Synthesis, spectroscopy, photophysics and thermal behaviour of stilbene-based triarylamines with dehydroabietic acid methyl ester moieties

Detalhes bibliográficos
Autor(a) principal: Gigante, Bárbara
Data de Publicação: 2009
Outros Autores: Esteves, M. Alexandra, Pires, N., Davies, Matthew L., Douglas, Peter, Fonseca, Sofia M., Burrows, Hugh D., Pina, João, Melo, João Seixas de
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.9/1074
Resumo: Novel stilbene-based triarylamines with dehydroabietic acid methyl ester moieties have been synthesised by palladium catalysed C–N coupling reactions. The presence of the bulky dehydroabietic acid group increases solubility, hinders crystallisation and permits their sublimation while preserving their electronic and optical characteristics. This makes them good candidates for various molecular electronic applications. We report a detailed characterisation of their electrochemical, spectroscopic and photophysical properties. In addition, the thermal stability and behaviour is discussed with reference to the potential for preparation of stable thin films.
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spelling Synthesis, spectroscopy, photophysics and thermal behaviour of stilbene-based triarylamines with dehydroabietic acid methyl ester moietiesNovel stilbene-based triarylamines with dehydroabietic acid methyl ester moieties have been synthesised by palladium catalysed C–N coupling reactions. The presence of the bulky dehydroabietic acid group increases solubility, hinders crystallisation and permits their sublimation while preserving their electronic and optical characteristics. This makes them good candidates for various molecular electronic applications. We report a detailed characterisation of their electrochemical, spectroscopic and photophysical properties. In addition, the thermal stability and behaviour is discussed with reference to the potential for preparation of stable thin films.The Royal Society of Chemistry and the Centre National de la Recherche ScientifiqueRepositório do LNEGGigante, BárbaraEsteves, M. AlexandraPires, N.Davies, Matthew L.Douglas, PeterFonseca, Sofia M.Burrows, Hugh D.Pina, JoãoMelo, João Seixas de2010-11-30T15:13:17Z2009-01-01T00:00:00Z2009-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.9/1074engGigante, B.; Esteves, M. A.; Pires, N.; Davies, M. L.; Douglas, P.; Fonseca, S. M.; Burrows, H. D.; Pina, J.; Melo, J. S. Synthesis, spectroscopy, photophysics and thermal behaviour of stilbene-based triarylamines with dehydroabietic acid methyl ester moieties. In: New Journal of Chemistry, 2009, vol. 33, p. 877-885info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2022-09-06T12:25:28Zoai:repositorio.lneg.pt:10400.9/1074Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T15:33:53.799689Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Synthesis, spectroscopy, photophysics and thermal behaviour of stilbene-based triarylamines with dehydroabietic acid methyl ester moieties
title Synthesis, spectroscopy, photophysics and thermal behaviour of stilbene-based triarylamines with dehydroabietic acid methyl ester moieties
spellingShingle Synthesis, spectroscopy, photophysics and thermal behaviour of stilbene-based triarylamines with dehydroabietic acid methyl ester moieties
Gigante, Bárbara
title_short Synthesis, spectroscopy, photophysics and thermal behaviour of stilbene-based triarylamines with dehydroabietic acid methyl ester moieties
title_full Synthesis, spectroscopy, photophysics and thermal behaviour of stilbene-based triarylamines with dehydroabietic acid methyl ester moieties
title_fullStr Synthesis, spectroscopy, photophysics and thermal behaviour of stilbene-based triarylamines with dehydroabietic acid methyl ester moieties
title_full_unstemmed Synthesis, spectroscopy, photophysics and thermal behaviour of stilbene-based triarylamines with dehydroabietic acid methyl ester moieties
title_sort Synthesis, spectroscopy, photophysics and thermal behaviour of stilbene-based triarylamines with dehydroabietic acid methyl ester moieties
author Gigante, Bárbara
author_facet Gigante, Bárbara
Esteves, M. Alexandra
Pires, N.
Davies, Matthew L.
Douglas, Peter
Fonseca, Sofia M.
Burrows, Hugh D.
Pina, João
Melo, João Seixas de
author_role author
author2 Esteves, M. Alexandra
Pires, N.
Davies, Matthew L.
Douglas, Peter
Fonseca, Sofia M.
Burrows, Hugh D.
Pina, João
Melo, João Seixas de
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Repositório do LNEG
dc.contributor.author.fl_str_mv Gigante, Bárbara
Esteves, M. Alexandra
Pires, N.
Davies, Matthew L.
Douglas, Peter
Fonseca, Sofia M.
Burrows, Hugh D.
Pina, João
Melo, João Seixas de
description Novel stilbene-based triarylamines with dehydroabietic acid methyl ester moieties have been synthesised by palladium catalysed C–N coupling reactions. The presence of the bulky dehydroabietic acid group increases solubility, hinders crystallisation and permits their sublimation while preserving their electronic and optical characteristics. This makes them good candidates for various molecular electronic applications. We report a detailed characterisation of their electrochemical, spectroscopic and photophysical properties. In addition, the thermal stability and behaviour is discussed with reference to the potential for preparation of stable thin films.
publishDate 2009
dc.date.none.fl_str_mv 2009-01-01T00:00:00Z
2009-01-01T00:00:00Z
2010-11-30T15:13:17Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.9/1074
url http://hdl.handle.net/10400.9/1074
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Gigante, B.; Esteves, M. A.; Pires, N.; Davies, M. L.; Douglas, P.; Fonseca, S. M.; Burrows, H. D.; Pina, J.; Melo, J. S. Synthesis, spectroscopy, photophysics and thermal behaviour of stilbene-based triarylamines with dehydroabietic acid methyl ester moieties. In: New Journal of Chemistry, 2009, vol. 33, p. 877-885
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv The Royal Society of Chemistry and the Centre National de la Recherche Scientifique
publisher.none.fl_str_mv The Royal Society of Chemistry and the Centre National de la Recherche Scientifique
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
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repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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