10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine
Autor(a) principal: | |
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Data de Publicação: | 2021 |
Outros Autores: | , , , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Polímeros (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282021000100402 |
Resumo: | Abstract The UV light-mediated metal-free polymerizations of 4-vinylpyridine (4VP) have been successfully performed by using 10-(pyren-1-yl)-10H-phenothiazine (PPTh) and pyrene as photocatalysts. The preparation of narrow polydispersity poly (4-vinyl pyridine) (P4VP) with high conversions was enabled in both protic as well as unprotic reaction media at ambient temperature. Additionally, copolymerizations of 4VP with acrylate and methacrylate monomers were also demonstrated, affording metal-free copolymer products. |
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Polímeros (São Carlos. Online) |
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10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridineorganic photocatalystmetal-free atom transfer radical polymerization4-vinylpyridinepyreneAbstract The UV light-mediated metal-free polymerizations of 4-vinylpyridine (4VP) have been successfully performed by using 10-(pyren-1-yl)-10H-phenothiazine (PPTh) and pyrene as photocatalysts. The preparation of narrow polydispersity poly (4-vinyl pyridine) (P4VP) with high conversions was enabled in both protic as well as unprotic reaction media at ambient temperature. Additionally, copolymerizations of 4VP with acrylate and methacrylate monomers were also demonstrated, affording metal-free copolymer products.Associação Brasileira de Polímeros2021-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282021000100402Polímeros v.31 n.1 2021reponame:Polímeros (São Carlos. Online)instname:Associação Brasileira de Polímeros (ABPol)instacron:ABPO10.1590/0104-1428.08120info:eu-repo/semantics/openAccessNguyen,Loc TanPham,Hung QuangNguyen,Duc Anh SongNguyen,Luan ThanhHuynh,Ky Phuong HaLe Tran,HaiMai,Phong ThanhNguyen,Ha TranNguyen,Le-Thu ThiTruong,Thuy Thueng2021-05-07T00:00:00Zoai:scielo:S0104-14282021000100402Revistahttp://www.scielo.br/pohttps://old.scielo.br/oai/scielo-oai.php||revista@abpol.org.br1678-51690104-1428opendoar:2021-05-07T00:00Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol)false |
dc.title.none.fl_str_mv |
10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine |
title |
10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine |
spellingShingle |
10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine Nguyen,Loc Tan organic photocatalyst metal-free atom transfer radical polymerization 4-vinylpyridine pyrene |
title_short |
10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine |
title_full |
10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine |
title_fullStr |
10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine |
title_full_unstemmed |
10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine |
title_sort |
10-(pyren-1-yl)-10h-phenothiazine and pyrene as organic catalysts for photoinitiated ATRP of 4-vinylpyridine |
author |
Nguyen,Loc Tan |
author_facet |
Nguyen,Loc Tan Pham,Hung Quang Nguyen,Duc Anh Song Nguyen,Luan Thanh Huynh,Ky Phuong Ha Le Tran,Hai Mai,Phong Thanh Nguyen,Ha Tran Nguyen,Le-Thu Thi Truong,Thuy Thu |
author_role |
author |
author2 |
Pham,Hung Quang Nguyen,Duc Anh Song Nguyen,Luan Thanh Huynh,Ky Phuong Ha Le Tran,Hai Mai,Phong Thanh Nguyen,Ha Tran Nguyen,Le-Thu Thi Truong,Thuy Thu |
author2_role |
author author author author author author author author author |
dc.contributor.author.fl_str_mv |
Nguyen,Loc Tan Pham,Hung Quang Nguyen,Duc Anh Song Nguyen,Luan Thanh Huynh,Ky Phuong Ha Le Tran,Hai Mai,Phong Thanh Nguyen,Ha Tran Nguyen,Le-Thu Thi Truong,Thuy Thu |
dc.subject.por.fl_str_mv |
organic photocatalyst metal-free atom transfer radical polymerization 4-vinylpyridine pyrene |
topic |
organic photocatalyst metal-free atom transfer radical polymerization 4-vinylpyridine pyrene |
description |
Abstract The UV light-mediated metal-free polymerizations of 4-vinylpyridine (4VP) have been successfully performed by using 10-(pyren-1-yl)-10H-phenothiazine (PPTh) and pyrene as photocatalysts. The preparation of narrow polydispersity poly (4-vinyl pyridine) (P4VP) with high conversions was enabled in both protic as well as unprotic reaction media at ambient temperature. Additionally, copolymerizations of 4VP with acrylate and methacrylate monomers were also demonstrated, affording metal-free copolymer products. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282021000100402 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282021000100402 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/0104-1428.08120 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Associação Brasileira de Polímeros |
publisher.none.fl_str_mv |
Associação Brasileira de Polímeros |
dc.source.none.fl_str_mv |
Polímeros v.31 n.1 2021 reponame:Polímeros (São Carlos. Online) instname:Associação Brasileira de Polímeros (ABPol) instacron:ABPO |
instname_str |
Associação Brasileira de Polímeros (ABPol) |
instacron_str |
ABPO |
institution |
ABPO |
reponame_str |
Polímeros (São Carlos. Online) |
collection |
Polímeros (São Carlos. Online) |
repository.name.fl_str_mv |
Polímeros (São Carlos. Online) - Associação Brasileira de Polímeros (ABPol) |
repository.mail.fl_str_mv |
||revista@abpol.org.br |
_version_ |
1754212591302868992 |