Biomass ash-based soil improvers: impact of formulation and stabilization conditions on materials’ properties

• Autor(a) principal: Cruz, Nuno
• Data de Publicação: 2023
• Outros Autores: Avellan, A., Ruivo, L., Silva, F. C., Rӧmkens, P.F.A.M., Tarelho, L.A.C., Rodrigues, S. M.
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
• Texto Completo: http://hdl.handle.net/10773/36882
• topic: Biomass fly ash; Biological sludge; Carbonation; EU Fertilizing Products Regulation (EU, 2019/1009); Granulation; Leaching behaviour

Biomass ash and sludge from pulp and paper industry have enormous potential to be recycled and used as components in soil improvers. Those materials can supply large amounts of nutrients and organic matter and its recycling avoids the need of landfilling. However, these wastes cannot be directly applied to soils. Some form of processing is required to ensure efficient soil pH correction, fertilization, guarantee soil protection, and reduce potential sanitary and environmental risks. In this study, different ash formulations (with or without addition of organic wastes) and stabilization conditions (indoors vs. outdoors) were tested to optimize physico-chemical properties of ash-based granules to be used as soil improvers. Biomass fly ash (BFA) was granulated in combination with different binding agents: distilled water, biological sludge (BS), biological sludge effluent (BSE), or composted biological sludge (CBS). All granulated materials were alkaline, ranging from pH 7.9 to 12.1. Their acid-neutralizing capacity ranged from 45 to 51 equiv. CaCO3, rendering them suitable as liming materials. Incorporation of organic materials (BS and CBS) enhanced water holding capacity (up to 38 %) and bulk porosity (up to 20 %). Stabilization outdoors resulted in a faster carbonation and consequent reduction of the granules pH. It also yielded a lower electrical conductivity and lower soluble salts content (Ca, Cl, K, and Na) than materials stabilized indoors. After processing and stabilization, some of these ash formulations fulfilled the criteria to be used as component for inorganic macronutrient fertilizers, liming materials or inorganic soil improvers under the EU Fertilizing Products Regulation.