Dielectric relaxation dynamics of high-temperature piezoelectric polyimide copolymers

• Autor(a) principal: Maceiras, A.
• Data de Publicação: 2015
• Outros Autores: Costa, C. M., Lopes, A. C., San Sebastián, M., Laza, J. M., Vilas, J. L., Ribelles, J. L. G., Sabater i Serra, R., Andrio Balado, A., Lanceros-Méndez, S., León, L. M.
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
• Texto Completo: http://hdl.handle.net/1822/38881
• topic: Dielectric response; Conductivity; Electric modulus; Polyimides polymer; Ciências Naturais::Ciências Físicas; Science & Technology

Polyimide co-polymers have been prepared based on different diamines as co-monomers: a diamine without CN groups and a novel synthesized diamine with two CN groups prepared by polycondensation reaction followed by thermal cyclodehydration. Dielectric spectroscopy measurements were performed and the dielectric complex function, ac conductivity and electric modulus of the co-polymers were investigated as a function of CN group content in the frequency range from 0.1 Hz to 107 Hz at temperatures from 25 to 260 °C. For all samples and temperatures above 150ºC, the dielectric constant increases with increasing temperature due to increaseing conductivity. The α-relaxation is just detected for the sample without CN groups, being this relaxation overlapped by the electrical conductivity contributions in the remaining samples. For the copolymer samples and the polymer with CN groups an important Maxwell-Wagner-Sillars contribution is detected. The mechanisms responsible for the dielectric relaxation, conduction process and electric modulus response have been discussed as a function of the CN groups content present in the samples.