zn (II) with monocatenated triazenide ligands derived from the 1,3-bis(phenyl)triazene. The coordination of metallic ions by triazenido compounds had been studied in the solid state. We studied the relations that make possible the formation of intramoleculares and intermoleculares interactions, that could show supramolecular arrangements unidimensionais, bidimensional and until three-dimensional. Other eight ligands had been synthesized and we investigated its physical and molecular properties: 1,3-bis (3-nitrophenyl)triazene, 1,3-bis(4-methoxycarbonylphenyl)triazene, 1,3-bis(4-ethoxycarbonylphenyl)triazene, 1,3-bis(4-chlorophenyl)-triazene, 1-(phenyl)-3-(4-nitrophenyl)triazene, 1-(4-chlorophenyl)-3-(4-nitrophenyl)triazene, 1-(2-methoxy-4-nitrophenyl)-3-(2,4-dibromophenyl)triazene and 1-(4-nitrophenyl)-3-(2-pyrimidinyl) triazene. We used techniques of Infrared Absorption Spectroscopy, Spectrometry of Nuclear Magnetic Resonance, Melting Point and Elementary Analysis CHN in this study. The variety in the geometry of coordination of the 1,3-bis(2-methoxy-4-nitrophenyl)triazene can be used to depicted its versatility to form complexes with many metallic ions, beyond presenting a variety of chemical and spectroscopic properties. The complexes {Cu[CH3O(NO2)C6H3NNNC6H3(NO2)OCH3]}4(CH3CN)4 (1), {Cu[CH3O(NO2)C6H3NNNC6H3(NO2)OCH3(C5H5N)2(N3)]}(3) and {Cu[CH3O(O2N)C6H3NNNC6H3(NO2)OCH3-(C5H5N)2(CH3COO)]} (4), using the copper ion (I and II) had been characterized by Spectroscopy of Electronic Paramagnetic Resonance, Electronic and Electrochemical Spectroscopy. All these complexes of Cu (II) had presented interesting magnetic and electrochemical properties. |
publishDate |
2007 |
dc.date.issued.fl_str_mv |
2007-09-13 |
dc.date.accessioned.fl_str_mv |
2017-05-22 |
dc.date.available.fl_str_mv |
2017-05-22 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/doctoralThesis |
format |
doctoralThesis |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
VILLIS, Paulo Cesar Mendes. Evaluation of the molecular autoassociation of metallic complexes with triazenide derived from 1,3-bis (phenyl)triazene. 2007. 370 f. Tese (Doutorado em Química) - Universidade Federal de Santa Maria, Santa Maria, 2007. |
dc.identifier.uri.fl_str_mv |
http://repositorio.ufsm.br/handle/1/4141 |
identifier_str_mv |
VILLIS, Paulo Cesar Mendes. Evaluation of the molecular autoassociation of metallic complexes with triazenide derived from 1,3-bis (phenyl)triazene. 2007. 370 f. Tese (Doutorado em Química) - Universidade Federal de Santa Maria, Santa Maria, 2007. |
url |
http://repositorio.ufsm.br/handle/1/4141 |
dc.language.iso.fl_str_mv |
por |
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por |
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100600000000 |
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400 300 300 300 300 300 300 |
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info:eu-repo/semantics/openAccess |
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openAccess |
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application/pdf |
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Universidade Federal de Santa Maria |
dc.publisher.program.fl_str_mv |
Programa de Pós-Graduação em Química |
dc.publisher.initials.fl_str_mv |
UFSM |
dc.publisher.country.fl_str_mv |
BR |
dc.publisher.department.fl_str_mv |
Química |
publisher.none.fl_str_mv |
Universidade Federal de Santa Maria |
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