Aggregation and phase equilibria of fluorinated ionic liquids

Detalhes bibliográficos
Autor(a) principal: Vieira, Nicole S. M.
Data de Publicação: 2019
Outros Autores: Bastos, Joana C., Hermida-Merino, Carolina, Pastoriza-Gallego, María J., Rebelo, Luís P. N., Piñeiro, Manuel M., Araújo, João M. M., Pereiro, Ana B.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/90032
Resumo: Grant SFRH/BD/100563/2014. IF/00190/2014 . IF/00210/2014. PTDC/EQU-EQU/29737/2017. PTDC/QEQ-FTT/3289/2014. IF/00210/2014/CP1244/CT0003. UID/QUI/50006/2019. POCI-01-0145-FEDER - 007265.
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spelling Aggregation and phase equilibria of fluorinated ionic liquidsFluorinated ionic liquidsLiquid-liquid phase equilibriaSelf-aggregationSolubilitySurface activityElectronic, Optical and Magnetic MaterialsAtomic and Molecular Physics, and OpticsCondensed Matter PhysicsSpectroscopyPhysical and Theoretical ChemistryMaterials ChemistryGrant SFRH/BD/100563/2014. IF/00190/2014 . IF/00210/2014. PTDC/EQU-EQU/29737/2017. PTDC/QEQ-FTT/3289/2014. IF/00210/2014/CP1244/CT0003. UID/QUI/50006/2019. POCI-01-0145-FEDER - 007265.In this work a specific family of ionic liquids, denominated fluorinated ionic liquids, with fluorine tags equal or longer than four carbon atoms, are fully characterized in order to understand their solubility and self-aggregation in aqueous solutions. The numerous combinations between cations and anions make these compounds a feasible option for the replacement of traditional and toxic surfactants used in the industrial and biomedical field. In this work, the increment of both hydrogenated and fluorinated side chain lengths, the influence of the cation headgroup (imidazolium and cholinium)as well as the difference between perfluorobutanesulfonate and perfluoropentanoate anions were studied. The liquid-liquid phase equilibria of fluorinated ionic liquids based on the perfluorobutanesulfonate anion with water were carried out. The self-aggregation behaviour of the different fluorinated ionic liquids in aqueous solutions was also determined using conductimetric titration, surface tension measurements and transmission electron microscopy. Several thermodynamic and surface parameters were obtained and used to discuss the aggregation process. These novel characterized fluorinated ionic liquids demonstrate an improved surface activity and aggregation behaviour, driven essentially by the increment of both hydrogenated and fluorinated chain lengths.LAQV@REQUIMTEInstituto de Tecnologia Química e Biológica António Xavier (ITQB)DQ - Departamento de QuímicaRUNVieira, Nicole S. M.Bastos, Joana C.Hermida-Merino, CarolinaPastoriza-Gallego, María J.Rebelo, Luís P. N.Piñeiro, Manuel M.Araújo, João M. M.Pereiro, Ana B.2022-03-31T00:31:38Z2019-07-012019-07-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article11application/pdfhttp://hdl.handle.net/10362/90032eng0167-7322PURE: 13081334https://doi.org/10.1016/j.molliq.2019.04.086info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T04:40:09Zoai:run.unl.pt:10362/90032Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:37:07.411836Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Aggregation and phase equilibria of fluorinated ionic liquids
title Aggregation and phase equilibria of fluorinated ionic liquids
spellingShingle Aggregation and phase equilibria of fluorinated ionic liquids
Vieira, Nicole S. M.
Fluorinated ionic liquids
Liquid-liquid phase equilibria
Self-aggregation
Solubility
Surface activity
Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry
Materials Chemistry
title_short Aggregation and phase equilibria of fluorinated ionic liquids
title_full Aggregation and phase equilibria of fluorinated ionic liquids
title_fullStr Aggregation and phase equilibria of fluorinated ionic liquids
title_full_unstemmed Aggregation and phase equilibria of fluorinated ionic liquids
title_sort Aggregation and phase equilibria of fluorinated ionic liquids
author Vieira, Nicole S. M.
author_facet Vieira, Nicole S. M.
Bastos, Joana C.
Hermida-Merino, Carolina
Pastoriza-Gallego, María J.
Rebelo, Luís P. N.
Piñeiro, Manuel M.
Araújo, João M. M.
Pereiro, Ana B.
author_role author
author2 Bastos, Joana C.
Hermida-Merino, Carolina
Pastoriza-Gallego, María J.
Rebelo, Luís P. N.
Piñeiro, Manuel M.
Araújo, João M. M.
Pereiro, Ana B.
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
Instituto de Tecnologia Química e Biológica António Xavier (ITQB)
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Vieira, Nicole S. M.
Bastos, Joana C.
Hermida-Merino, Carolina
Pastoriza-Gallego, María J.
Rebelo, Luís P. N.
Piñeiro, Manuel M.
Araújo, João M. M.
Pereiro, Ana B.
dc.subject.por.fl_str_mv Fluorinated ionic liquids
Liquid-liquid phase equilibria
Self-aggregation
Solubility
Surface activity
Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry
Materials Chemistry
topic Fluorinated ionic liquids
Liquid-liquid phase equilibria
Self-aggregation
Solubility
Surface activity
Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry
Materials Chemistry
description Grant SFRH/BD/100563/2014. IF/00190/2014 . IF/00210/2014. PTDC/EQU-EQU/29737/2017. PTDC/QEQ-FTT/3289/2014. IF/00210/2014/CP1244/CT0003. UID/QUI/50006/2019. POCI-01-0145-FEDER - 007265.
publishDate 2019
dc.date.none.fl_str_mv 2019-07-01
2019-07-01T00:00:00Z
2022-03-31T00:31:38Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/90032
url http://hdl.handle.net/10362/90032
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0167-7322
PURE: 13081334
https://doi.org/10.1016/j.molliq.2019.04.086
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 11
application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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