Mild two-step conversion of primary amides to alcohols by reduction of acylimidodicarbonates with sodium borohydride

Detalhes bibliográficos
Autor(a) principal: Ragnarsson, Ulf
Data de Publicação: 2003
Outros Autores: Grehn, Leif, Monteiro, Luís S., Maia, Hernâni Lopes Silva
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/1822/72929
Resumo: Di-tert-butyl acylimidodicarbonates, prepared from primary amides with two equivalents of di-tert-butyl dicarbonate under catalysis by 4-dimethylaminopyridine, readily undergo selective reductive cleavage of their acyl CO-N bonds by NaBH4 to provide the corresponding alcohols in high yields.
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spelling Mild two-step conversion of primary amides to alcohols by reduction of acylimidodicarbonates with sodium borohydrideAlcoholsAmidesCleavagereductionssodium borohydrideScience & TechnologyDi-tert-butyl acylimidodicarbonates, prepared from primary amides with two equivalents of di-tert-butyl dicarbonate under catalysis by 4-dimethylaminopyridine, readily undergo selective reductive cleavage of their acyl CO-N bonds by NaBH4 to provide the corresponding alcohols in high yields.- (undefined)Georg Thieme VerlagUniversidade do MinhoRagnarsson, UlfGrehn, LeifMonteiro, Luís S.Maia, Hernâni Lopes Silva2003-122003-12-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/72929eng0936-52141437-209610.1055/s-2003-42116info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:42:19Zoai:repositorium.sdum.uminho.pt:1822/72929Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T19:39:31.547751Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Mild two-step conversion of primary amides to alcohols by reduction of acylimidodicarbonates with sodium borohydride
title Mild two-step conversion of primary amides to alcohols by reduction of acylimidodicarbonates with sodium borohydride
spellingShingle Mild two-step conversion of primary amides to alcohols by reduction of acylimidodicarbonates with sodium borohydride
Ragnarsson, Ulf
Alcohols
Amides
Cleavage
reductions
sodium borohydride
Science & Technology
title_short Mild two-step conversion of primary amides to alcohols by reduction of acylimidodicarbonates with sodium borohydride
title_full Mild two-step conversion of primary amides to alcohols by reduction of acylimidodicarbonates with sodium borohydride
title_fullStr Mild two-step conversion of primary amides to alcohols by reduction of acylimidodicarbonates with sodium borohydride
title_full_unstemmed Mild two-step conversion of primary amides to alcohols by reduction of acylimidodicarbonates with sodium borohydride
title_sort Mild two-step conversion of primary amides to alcohols by reduction of acylimidodicarbonates with sodium borohydride
author Ragnarsson, Ulf
author_facet Ragnarsson, Ulf
Grehn, Leif
Monteiro, Luís S.
Maia, Hernâni Lopes Silva
author_role author
author2 Grehn, Leif
Monteiro, Luís S.
Maia, Hernâni Lopes Silva
author2_role author
author
author
dc.contributor.none.fl_str_mv Universidade do Minho
dc.contributor.author.fl_str_mv Ragnarsson, Ulf
Grehn, Leif
Monteiro, Luís S.
Maia, Hernâni Lopes Silva
dc.subject.por.fl_str_mv Alcohols
Amides
Cleavage
reductions
sodium borohydride
Science & Technology
topic Alcohols
Amides
Cleavage
reductions
sodium borohydride
Science & Technology
description Di-tert-butyl acylimidodicarbonates, prepared from primary amides with two equivalents of di-tert-butyl dicarbonate under catalysis by 4-dimethylaminopyridine, readily undergo selective reductive cleavage of their acyl CO-N bonds by NaBH4 to provide the corresponding alcohols in high yields.
publishDate 2003
dc.date.none.fl_str_mv 2003-12
2003-12-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1822/72929
url http://hdl.handle.net/1822/72929
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0936-5214
1437-2096
10.1055/s-2003-42116
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Georg Thieme Verlag
publisher.none.fl_str_mv Georg Thieme Verlag
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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