Conjugated Azomethine Ylides
| Autor(a) principal: | |
|---|---|
| Data de Publicação: | 2006 |
| Tipo de documento: | Artigo |
| Idioma: | eng |
| Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
| Texto Completo: | http://hdl.handle.net/10316/8275 https://doi.org/10.1002/ejoc.200500892 |
Resumo: | The 1,3-dipolar cycloaddition of azomethine ylides is an efficient and versatile tool for the construction of five-membered nitrogen-heterocycles. When the azomethine ylide is conjugated with a double bond or a 1,3-diene moiety, other reactivity pathways are also available, namely 1,5-electrocyclization or 1,7-electrocyclization. The present review is focused on the generation and reactivity of this type of dipoles, which offer general strategies for the formation of five- and seven-membered nitrogen-heterocyclic compounds. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006) |
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Conjugated Azomethine YlidesThe 1,3-dipolar cycloaddition of azomethine ylides is an efficient and versatile tool for the construction of five-membered nitrogen-heterocycles. When the azomethine ylide is conjugated with a double bond or a 1,3-diene moiety, other reactivity pathways are also available, namely 1,5-electrocyclization or 1,7-electrocyclization. The present review is focused on the generation and reactivity of this type of dipoles, which offer general strategies for the formation of five- and seven-membered nitrogen-heterocyclic compounds. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)2006info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://hdl.handle.net/10316/8275http://hdl.handle.net/10316/8275https://doi.org/10.1002/ejoc.200500892engEuropean Journal of Organic Chemistry. 2006:13 (2006) 2873-2888Melo, Teresa M. V. D. Pinho einfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2020-05-25T13:13:00Zoai:estudogeral.uc.pt:10316/8275Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T21:01:11.235147Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
| dc.title.none.fl_str_mv |
Conjugated Azomethine Ylides |
| title |
Conjugated Azomethine Ylides |
| spellingShingle |
Conjugated Azomethine Ylides Melo, Teresa M. V. D. Pinho e |
| title_short |
Conjugated Azomethine Ylides |
| title_full |
Conjugated Azomethine Ylides |
| title_fullStr |
Conjugated Azomethine Ylides |
| title_full_unstemmed |
Conjugated Azomethine Ylides |
| title_sort |
Conjugated Azomethine Ylides |
| author |
Melo, Teresa M. V. D. Pinho e |
| author_facet |
Melo, Teresa M. V. D. Pinho e |
| author_role |
author |
| dc.contributor.author.fl_str_mv |
Melo, Teresa M. V. D. Pinho e |
| description |
The 1,3-dipolar cycloaddition of azomethine ylides is an efficient and versatile tool for the construction of five-membered nitrogen-heterocycles. When the azomethine ylide is conjugated with a double bond or a 1,3-diene moiety, other reactivity pathways are also available, namely 1,5-electrocyclization or 1,7-electrocyclization. The present review is focused on the generation and reactivity of this type of dipoles, which offer general strategies for the formation of five- and seven-membered nitrogen-heterocyclic compounds. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006) |
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2006 |
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2006 |
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info:eu-repo/semantics/publishedVersion |
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info:eu-repo/semantics/article |
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article |
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publishedVersion |
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http://hdl.handle.net/10316/8275 http://hdl.handle.net/10316/8275 https://doi.org/10.1002/ejoc.200500892 |
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http://hdl.handle.net/10316/8275 https://doi.org/10.1002/ejoc.200500892 |
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eng |
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eng |
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European Journal of Organic Chemistry. 2006:13 (2006) 2873-2888 |
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info:eu-repo/semantics/openAccess |
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openAccess |
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