New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand
Autor(a) principal: | |
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Data de Publicação: | 2022 |
Outros Autores: | , , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10362/151037 |
Resumo: | Funding Information: NMM Moura, VV Serra and A Bastos thank their research contracts (CDL-CTTRI-048-88-ARH/2018, and CDL-CTTRI-62-ARH/2018) which are funded by national funds (OE), through FCT–Fundação para a Ciência e a Tecnologia, I.P., in the scope of the framework contract foreseen in numbers 4, 5 and 6 of the article 23, of the Law Decree 57/2016, of August 29, changed by Law 57/2017, of July 19. This work was partially supported by the Scientific Society PROTEOMASS (General Funds) (Portugal), Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP-2019/19448-8) and Universidade de São Paulo. K.A.D.F. Castro thanks CAPES for the post-doctoral scholarship granted (PNPD/CAPES). Publisher Copyright: © 2022 by the authors. |
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New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary LigandElectrochemical and Photophysical Insightscoordination chemistrycyclometalated iridium(III)PETporphyrinsinglet oxygenCatalysisMolecular BiologySpectroscopyComputer Science ApplicationsPhysical and Theoretical ChemistryOrganic ChemistryInorganic ChemistryFunding Information: NMM Moura, VV Serra and A Bastos thank their research contracts (CDL-CTTRI-048-88-ARH/2018, and CDL-CTTRI-62-ARH/2018) which are funded by national funds (OE), through FCT–Fundação para a Ciência e a Tecnologia, I.P., in the scope of the framework contract foreseen in numbers 4, 5 and 6 of the article 23, of the Law Decree 57/2016, of August 29, changed by Law 57/2017, of July 19. This work was partially supported by the Scientific Society PROTEOMASS (General Funds) (Portugal), Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP-2019/19448-8) and Universidade de São Paulo. K.A.D.F. Castro thanks CAPES for the post-doctoral scholarship granted (PNPD/CAPES). Publisher Copyright: © 2022 by the authors.An efficient synthetic access to new cationic porphyrin-bipyridine iridium(III) bis-cyclometalated complexes was developed. These porphyrins bearing arylbipyridine moieties at β-pyrrolic positions coordinated with iridium(III), and the corresponding Zn(II) porphyrin complexes were spectroscopically, electrochemically, and electronically characterized. The features displayed by the new cyclometalated porphyrin-bipyridine iridium(III) complexes, namely photoinduced electron transfer process (PET), and a remarkable efficiency to generate 1O2, allowing us to envisage new challenges and opportunities for their applications in several fields, such as photo(catalysis) and photodynamic therapies.DQ - Departamento de QuímicaLAQV@REQUIMTERUNMoura, Nuno M. M.Serra, Vanda VazBastos, AlexandreBiazotto, Juliana C.Castro, Kelly A. D. F.Faustino, Maria Amparo F.Lodeiro, Carlosda Silva, Roberto S.Neves, Maria da Graça P. M. S.2023-03-21T22:29:16Z2022-07-092022-07-09T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article19application/pdfhttp://hdl.handle.net/10362/151037eng1661-6596PURE: 56530588https://doi.org/10.3390/ijms23147606info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:33:29Zoai:run.unl.pt:10362/151037Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:54:26.303960Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand Electrochemical and Photophysical Insights |
title |
New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand |
spellingShingle |
New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand Moura, Nuno M. M. coordination chemistry cyclometalated iridium(III) PET porphyrin singlet oxygen Catalysis Molecular Biology Spectroscopy Computer Science Applications Physical and Theoretical Chemistry Organic Chemistry Inorganic Chemistry |
title_short |
New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand |
title_full |
New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand |
title_fullStr |
New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand |
title_full_unstemmed |
New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand |
title_sort |
New Bis-Cyclometalated Iridium(III) Complexes with β-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand |
author |
Moura, Nuno M. M. |
author_facet |
Moura, Nuno M. M. Serra, Vanda Vaz Bastos, Alexandre Biazotto, Juliana C. Castro, Kelly A. D. F. Faustino, Maria Amparo F. Lodeiro, Carlos da Silva, Roberto S. Neves, Maria da Graça P. M. S. |
author_role |
author |
author2 |
Serra, Vanda Vaz Bastos, Alexandre Biazotto, Juliana C. Castro, Kelly A. D. F. Faustino, Maria Amparo F. Lodeiro, Carlos da Silva, Roberto S. Neves, Maria da Graça P. M. S. |
author2_role |
author author author author author author author author |
dc.contributor.none.fl_str_mv |
DQ - Departamento de Química LAQV@REQUIMTE RUN |
dc.contributor.author.fl_str_mv |
Moura, Nuno M. M. Serra, Vanda Vaz Bastos, Alexandre Biazotto, Juliana C. Castro, Kelly A. D. F. Faustino, Maria Amparo F. Lodeiro, Carlos da Silva, Roberto S. Neves, Maria da Graça P. M. S. |
dc.subject.por.fl_str_mv |
coordination chemistry cyclometalated iridium(III) PET porphyrin singlet oxygen Catalysis Molecular Biology Spectroscopy Computer Science Applications Physical and Theoretical Chemistry Organic Chemistry Inorganic Chemistry |
topic |
coordination chemistry cyclometalated iridium(III) PET porphyrin singlet oxygen Catalysis Molecular Biology Spectroscopy Computer Science Applications Physical and Theoretical Chemistry Organic Chemistry Inorganic Chemistry |
description |
Funding Information: NMM Moura, VV Serra and A Bastos thank their research contracts (CDL-CTTRI-048-88-ARH/2018, and CDL-CTTRI-62-ARH/2018) which are funded by national funds (OE), through FCT–Fundação para a Ciência e a Tecnologia, I.P., in the scope of the framework contract foreseen in numbers 4, 5 and 6 of the article 23, of the Law Decree 57/2016, of August 29, changed by Law 57/2017, of July 19. This work was partially supported by the Scientific Society PROTEOMASS (General Funds) (Portugal), Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP-2019/19448-8) and Universidade de São Paulo. K.A.D.F. Castro thanks CAPES for the post-doctoral scholarship granted (PNPD/CAPES). Publisher Copyright: © 2022 by the authors. |
publishDate |
2022 |
dc.date.none.fl_str_mv |
2022-07-09 2022-07-09T00:00:00Z 2023-03-21T22:29:16Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10362/151037 |
url |
http://hdl.handle.net/10362/151037 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
1661-6596 PURE: 56530588 https://doi.org/10.3390/ijms23147606 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
19 application/pdf |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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1799138133046984704 |