Allylic and benzylic oxidation reactions with sodium chlorite
Autor(a) principal: | |
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Data de Publicação: | 2007 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10316/5861 https://doi.org/10.1016/j.tet.2007.01.012 |
Resumo: | Various allylic and benzylic substrates were selectively oxidized to the corresponding enones in good yields using sodium chlorite, either in combination with tert-butyl hydroperoxide in stoichiometric conditions, or associated with N-hydroxyphthalimide as catalyst. These oxidation reactions were effectively and economically performed under mild, transition-metal free conditions and therefore the dual challenge of cost effectiveness and benign nature of the processes was met with. |
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Allylic and benzylic oxidation reactions with sodium chloriteSodium chloriteAllylic oxidationBenzylic oxidationTransition-metal freeVarious allylic and benzylic substrates were selectively oxidized to the corresponding enones in good yields using sodium chlorite, either in combination with tert-butyl hydroperoxide in stoichiometric conditions, or associated with N-hydroxyphthalimide as catalyst. These oxidation reactions were effectively and economically performed under mild, transition-metal free conditions and therefore the dual challenge of cost effectiveness and benign nature of the processes was met with.http://www.sciencedirect.com/science/article/B6THR-4MT5JX3-5/1/64e51e9b1aae448b3f47f8c2efad85af2007info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleaplication/PDFhttp://hdl.handle.net/10316/5861http://hdl.handle.net/10316/5861https://doi.org/10.1016/j.tet.2007.01.012engTetrahedron. 63:11 (2007) 2439-2445Silvestre, Samuel M.Salvador, Jorge A. R.info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2021-10-28T11:13:47Zoai:estudogeral.uc.pt:10316/5861Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T20:47:24.367529Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Allylic and benzylic oxidation reactions with sodium chlorite |
title |
Allylic and benzylic oxidation reactions with sodium chlorite |
spellingShingle |
Allylic and benzylic oxidation reactions with sodium chlorite Silvestre, Samuel M. Sodium chlorite Allylic oxidation Benzylic oxidation Transition-metal free |
title_short |
Allylic and benzylic oxidation reactions with sodium chlorite |
title_full |
Allylic and benzylic oxidation reactions with sodium chlorite |
title_fullStr |
Allylic and benzylic oxidation reactions with sodium chlorite |
title_full_unstemmed |
Allylic and benzylic oxidation reactions with sodium chlorite |
title_sort |
Allylic and benzylic oxidation reactions with sodium chlorite |
author |
Silvestre, Samuel M. |
author_facet |
Silvestre, Samuel M. Salvador, Jorge A. R. |
author_role |
author |
author2 |
Salvador, Jorge A. R. |
author2_role |
author |
dc.contributor.author.fl_str_mv |
Silvestre, Samuel M. Salvador, Jorge A. R. |
dc.subject.por.fl_str_mv |
Sodium chlorite Allylic oxidation Benzylic oxidation Transition-metal free |
topic |
Sodium chlorite Allylic oxidation Benzylic oxidation Transition-metal free |
description |
Various allylic and benzylic substrates were selectively oxidized to the corresponding enones in good yields using sodium chlorite, either in combination with tert-butyl hydroperoxide in stoichiometric conditions, or associated with N-hydroxyphthalimide as catalyst. These oxidation reactions were effectively and economically performed under mild, transition-metal free conditions and therefore the dual challenge of cost effectiveness and benign nature of the processes was met with. |
publishDate |
2007 |
dc.date.none.fl_str_mv |
2007 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10316/5861 http://hdl.handle.net/10316/5861 https://doi.org/10.1016/j.tet.2007.01.012 |
url |
http://hdl.handle.net/10316/5861 https://doi.org/10.1016/j.tet.2007.01.012 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Tetrahedron. 63:11 (2007) 2439-2445 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
aplication/PDF |
dc.source.none.fl_str_mv |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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1799133751166369792 |