Optimization of the production of ethyl esters by ultrasound assisted reaction of soybean oil and ethanol
Autor(a) principal: | |
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Data de Publicação: | 2009 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Brazilian Journal of Chemical Engineering |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322009000200013 |
Resumo: | Biodiesel is a renewable liquid fuel that can be produced by a transesterification reaction between a vegetable oil and an alcohol. This paper evaluates and optimizes the production of ethyl esters (biodiesel) from soybean oil and ethanol. The reaction was carried out by applying ultrasound under atmospheric pressure and ambient temperature. Response surface methodology was used to evaluate the influence of alcohol to oil molar ratio and catalyst concentration on the yield of conversion of soybean oil into ethyl esters. The process resulted in a maximum yield of 91.8% after 30 minutes of reaction. The process variables alcohol to oil ratio and catalyst to oil ratio were statistically significant regarding the yield of ethyl esters. The optimal operating condition was obtained applying an alcohol to oil molar ratio of 10.2 and a catalyst to oil weight ratio of 0.0035. |
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Brazilian Journal of Chemical Engineering |
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Optimization of the production of ethyl esters by ultrasound assisted reaction of soybean oil and ethanolEthyl estersUltrasoundSoybean oilTransesterificationBiodiesel is a renewable liquid fuel that can be produced by a transesterification reaction between a vegetable oil and an alcohol. This paper evaluates and optimizes the production of ethyl esters (biodiesel) from soybean oil and ethanol. The reaction was carried out by applying ultrasound under atmospheric pressure and ambient temperature. Response surface methodology was used to evaluate the influence of alcohol to oil molar ratio and catalyst concentration on the yield of conversion of soybean oil into ethyl esters. The process resulted in a maximum yield of 91.8% after 30 minutes of reaction. The process variables alcohol to oil ratio and catalyst to oil ratio were statistically significant regarding the yield of ethyl esters. The optimal operating condition was obtained applying an alcohol to oil molar ratio of 10.2 and a catalyst to oil weight ratio of 0.0035.Brazilian Society of Chemical Engineering2009-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322009000200013Brazilian Journal of Chemical Engineering v.26 n.2 2009reponame:Brazilian Journal of Chemical Engineeringinstname:Associação Brasileira de Engenharia Química (ABEQ)instacron:ABEQ10.1590/S0104-66322009000200013info:eu-repo/semantics/openAccessRodrigues,S.Mazzone,L. C. A.Santos,F. F. P.Cruz,M. G. A.Fernandes,F. A. N.eng2009-06-23T00:00:00Zoai:scielo:S0104-66322009000200013Revistahttps://www.scielo.br/j/bjce/https://old.scielo.br/oai/scielo-oai.phprgiudici@usp.br||rgiudici@usp.br1678-43830104-6632opendoar:2009-06-23T00:00Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ)false |
dc.title.none.fl_str_mv |
Optimization of the production of ethyl esters by ultrasound assisted reaction of soybean oil and ethanol |
title |
Optimization of the production of ethyl esters by ultrasound assisted reaction of soybean oil and ethanol |
spellingShingle |
Optimization of the production of ethyl esters by ultrasound assisted reaction of soybean oil and ethanol Rodrigues,S. Ethyl esters Ultrasound Soybean oil Transesterification |
title_short |
Optimization of the production of ethyl esters by ultrasound assisted reaction of soybean oil and ethanol |
title_full |
Optimization of the production of ethyl esters by ultrasound assisted reaction of soybean oil and ethanol |
title_fullStr |
Optimization of the production of ethyl esters by ultrasound assisted reaction of soybean oil and ethanol |
title_full_unstemmed |
Optimization of the production of ethyl esters by ultrasound assisted reaction of soybean oil and ethanol |
title_sort |
Optimization of the production of ethyl esters by ultrasound assisted reaction of soybean oil and ethanol |
author |
Rodrigues,S. |
author_facet |
Rodrigues,S. Mazzone,L. C. A. Santos,F. F. P. Cruz,M. G. A. Fernandes,F. A. N. |
author_role |
author |
author2 |
Mazzone,L. C. A. Santos,F. F. P. Cruz,M. G. A. Fernandes,F. A. N. |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Rodrigues,S. Mazzone,L. C. A. Santos,F. F. P. Cruz,M. G. A. Fernandes,F. A. N. |
dc.subject.por.fl_str_mv |
Ethyl esters Ultrasound Soybean oil Transesterification |
topic |
Ethyl esters Ultrasound Soybean oil Transesterification |
description |
Biodiesel is a renewable liquid fuel that can be produced by a transesterification reaction between a vegetable oil and an alcohol. This paper evaluates and optimizes the production of ethyl esters (biodiesel) from soybean oil and ethanol. The reaction was carried out by applying ultrasound under atmospheric pressure and ambient temperature. Response surface methodology was used to evaluate the influence of alcohol to oil molar ratio and catalyst concentration on the yield of conversion of soybean oil into ethyl esters. The process resulted in a maximum yield of 91.8% after 30 minutes of reaction. The process variables alcohol to oil ratio and catalyst to oil ratio were statistically significant regarding the yield of ethyl esters. The optimal operating condition was obtained applying an alcohol to oil molar ratio of 10.2 and a catalyst to oil weight ratio of 0.0035. |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-06-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322009000200013 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322009000200013 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0104-66322009000200013 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Brazilian Society of Chemical Engineering |
publisher.none.fl_str_mv |
Brazilian Society of Chemical Engineering |
dc.source.none.fl_str_mv |
Brazilian Journal of Chemical Engineering v.26 n.2 2009 reponame:Brazilian Journal of Chemical Engineering instname:Associação Brasileira de Engenharia Química (ABEQ) instacron:ABEQ |
instname_str |
Associação Brasileira de Engenharia Química (ABEQ) |
instacron_str |
ABEQ |
institution |
ABEQ |
reponame_str |
Brazilian Journal of Chemical Engineering |
collection |
Brazilian Journal of Chemical Engineering |
repository.name.fl_str_mv |
Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ) |
repository.mail.fl_str_mv |
rgiudici@usp.br||rgiudici@usp.br |
_version_ |
1754213172764475392 |