Nanostructured hydrocerussite compound (Pb 3 (CO 3) 2 (OH) 2) prepared by laser ablation technique in liquid environment
Autor(a) principal: | |
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Data de Publicação: | 2014 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | LOCUS Repositório Institucional da UFV |
Texto Completo: | https://doi.org/10.1016/j.materresbull.2013.08.030 http://www.locus.ufv.br/handle/123456789/22508 |
Resumo: | This article presents a chemical bottom-up synthesis of highly crystalline and nanostructured hydrocerussite (Pb3(CO3)2(OH)2) with hexagonal morphology prepared by laser ablation in liquid. The results demonstrate that is possible to use laser ablation in liquid to prepare complex chemical compounds. The experiment consisted of a high power second harmonic of an Nd:YAG laser incidence on the surface of a Pb target immersed in primary alcohols. Three different values of fluency and four different primary alcohols were used in order to investigate the influence of fluency delivered to the target surface and the chemical composition of the liquid environment on the properties of the prepared materials. Crystalline and nanostructured hexagonal particles of hydrocerussite, with average widths of 1.0 ± 0.3 μm and average thickness of 80 ± 20 nm, were obtained when laser ablation was done in methanol and ethanol whereas hydrocerussite and metallic lead were obtained when 1-propanol or 1-butanol were used. Additionally, it was shown that the values of the laser fluency used in this study do not modify the sample morphology and composition. In order to explain the observed results a photochemical reaction model induced by laser ablation of a metallic Pb surface immersed in alcohol solution is presented. |
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Felix, J. F.Cunha, D. L. daPereira, G. F. C.Aguiar, J. AlbinoAzevedo, W. M. de2018-11-08T17:26:55Z2018-11-08T17:26:55Z2014-0100255408https://doi.org/10.1016/j.materresbull.2013.08.030http://www.locus.ufv.br/handle/123456789/22508This article presents a chemical bottom-up synthesis of highly crystalline and nanostructured hydrocerussite (Pb3(CO3)2(OH)2) with hexagonal morphology prepared by laser ablation in liquid. The results demonstrate that is possible to use laser ablation in liquid to prepare complex chemical compounds. The experiment consisted of a high power second harmonic of an Nd:YAG laser incidence on the surface of a Pb target immersed in primary alcohols. Three different values of fluency and four different primary alcohols were used in order to investigate the influence of fluency delivered to the target surface and the chemical composition of the liquid environment on the properties of the prepared materials. Crystalline and nanostructured hexagonal particles of hydrocerussite, with average widths of 1.0 ± 0.3 μm and average thickness of 80 ± 20 nm, were obtained when laser ablation was done in methanol and ethanol whereas hydrocerussite and metallic lead were obtained when 1-propanol or 1-butanol were used. Additionally, it was shown that the values of the laser fluency used in this study do not modify the sample morphology and composition. In order to explain the observed results a photochemical reaction model induced by laser ablation of a metallic Pb surface immersed in alcohol solution is presented.engMaterials Research BulletinVolume 49, Pages 172- 175, January 20142013 Elsevier Ltd. All rights reserved.info:eu-repo/semantics/openAccessA. Inorganic compoundA. NanostructuresB. Chemical synthesisC. X-ray diffractionD. MicrostructureNanostructured hydrocerussite compound (Pb 3 (CO 3) 2 (OH) 2) prepared by laser ablation technique in liquid environmentinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfreponame:LOCUS Repositório Institucional da UFVinstname:Universidade Federal de Viçosa (UFV)instacron:UFVORIGINALartigo.pdfartigo.pdftexto completoapplication/pdf1542954https://locus.ufv.br//bitstream/123456789/22508/1/artigo.pdf403cac40daf655abd13c36211d5e3133MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://locus.ufv.br//bitstream/123456789/22508/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52123456789/225082018-11-08 14:46:15.737oai:locus.ufv.br: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Repositório InstitucionalPUBhttps://www.locus.ufv.br/oai/requestfabiojreis@ufv.bropendoar:21452018-11-08T17:46:15LOCUS Repositório Institucional da UFV - Universidade Federal de Viçosa (UFV)false |
dc.title.en.fl_str_mv |
Nanostructured hydrocerussite compound (Pb 3 (CO 3) 2 (OH) 2) prepared by laser ablation technique in liquid environment |
title |
Nanostructured hydrocerussite compound (Pb 3 (CO 3) 2 (OH) 2) prepared by laser ablation technique in liquid environment |
spellingShingle |
Nanostructured hydrocerussite compound (Pb 3 (CO 3) 2 (OH) 2) prepared by laser ablation technique in liquid environment Felix, J. F. A. Inorganic compound A. Nanostructures B. Chemical synthesis C. X-ray diffraction D. Microstructure |
title_short |
Nanostructured hydrocerussite compound (Pb 3 (CO 3) 2 (OH) 2) prepared by laser ablation technique in liquid environment |
title_full |
Nanostructured hydrocerussite compound (Pb 3 (CO 3) 2 (OH) 2) prepared by laser ablation technique in liquid environment |
title_fullStr |
Nanostructured hydrocerussite compound (Pb 3 (CO 3) 2 (OH) 2) prepared by laser ablation technique in liquid environment |
title_full_unstemmed |
Nanostructured hydrocerussite compound (Pb 3 (CO 3) 2 (OH) 2) prepared by laser ablation technique in liquid environment |
title_sort |
Nanostructured hydrocerussite compound (Pb 3 (CO 3) 2 (OH) 2) prepared by laser ablation technique in liquid environment |
author |
Felix, J. F. |
author_facet |
Felix, J. F. Cunha, D. L. da Pereira, G. F. C. Aguiar, J. Albino Azevedo, W. M. de |
author_role |
author |
author2 |
Cunha, D. L. da Pereira, G. F. C. Aguiar, J. Albino Azevedo, W. M. de |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Felix, J. F. Cunha, D. L. da Pereira, G. F. C. Aguiar, J. Albino Azevedo, W. M. de |
dc.subject.pt-BR.fl_str_mv |
A. Inorganic compound A. Nanostructures B. Chemical synthesis C. X-ray diffraction D. Microstructure |
topic |
A. Inorganic compound A. Nanostructures B. Chemical synthesis C. X-ray diffraction D. Microstructure |
description |
This article presents a chemical bottom-up synthesis of highly crystalline and nanostructured hydrocerussite (Pb3(CO3)2(OH)2) with hexagonal morphology prepared by laser ablation in liquid. The results demonstrate that is possible to use laser ablation in liquid to prepare complex chemical compounds. The experiment consisted of a high power second harmonic of an Nd:YAG laser incidence on the surface of a Pb target immersed in primary alcohols. Three different values of fluency and four different primary alcohols were used in order to investigate the influence of fluency delivered to the target surface and the chemical composition of the liquid environment on the properties of the prepared materials. Crystalline and nanostructured hexagonal particles of hydrocerussite, with average widths of 1.0 ± 0.3 μm and average thickness of 80 ± 20 nm, were obtained when laser ablation was done in methanol and ethanol whereas hydrocerussite and metallic lead were obtained when 1-propanol or 1-butanol were used. Additionally, it was shown that the values of the laser fluency used in this study do not modify the sample morphology and composition. In order to explain the observed results a photochemical reaction model induced by laser ablation of a metallic Pb surface immersed in alcohol solution is presented. |
publishDate |
2014 |
dc.date.issued.fl_str_mv |
2014-01 |
dc.date.accessioned.fl_str_mv |
2018-11-08T17:26:55Z |
dc.date.available.fl_str_mv |
2018-11-08T17:26:55Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
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info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://doi.org/10.1016/j.materresbull.2013.08.030 http://www.locus.ufv.br/handle/123456789/22508 |
dc.identifier.issn.none.fl_str_mv |
00255408 |
identifier_str_mv |
00255408 |
url |
https://doi.org/10.1016/j.materresbull.2013.08.030 http://www.locus.ufv.br/handle/123456789/22508 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.ispartofseries.pt-BR.fl_str_mv |
Volume 49, Pages 172- 175, January 2014 |
dc.rights.driver.fl_str_mv |
2013 Elsevier Ltd. All rights reserved. info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
2013 Elsevier Ltd. All rights reserved. |
eu_rights_str_mv |
openAccess |
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dc.publisher.none.fl_str_mv |
Materials Research Bulletin |
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Materials Research Bulletin |
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LOCUS Repositório Institucional da UFV |
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LOCUS Repositório Institucional da UFV |
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