Investigations into the mechanism of action of nitrobenzene as a mild dehydrogenating agent under acid-catalysed conditions

Detalhes bibliográficos
Autor(a) principal: Cristiano, Maria Lurdes Santos
Data de Publicação: 2003
Outros Autores: Gago, David J. P., Gonsalves, Antonio M. d'A. Rocha, Johnstone, Robert A. W., McCarron, Moya, Varejão, Jorge M. T. B.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.1/4246
Resumo: Protonated nitrobenzene can be used to dehydrogenate a range of hydrocarbons, which already possess at least one double bond. Kinetic and spectroscopic results, together with known electrode potentials, yield approximate limits within which protonated nitrobenzenes can be expected to effect dehydrogenation of hydroaromatic compounds. A high yielding synthesis of benzo[ j ]fluoranthene is described.
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spelling Investigations into the mechanism of action of nitrobenzene as a mild dehydrogenating agent under acid-catalysed conditionsProtonated nitrobenzene can be used to dehydrogenate a range of hydrocarbons, which already possess at least one double bond. Kinetic and spectroscopic results, together with known electrode potentials, yield approximate limits within which protonated nitrobenzenes can be expected to effect dehydrogenation of hydroaromatic compounds. A high yielding synthesis of benzo[ j ]fluoranthene is described.Royal Society of ChemistrySapientiaCristiano, Maria Lurdes SantosGago, David J. P.Gonsalves, Antonio M. d'A. RochaJohnstone, Robert A. W.McCarron, MoyaVarejão, Jorge M. T. B.2014-06-07T11:52:24Z20032014-06-05T09:51:10Z2003-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.1/4246engCristiano, M. Lurdes S.; Gago, David J. P.; d'A. Rocha Gonsalves, Antonio M.; Johnstone, Robert A. W.; McCarron, Moya; Varejão, Jorge M. T. B. Investigations into the mechanism of action of nitrobenzene as a mild dehydrogenating agent under acid-catalysed conditions, Organic & Biomolecular Chemistry, 1, 3, 565-574, 2003.1477-0520AUT: MCR00716;http://dx.doi.org/10.1039/b210887ainfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-24T10:15:31Zoai:sapientia.ualg.pt:10400.1/4246Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T19:57:42.307393Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Investigations into the mechanism of action of nitrobenzene as a mild dehydrogenating agent under acid-catalysed conditions
title Investigations into the mechanism of action of nitrobenzene as a mild dehydrogenating agent under acid-catalysed conditions
spellingShingle Investigations into the mechanism of action of nitrobenzene as a mild dehydrogenating agent under acid-catalysed conditions
Cristiano, Maria Lurdes Santos
title_short Investigations into the mechanism of action of nitrobenzene as a mild dehydrogenating agent under acid-catalysed conditions
title_full Investigations into the mechanism of action of nitrobenzene as a mild dehydrogenating agent under acid-catalysed conditions
title_fullStr Investigations into the mechanism of action of nitrobenzene as a mild dehydrogenating agent under acid-catalysed conditions
title_full_unstemmed Investigations into the mechanism of action of nitrobenzene as a mild dehydrogenating agent under acid-catalysed conditions
title_sort Investigations into the mechanism of action of nitrobenzene as a mild dehydrogenating agent under acid-catalysed conditions
author Cristiano, Maria Lurdes Santos
author_facet Cristiano, Maria Lurdes Santos
Gago, David J. P.
Gonsalves, Antonio M. d'A. Rocha
Johnstone, Robert A. W.
McCarron, Moya
Varejão, Jorge M. T. B.
author_role author
author2 Gago, David J. P.
Gonsalves, Antonio M. d'A. Rocha
Johnstone, Robert A. W.
McCarron, Moya
Varejão, Jorge M. T. B.
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Sapientia
dc.contributor.author.fl_str_mv Cristiano, Maria Lurdes Santos
Gago, David J. P.
Gonsalves, Antonio M. d'A. Rocha
Johnstone, Robert A. W.
McCarron, Moya
Varejão, Jorge M. T. B.
description Protonated nitrobenzene can be used to dehydrogenate a range of hydrocarbons, which already possess at least one double bond. Kinetic and spectroscopic results, together with known electrode potentials, yield approximate limits within which protonated nitrobenzenes can be expected to effect dehydrogenation of hydroaromatic compounds. A high yielding synthesis of benzo[ j ]fluoranthene is described.
publishDate 2003
dc.date.none.fl_str_mv 2003
2003-01-01T00:00:00Z
2014-06-07T11:52:24Z
2014-06-05T09:51:10Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.1/4246
url http://hdl.handle.net/10400.1/4246
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Cristiano, M. Lurdes S.; Gago, David J. P.; d'A. Rocha Gonsalves, Antonio M.; Johnstone, Robert A. W.; McCarron, Moya; Varejão, Jorge M. T. B. Investigations into the mechanism of action of nitrobenzene as a mild dehydrogenating agent under acid-catalysed conditions, Organic & Biomolecular Chemistry, 1, 3, 565-574, 2003.
1477-0520
AUT: MCR00716;
http://dx.doi.org/10.1039/b210887a
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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