Ferrocene-Based Porous Organic Polymer (FPOP)

Detalhes bibliográficos
Autor(a) principal: Petrovski, Zeljko
Data de Publicação: 2022
Outros Autores: Moreira, Mateus P., Santos, Andreia F. M., Freitas, Sunny K. S., Jordão, Noémi, Maia, Renata A., Nunes, Ana V. M., Branco, Luis C., Cruz, Hugo, Esteves, Pierre M.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/143300
Resumo: This study was funded in part by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior—Brasil (CAPES)—Finance Code 001 and FCT-CAPES project (2019–2020). The authors also thank the funding agencies FAPERJ, CNPq and Fundação para a Ciência e Tecnologia (PEst-C/LA0006/2013, RECI/BBBBQB/0230/2012 as well as “SunStorage—Harvesting and storage of solar energy”, with reference POCI-01-0145-FEDER-016387. The NMR spectrometers are part of the National NMR Network (PTNMR) and are partially supported by Infrastructure Project N° 022161 (co-financed by FEDER through COMPETE 2020, POCI and PORL and FCT through PIDDAC). Ž.P. and H.C. acknowledge Fundação para a Ciência e a Tecnologia, MCTES, for the Norma Transitória DL57/2016 Program contract.
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spelling Ferrocene-Based Porous Organic Polymer (FPOP)Synthesis, Characterization and an Electrochemical StudyThis study was funded in part by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior—Brasil (CAPES)—Finance Code 001 and FCT-CAPES project (2019–2020). The authors also thank the funding agencies FAPERJ, CNPq and Fundação para a Ciência e Tecnologia (PEst-C/LA0006/2013, RECI/BBBBQB/0230/2012 as well as “SunStorage—Harvesting and storage of solar energy”, with reference POCI-01-0145-FEDER-016387. The NMR spectrometers are part of the National NMR Network (PTNMR) and are partially supported by Infrastructure Project N° 022161 (co-financed by FEDER through COMPETE 2020, POCI and PORL and FCT through PIDDAC). Ž.P. and H.C. acknowledge Fundação para a Ciência e a Tecnologia, MCTES, for the Norma Transitória DL57/2016 Program contract.Ferrocene-based porous organic polymers (FPOPs) were prepared fromphenol-formaldehyde polymer (Bakelite) and phenol as starting materials; and two possible mechanisms for polymerization were discussed. Solid-state 13C CP-MAS NMR, FTIR, powder XRD, elemental analysis and ICP (Fe, Na, B) were performed to characterize the prepared materials. The two synthetic approaches produced polymers with different pore sizes: the FPOP synthesized through Bakelite presented a higher surface area (52 m2 g1) when compared to the one obtained by the bottom-up polymerization from phenol (only 5 m2 g1). Thermogravimetric analysis confirmed the thermal stability of the material, which decomposed at 350 C. Furthermore, cyclic voltammetry (CV) of the new FPOP on modified electrodes, in ACN and 0.1 M TBAP as an electrolyte, showed fully reversible electron transfer, which is similar to that observed for the ferrocene probe dissolved in the same electrolyte. As a proof-of-concept for an electrochromic device, this novel material was also tested, with a color change detected between yellow/brownish coloration (reduced form) and green/blue coloration (oxidized form). The new hybrid FPOP seems very promising for material science, energy storage and electrochromic applications, as well as for plastic degradation.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNPetrovski, ZeljkoMoreira, Mateus P.Santos, Andreia F. M.Freitas, Sunny K. S.Jordão, NoémiMaia, Renata A.Nunes, Ana V. M.Branco, Luis C.Cruz, HugoEsteves, Pierre M.2022-08-25T22:19:49Z2022-02-272022-02-27T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article14application/pdfhttp://hdl.handle.net/10362/143300eng2673-3293PURE: 42037312https://doi.org/10.3390/electrochem3010011info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:21:36Zoai:run.unl.pt:10362/143300Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:50:49.130964Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Ferrocene-Based Porous Organic Polymer (FPOP)
Synthesis, Characterization and an Electrochemical Study
title Ferrocene-Based Porous Organic Polymer (FPOP)
spellingShingle Ferrocene-Based Porous Organic Polymer (FPOP)
Petrovski, Zeljko
title_short Ferrocene-Based Porous Organic Polymer (FPOP)
title_full Ferrocene-Based Porous Organic Polymer (FPOP)
title_fullStr Ferrocene-Based Porous Organic Polymer (FPOP)
title_full_unstemmed Ferrocene-Based Porous Organic Polymer (FPOP)
title_sort Ferrocene-Based Porous Organic Polymer (FPOP)
author Petrovski, Zeljko
author_facet Petrovski, Zeljko
Moreira, Mateus P.
Santos, Andreia F. M.
Freitas, Sunny K. S.
Jordão, Noémi
Maia, Renata A.
Nunes, Ana V. M.
Branco, Luis C.
Cruz, Hugo
Esteves, Pierre M.
author_role author
author2 Moreira, Mateus P.
Santos, Andreia F. M.
Freitas, Sunny K. S.
Jordão, Noémi
Maia, Renata A.
Nunes, Ana V. M.
Branco, Luis C.
Cruz, Hugo
Esteves, Pierre M.
author2_role author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Petrovski, Zeljko
Moreira, Mateus P.
Santos, Andreia F. M.
Freitas, Sunny K. S.
Jordão, Noémi
Maia, Renata A.
Nunes, Ana V. M.
Branco, Luis C.
Cruz, Hugo
Esteves, Pierre M.
description This study was funded in part by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior—Brasil (CAPES)—Finance Code 001 and FCT-CAPES project (2019–2020). The authors also thank the funding agencies FAPERJ, CNPq and Fundação para a Ciência e Tecnologia (PEst-C/LA0006/2013, RECI/BBBBQB/0230/2012 as well as “SunStorage—Harvesting and storage of solar energy”, with reference POCI-01-0145-FEDER-016387. The NMR spectrometers are part of the National NMR Network (PTNMR) and are partially supported by Infrastructure Project N° 022161 (co-financed by FEDER through COMPETE 2020, POCI and PORL and FCT through PIDDAC). Ž.P. and H.C. acknowledge Fundação para a Ciência e a Tecnologia, MCTES, for the Norma Transitória DL57/2016 Program contract.
publishDate 2022
dc.date.none.fl_str_mv 2022-08-25T22:19:49Z
2022-02-27
2022-02-27T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
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status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/143300
url http://hdl.handle.net/10362/143300
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2673-3293
PURE: 42037312
https://doi.org/10.3390/electrochem3010011
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
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instacron:RCAAP
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repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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