A photocatalytic cycle for mild oxidation by dioxygen of substrates easily oxidizable by iodine

Detalhes bibliográficos
Autor(a) principal: Figueiredo, Paulo
Data de Publicação: 1988
Outros Autores: Pina, Fernando
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10884/1329
Resumo: A photocatalytic cycle based on the ion pair Co(sep)3+·I− (sep  sepulchrate  1,3,6,8,10,13,16,19-octaazabicyclo[6.6.6] eicosane)), in which substrates easily oxidizable by iodine are oxidized by dioxygen, is described. A direct relation between the ion pair charge transfer band maximum and the one-electron redox potential of the corresponding anion was verified. Possible applications of these cycles, such as energy conversion, are discussed.
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spelling A photocatalytic cycle for mild oxidation by dioxygen of substrates easily oxidizable by iodineA photocatalytic cycle based on the ion pair Co(sep)3+·I− (sep  sepulchrate  1,3,6,8,10,13,16,19-octaazabicyclo[6.6.6] eicosane)), in which substrates easily oxidizable by iodine are oxidized by dioxygen, is described. A direct relation between the ion pair charge transfer band maximum and the one-electron redox potential of the corresponding anion was verified. Possible applications of these cycles, such as energy conversion, are discussed.2018-09-03T21:13:40Z1988-07-01T00:00:00Z1988-07info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleimage/pnghttp://hdl.handle.net/10884/1329engFigueiredo, PauloPina, Fernandoinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-01-04T11:08:03Zoai:repositorio-cientifico.uatlantica.pt:10884/1329Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T01:29:54.163716Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv A photocatalytic cycle for mild oxidation by dioxygen of substrates easily oxidizable by iodine
title A photocatalytic cycle for mild oxidation by dioxygen of substrates easily oxidizable by iodine
spellingShingle A photocatalytic cycle for mild oxidation by dioxygen of substrates easily oxidizable by iodine
Figueiredo, Paulo
title_short A photocatalytic cycle for mild oxidation by dioxygen of substrates easily oxidizable by iodine
title_full A photocatalytic cycle for mild oxidation by dioxygen of substrates easily oxidizable by iodine
title_fullStr A photocatalytic cycle for mild oxidation by dioxygen of substrates easily oxidizable by iodine
title_full_unstemmed A photocatalytic cycle for mild oxidation by dioxygen of substrates easily oxidizable by iodine
title_sort A photocatalytic cycle for mild oxidation by dioxygen of substrates easily oxidizable by iodine
author Figueiredo, Paulo
author_facet Figueiredo, Paulo
Pina, Fernando
author_role author
author2 Pina, Fernando
author2_role author
dc.contributor.author.fl_str_mv Figueiredo, Paulo
Pina, Fernando
description A photocatalytic cycle based on the ion pair Co(sep)3+·I− (sep  sepulchrate  1,3,6,8,10,13,16,19-octaazabicyclo[6.6.6] eicosane)), in which substrates easily oxidizable by iodine are oxidized by dioxygen, is described. A direct relation between the ion pair charge transfer band maximum and the one-electron redox potential of the corresponding anion was verified. Possible applications of these cycles, such as energy conversion, are discussed.
publishDate 1988
dc.date.none.fl_str_mv 1988-07-01T00:00:00Z
1988-07
2018-09-03T21:13:40Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10884/1329
url http://hdl.handle.net/10884/1329
dc.language.iso.fl_str_mv eng
language eng
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eu_rights_str_mv openAccess
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dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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