10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine

Detalhes bibliográficos
Autor(a) principal: Nguyen,Loc Tan
Data de Publicação: 2021
Outros Autores: Pham,Hung Quang, Nguyen,Duc Anh Song, Nguyen,Luan Thanh, Huynh,Ky Phuong Ha, Le Tran,Hai, Mai,Phong Thanh, Nguyen,Ha Tran, Nguyen,Le-Thu Thi, Truong,Thuy Thu
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Polímeros (São Carlos. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282021000100402
Resumo: Abstract The UV light-mediated metal-free polymerizations of 4-vinylpyridine (4VP) have been successfully performed by using 10-(pyren-1-yl)-10H-phenothiazine (PPTh) and pyrene as photocatalysts. The preparation of narrow polydispersity poly (4-vinyl pyridine) (P4VP) with high conversions was enabled in both protic as well as unprotic reaction media at ambient temperature. Additionally, copolymerizations of 4VP with acrylate and methacrylate monomers were also demonstrated, affording metal-free copolymer products.
id ABPO-1_7deea547fe4b27816725274aab669784
oai_identifier_str oai:scielo:S0104-14282021000100402
network_acronym_str ABPO-1
network_name_str Polímeros (São Carlos. Online)
repository_id_str
spelling 10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridineorganic photocatalystmetal-free atom transfer radical polymerization4-vinylpyridinepyreneAbstract The UV light-mediated metal-free polymerizations of 4-vinylpyridine (4VP) have been successfully performed by using 10-(pyren-1-yl)-10H-phenothiazine (PPTh) and pyrene as photocatalysts. The preparation of narrow polydispersity poly (4-vinyl pyridine) (P4VP) with high conversions was enabled in both protic as well as unprotic reaction media at ambient temperature. Additionally, copolymerizations of 4VP with acrylate and methacrylate monomers were also demonstrated, affording metal-free copolymer products.Associação Brasileira de Polímeros2021-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282021000100402Polímeros v.31 n.1 2021reponame:Polímeros (São Carlos. Online)instname:Associação Brasileira de Polímeros (ABPol)instacron:ABPO10.1590/0104-1428.08120info:eu-repo/semantics/openAccessNguyen,Loc TanPham,Hung QuangNguyen,Duc Anh SongNguyen,Luan ThanhHuynh,Ky Phuong HaLe Tran,HaiMai,Phong ThanhNguyen,Ha TranNguyen,Le-Thu ThiTruong,Thuy Thueng2021-05-07T00:00:00Zoai:scielo:S0104-14282021000100402Revistahttp://www.scielo.br/pohttps://old.scielo.br/oai/scielo-oai.php||revista@abpol.org.br1678-51690104-1428opendoar:2021-05-07T00:00Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol)false
dc.title.none.fl_str_mv 10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine
title 10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine
spellingShingle 10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine
Nguyen,Loc Tan
organic photocatalyst
metal-free atom transfer radical polymerization
4-vinylpyridine
pyrene
title_short 10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine
title_full 10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine
title_fullStr 10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine
title_full_unstemmed 10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine
title_sort 10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine
author Nguyen,Loc Tan
author_facet Nguyen,Loc Tan
Pham,Hung Quang
Nguyen,Duc Anh Song
Nguyen,Luan Thanh
Huynh,Ky Phuong Ha
Le Tran,Hai
Mai,Phong Thanh
Nguyen,Ha Tran
Nguyen,Le-Thu Thi
Truong,Thuy Thu
author_role author
author2 Pham,Hung Quang
Nguyen,Duc Anh Song
Nguyen,Luan Thanh
Huynh,Ky Phuong Ha
Le Tran,Hai
Mai,Phong Thanh
Nguyen,Ha Tran
Nguyen,Le-Thu Thi
Truong,Thuy Thu
author2_role author
author
author
author
author
author
author
author
author
dc.contributor.author.fl_str_mv Nguyen,Loc Tan
Pham,Hung Quang
Nguyen,Duc Anh Song
Nguyen,Luan Thanh
Huynh,Ky Phuong Ha
Le Tran,Hai
Mai,Phong Thanh
Nguyen,Ha Tran
Nguyen,Le-Thu Thi
Truong,Thuy Thu
dc.subject.por.fl_str_mv organic photocatalyst
metal-free atom transfer radical polymerization
4-vinylpyridine
pyrene
topic organic photocatalyst
metal-free atom transfer radical polymerization
4-vinylpyridine
pyrene
description Abstract The UV light-mediated metal-free polymerizations of 4-vinylpyridine (4VP) have been successfully performed by using 10-(pyren-1-yl)-10H-phenothiazine (PPTh) and pyrene as photocatalysts. The preparation of narrow polydispersity poly (4-vinyl pyridine) (P4VP) with high conversions was enabled in both protic as well as unprotic reaction media at ambient temperature. Additionally, copolymerizations of 4VP with acrylate and methacrylate monomers were also demonstrated, affording metal-free copolymer products.
publishDate 2021
dc.date.none.fl_str_mv 2021-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282021000100402
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282021000100402
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/0104-1428.08120
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Associação Brasileira de Polímeros
publisher.none.fl_str_mv Associação Brasileira de Polímeros
dc.source.none.fl_str_mv Polímeros v.31 n.1 2021
reponame:Polímeros (São Carlos. Online)
instname:Associação Brasileira de Polímeros (ABPol)
instacron:ABPO
instname_str Associação Brasileira de Polímeros (ABPol)
instacron_str ABPO
institution ABPO
reponame_str Polímeros (São Carlos. Online)
collection Polímeros (São Carlos. Online)
repository.name.fl_str_mv Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol)
repository.mail.fl_str_mv ||revista@abpol.org.br
_version_ 1754212591302868992