Corrosion Inhibition of 1,4-di (1-vinyl-3-methylimidazolium) Benzene Dibromide on Mild Steel in HCl Solution
Autor(a) principal: | |
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Data de Publicação: | 2016 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042016000300004 |
Resumo: | The inhibition and the effect of temperature and concentration of 1,4-di(1-vinyl-3methylimidazolium) benzene dibromide (VMIBB) on the corrosion of mild steel in 1.0 M HCl solution was investigated by electrochemical polarization and weight loss experiments at temperatures ranging from 303 to 343 K. The studied inhibitor concentrations ranged between 1.0×10-6 M and 1.0×10-2 M. The percentage inhibition increased with the increase of the inhibitor's concentration. The percentage inhibition has reached about 93 % at the concentration of 1×10-2 M and 303 K. On the other hand, the percentage inhibition decreased with the increase of temperature. Using the Langmuir adsorption isotherm, the thermodynamic parameters for the adsorption of this inhibitor on the metal surface were calculated. 1,4-di(1-vinyl-3-methylimidazolium) benzene dibromide was found to be a potential corrosion inhibitor, since it contained not only nitrogen, but also three aromatic systems, double bond, and it is a large molecule which has a big surface with high molar surface coverage. |
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Corrosion Inhibition of 1,4-di (1-vinyl-3-methylimidazolium) Benzene Dibromide on Mild Steel in HCl SolutionCorrosioninhibitor1,4-di(1-vinyl-3-methylimidazolium) benzene dibromideLangmuir adsorption isothermThe inhibition and the effect of temperature and concentration of 1,4-di(1-vinyl-3methylimidazolium) benzene dibromide (VMIBB) on the corrosion of mild steel in 1.0 M HCl solution was investigated by electrochemical polarization and weight loss experiments at temperatures ranging from 303 to 343 K. The studied inhibitor concentrations ranged between 1.0×10-6 M and 1.0×10-2 M. The percentage inhibition increased with the increase of the inhibitor's concentration. The percentage inhibition has reached about 93 % at the concentration of 1×10-2 M and 303 K. On the other hand, the percentage inhibition decreased with the increase of temperature. Using the Langmuir adsorption isotherm, the thermodynamic parameters for the adsorption of this inhibitor on the metal surface were calculated. 1,4-di(1-vinyl-3-methylimidazolium) benzene dibromide was found to be a potential corrosion inhibitor, since it contained not only nitrogen, but also three aromatic systems, double bond, and it is a large molecule which has a big surface with high molar surface coverage.Sociedade Portuguesa de Electroquímica2016-05-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articletext/htmlhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042016000300004Portugaliae Electrochimica Acta v.34 n.3 2016reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAPenghttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042016000300004Nahle,AyssarAl-tuniji,Reem SaeedAbu-Abdoun,IdeisanAbdel-Rahman,Ibrahiminfo:eu-repo/semantics/openAccess2024-02-06T17:07:21Zoai:scielo:S0872-19042016000300004Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:20:18.426816Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Corrosion Inhibition of 1,4-di (1-vinyl-3-methylimidazolium) Benzene Dibromide on Mild Steel in HCl Solution |
title |
Corrosion Inhibition of 1,4-di (1-vinyl-3-methylimidazolium) Benzene Dibromide on Mild Steel in HCl Solution |
spellingShingle |
Corrosion Inhibition of 1,4-di (1-vinyl-3-methylimidazolium) Benzene Dibromide on Mild Steel in HCl Solution Nahle,Ayssar Corrosion inhibitor 1,4-di(1-vinyl-3-methylimidazolium) benzene dibromide Langmuir adsorption isotherm |
title_short |
Corrosion Inhibition of 1,4-di (1-vinyl-3-methylimidazolium) Benzene Dibromide on Mild Steel in HCl Solution |
title_full |
Corrosion Inhibition of 1,4-di (1-vinyl-3-methylimidazolium) Benzene Dibromide on Mild Steel in HCl Solution |
title_fullStr |
Corrosion Inhibition of 1,4-di (1-vinyl-3-methylimidazolium) Benzene Dibromide on Mild Steel in HCl Solution |
title_full_unstemmed |
Corrosion Inhibition of 1,4-di (1-vinyl-3-methylimidazolium) Benzene Dibromide on Mild Steel in HCl Solution |
title_sort |
Corrosion Inhibition of 1,4-di (1-vinyl-3-methylimidazolium) Benzene Dibromide on Mild Steel in HCl Solution |
author |
Nahle,Ayssar |
author_facet |
Nahle,Ayssar Al-tuniji,Reem Saeed Abu-Abdoun,Ideisan Abdel-Rahman,Ibrahim |
author_role |
author |
author2 |
Al-tuniji,Reem Saeed Abu-Abdoun,Ideisan Abdel-Rahman,Ibrahim |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Nahle,Ayssar Al-tuniji,Reem Saeed Abu-Abdoun,Ideisan Abdel-Rahman,Ibrahim |
dc.subject.por.fl_str_mv |
Corrosion inhibitor 1,4-di(1-vinyl-3-methylimidazolium) benzene dibromide Langmuir adsorption isotherm |
topic |
Corrosion inhibitor 1,4-di(1-vinyl-3-methylimidazolium) benzene dibromide Langmuir adsorption isotherm |
description |
The inhibition and the effect of temperature and concentration of 1,4-di(1-vinyl-3methylimidazolium) benzene dibromide (VMIBB) on the corrosion of mild steel in 1.0 M HCl solution was investigated by electrochemical polarization and weight loss experiments at temperatures ranging from 303 to 343 K. The studied inhibitor concentrations ranged between 1.0×10-6 M and 1.0×10-2 M. The percentage inhibition increased with the increase of the inhibitor's concentration. The percentage inhibition has reached about 93 % at the concentration of 1×10-2 M and 303 K. On the other hand, the percentage inhibition decreased with the increase of temperature. Using the Langmuir adsorption isotherm, the thermodynamic parameters for the adsorption of this inhibitor on the metal surface were calculated. 1,4-di(1-vinyl-3-methylimidazolium) benzene dibromide was found to be a potential corrosion inhibitor, since it contained not only nitrogen, but also three aromatic systems, double bond, and it is a large molecule which has a big surface with high molar surface coverage. |
publishDate |
2016 |
dc.date.none.fl_str_mv |
2016-05-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042016000300004 |
url |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042016000300004 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042016000300004 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
dc.source.none.fl_str_mv |
Portugaliae Electrochimica Acta v.34 n.3 2016 reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799137291476664320 |