An improved general kinetic analysis of non-linear irreversible polymerisations

Detalhes bibliográficos
Autor(a) principal: Costa, Mário Rui
Data de Publicação: 2005
Outros Autores: Dias, Rolando
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10198/336
Resumo: A method to predict average molecular weights before and after gelation for general irreversible non-linear polymerisations forming tree-like molecules is described. Recently developed numerical methods for solving two point boundary value problems are essential for the success of these calculations after gelation and open the way to eventually be able to efficiently predicting chain length distributions. Anionic and free-radical polymerisation of vinyl monomers in the presence of divinyl monomers or with transfer to polymer are taken as case studies. Comparison to experimental data and with simulation results obtained through “numerical fractionation” confirms the usefulness of current approach.
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spelling An improved general kinetic analysis of non-linear irreversible polymerisationsPolymerizationsKineticModellingGelsFree radicalAnionicA method to predict average molecular weights before and after gelation for general irreversible non-linear polymerisations forming tree-like molecules is described. Recently developed numerical methods for solving two point boundary value problems are essential for the success of these calculations after gelation and open the way to eventually be able to efficiently predicting chain length distributions. Anionic and free-radical polymerisation of vinyl monomers in the presence of divinyl monomers or with transfer to polymer are taken as case studies. Comparison to experimental data and with simulation results obtained through “numerical fractionation” confirms the usefulness of current approach.FCT European CommunityElsevierBiblioteca Digital do IPBCosta, Mário RuiDias, Rolando2008-01-04T11:04:30Z20052005-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10198/336engengCosta, Mário; Dias, Rolando (2005). An improved general kinetic analysis of non-linear irreversible polymerisations. Chemical Engineering Science. ISSN 0009-2509. 60:2, p.423-4460009-2509Chemical Engineering Science10.1016/j.ces.2004.07.125info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-11-21T10:03:18Zoai:bibliotecadigital.ipb.pt:10198/336Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T22:54:14.656366Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv An improved general kinetic analysis of non-linear irreversible polymerisations
title An improved general kinetic analysis of non-linear irreversible polymerisations
spellingShingle An improved general kinetic analysis of non-linear irreversible polymerisations
Costa, Mário Rui
Polymerizations
Kinetic
Modelling
Gels
Free radical
Anionic
title_short An improved general kinetic analysis of non-linear irreversible polymerisations
title_full An improved general kinetic analysis of non-linear irreversible polymerisations
title_fullStr An improved general kinetic analysis of non-linear irreversible polymerisations
title_full_unstemmed An improved general kinetic analysis of non-linear irreversible polymerisations
title_sort An improved general kinetic analysis of non-linear irreversible polymerisations
author Costa, Mário Rui
author_facet Costa, Mário Rui
Dias, Rolando
author_role author
author2 Dias, Rolando
author2_role author
dc.contributor.none.fl_str_mv Biblioteca Digital do IPB
dc.contributor.author.fl_str_mv Costa, Mário Rui
Dias, Rolando
dc.subject.por.fl_str_mv Polymerizations
Kinetic
Modelling
Gels
Free radical
Anionic
topic Polymerizations
Kinetic
Modelling
Gels
Free radical
Anionic
description A method to predict average molecular weights before and after gelation for general irreversible non-linear polymerisations forming tree-like molecules is described. Recently developed numerical methods for solving two point boundary value problems are essential for the success of these calculations after gelation and open the way to eventually be able to efficiently predicting chain length distributions. Anionic and free-radical polymerisation of vinyl monomers in the presence of divinyl monomers or with transfer to polymer are taken as case studies. Comparison to experimental data and with simulation results obtained through “numerical fractionation” confirms the usefulness of current approach.
publishDate 2005
dc.date.none.fl_str_mv 2005
2005-01-01T00:00:00Z
2008-01-04T11:04:30Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10198/336
url http://hdl.handle.net/10198/336
dc.language.iso.fl_str_mv eng
eng
language eng
dc.relation.none.fl_str_mv Costa, Mário; Dias, Rolando (2005). An improved general kinetic analysis of non-linear irreversible polymerisations. Chemical Engineering Science. ISSN 0009-2509. 60:2, p.423-446
0009-2509
Chemical Engineering Science
10.1016/j.ces.2004.07.125
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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