Synthesis and second-order nonlinear optical properties of new chromophores containing benzimidazole, thiophene and pyrrole heterocycles
Autor(a) principal: | |
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Data de Publicação: | 2007 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/1822/7826 |
Resumo: | A new series of thermally stable benzimidazole-based nonlinear optical (NLO) chromophores 4-5 has been developed. These chromophores possess a thienylpyrrolyl pi-conjugated system attached to functionalized benzimidazole heterocycles. This feature leads to robust chromophores with excellent solvatochromic properties, high thermal stabilities and good molecular optical nonlinearities. |
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Synthesis and second-order nonlinear optical properties of new chromophores containing benzimidazole, thiophene and pyrrole heterocyclesThiophenePyrroleBenzimidazoleAuxiliary donors and auxiliary acceptorsSolvatochromic probesHyper-Rayleigh scattering (HRS)Thermal stabilityNonlinear optics (NLO)Science & TechnologyA new series of thermally stable benzimidazole-based nonlinear optical (NLO) chromophores 4-5 has been developed. These chromophores possess a thienylpyrrolyl pi-conjugated system attached to functionalized benzimidazole heterocycles. This feature leads to robust chromophores with excellent solvatochromic properties, high thermal stabilities and good molecular optical nonlinearities.Fundação para a Ciência e Tecnologia.ElsevierUniversidade do MinhoBatista, Rosa Maria FerreiraCosta, Susana P. G.Belsley, M.Raposo, M. Manuela M.20072007-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/7826eng"Tetrahedron". ISSN 0040-4020. 63:29 (2007) 9842–9849.0040-402010.1016/j.tet.2007.06.098http://www.scirus.com/srsapp/search?p= 0&dt=all&ds=bls&ds=sd&ds=mps&ds=cps&ds= cpp&sa= all&q=(Synthesis+OR+and+OR+second-order+OR+nonlinear+OR+optical+OR+ properties+OR+of+OR+new+OR+ chromophores+OR+containing+OR+benzimidazole%2C+OR+thiophene+OR+and+OR+pyrrole+ OR+heterocycles)++AND+(issn%3A00404020)#resultsinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:42:05Zoai:repositorium.sdum.uminho.pt:1822/7826Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T19:39:14.789563Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Synthesis and second-order nonlinear optical properties of new chromophores containing benzimidazole, thiophene and pyrrole heterocycles |
title |
Synthesis and second-order nonlinear optical properties of new chromophores containing benzimidazole, thiophene and pyrrole heterocycles |
spellingShingle |
Synthesis and second-order nonlinear optical properties of new chromophores containing benzimidazole, thiophene and pyrrole heterocycles Batista, Rosa Maria Ferreira Thiophene Pyrrole Benzimidazole Auxiliary donors and auxiliary acceptors Solvatochromic probes Hyper-Rayleigh scattering (HRS) Thermal stability Nonlinear optics (NLO) Science & Technology |
title_short |
Synthesis and second-order nonlinear optical properties of new chromophores containing benzimidazole, thiophene and pyrrole heterocycles |
title_full |
Synthesis and second-order nonlinear optical properties of new chromophores containing benzimidazole, thiophene and pyrrole heterocycles |
title_fullStr |
Synthesis and second-order nonlinear optical properties of new chromophores containing benzimidazole, thiophene and pyrrole heterocycles |
title_full_unstemmed |
Synthesis and second-order nonlinear optical properties of new chromophores containing benzimidazole, thiophene and pyrrole heterocycles |
title_sort |
Synthesis and second-order nonlinear optical properties of new chromophores containing benzimidazole, thiophene and pyrrole heterocycles |
author |
Batista, Rosa Maria Ferreira |
author_facet |
Batista, Rosa Maria Ferreira Costa, Susana P. G. Belsley, M. Raposo, M. Manuela M. |
author_role |
author |
author2 |
Costa, Susana P. G. Belsley, M. Raposo, M. Manuela M. |
author2_role |
author author author |
dc.contributor.none.fl_str_mv |
Universidade do Minho |
dc.contributor.author.fl_str_mv |
Batista, Rosa Maria Ferreira Costa, Susana P. G. Belsley, M. Raposo, M. Manuela M. |
dc.subject.por.fl_str_mv |
Thiophene Pyrrole Benzimidazole Auxiliary donors and auxiliary acceptors Solvatochromic probes Hyper-Rayleigh scattering (HRS) Thermal stability Nonlinear optics (NLO) Science & Technology |
topic |
Thiophene Pyrrole Benzimidazole Auxiliary donors and auxiliary acceptors Solvatochromic probes Hyper-Rayleigh scattering (HRS) Thermal stability Nonlinear optics (NLO) Science & Technology |
description |
A new series of thermally stable benzimidazole-based nonlinear optical (NLO) chromophores 4-5 has been developed. These chromophores possess a thienylpyrrolyl pi-conjugated system attached to functionalized benzimidazole heterocycles. This feature leads to robust chromophores with excellent solvatochromic properties, high thermal stabilities and good molecular optical nonlinearities. |
publishDate |
2007 |
dc.date.none.fl_str_mv |
2007 2007-01-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/1822/7826 |
url |
http://hdl.handle.net/1822/7826 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
"Tetrahedron". ISSN 0040-4020. 63:29 (2007) 9842–9849. 0040-4020 10.1016/j.tet.2007.06.098 http://www.scirus.com/srsapp/search?p= 0&dt=all&ds=bls&ds=sd&ds=mps&ds=cps&ds= cpp&sa= all&q=(Synthesis+OR+and+OR+second-order+OR+nonlinear+OR+optical+OR+ properties+OR+of+OR+new+OR+ chromophores+OR+containing+OR+benzimidazole%2C+OR+thiophene+OR+and+OR+pyrrole+ OR+heterocycles)++AND+(issn%3A00404020)#results |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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1799132932237950976 |