Photooxidation of 4-chlorophenol sensitised by iron meso-tetrakis(2,6-dichloro-3-sulfophenyl)porphyrin in aqueous solution
Autor(a) principal: | |
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Data de Publicação: | 2003 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10316/10726 https://doi.org/10.1039/b308975d |
Resumo: | The photosensitised degradation of 4-chlorophenol (4-CP) by iron meso-tetrakis(2,6-dichloro-3-sulfophenyl)porphyrin (FeTDCPPS) has been studied in aerated aqueous solution, and is shown to lead to formation of p-benzoquinone (BQ) and p-hydroquinone (HQ) as main photoproducts. In deaerated solution no p-benzoquinone was formed. The photolysis products were identified by high performance liquid chromatography (HPLC) and UV-visible spectroscopy. The photodegradation in aerated solution was also carried out in the presence of sodium azide (NaN3) as a singlet oxygen [1O2(1g)] quencher, and showed a significant decrease in the rate of photolysis, suggesting under these conditions, that Type II sensitisation is one of the dominant mechanisms of 4-CP degradation. Support for this comes from laser flash photolysis and time-resolved singlet oxygen phosphorescence measurements. However, these also show direct reaction between the excited porphyrin and 4-CP, indicating that there are two mechanisms involved in the chlorophenol photodegradation. |
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Photooxidation of 4-chlorophenol sensitised by iron meso-tetrakis(2,6-dichloro-3-sulfophenyl)porphyrin in aqueous solutionThe photosensitised degradation of 4-chlorophenol (4-CP) by iron meso-tetrakis(2,6-dichloro-3-sulfophenyl)porphyrin (FeTDCPPS) has been studied in aerated aqueous solution, and is shown to lead to formation of p-benzoquinone (BQ) and p-hydroquinone (HQ) as main photoproducts. In deaerated solution no p-benzoquinone was formed. The photolysis products were identified by high performance liquid chromatography (HPLC) and UV-visible spectroscopy. The photodegradation in aerated solution was also carried out in the presence of sodium azide (NaN3) as a singlet oxygen [1O2(1g)] quencher, and showed a significant decrease in the rate of photolysis, suggesting under these conditions, that Type II sensitisation is one of the dominant mechanisms of 4-CP degradation. Support for this comes from laser flash photolysis and time-resolved singlet oxygen phosphorescence measurements. However, these also show direct reaction between the excited porphyrin and 4-CP, indicating that there are two mechanisms involved in the chlorophenol photodegradation.Clermont-Ferrand; ICCTI/GRICES; CNRS; FCT; POCTI; FEDERRoyal Society of Chemistry2003-11-25info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://hdl.handle.net/10316/10726http://hdl.handle.net/10316/10726https://doi.org/10.1039/b308975dengPhotochemical & Photobiological Sciences. 3 (2004) 200-2041474-905XSilva, ElianaPereira, Mariette M.Burrows, Hugh D.Azenha, M. E.Sarakha, MohamedBolte, Michèleinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2020-03-09T11:28:39Zoai:estudogeral.uc.pt:10316/10726Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T21:01:36.810067Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Photooxidation of 4-chlorophenol sensitised by iron meso-tetrakis(2,6-dichloro-3-sulfophenyl)porphyrin in aqueous solution |
title |
Photooxidation of 4-chlorophenol sensitised by iron meso-tetrakis(2,6-dichloro-3-sulfophenyl)porphyrin in aqueous solution |
spellingShingle |
Photooxidation of 4-chlorophenol sensitised by iron meso-tetrakis(2,6-dichloro-3-sulfophenyl)porphyrin in aqueous solution Silva, Eliana |
title_short |
Photooxidation of 4-chlorophenol sensitised by iron meso-tetrakis(2,6-dichloro-3-sulfophenyl)porphyrin in aqueous solution |
title_full |
Photooxidation of 4-chlorophenol sensitised by iron meso-tetrakis(2,6-dichloro-3-sulfophenyl)porphyrin in aqueous solution |
title_fullStr |
Photooxidation of 4-chlorophenol sensitised by iron meso-tetrakis(2,6-dichloro-3-sulfophenyl)porphyrin in aqueous solution |
title_full_unstemmed |
Photooxidation of 4-chlorophenol sensitised by iron meso-tetrakis(2,6-dichloro-3-sulfophenyl)porphyrin in aqueous solution |
title_sort |
Photooxidation of 4-chlorophenol sensitised by iron meso-tetrakis(2,6-dichloro-3-sulfophenyl)porphyrin in aqueous solution |
author |
Silva, Eliana |
author_facet |
Silva, Eliana Pereira, Mariette M. Burrows, Hugh D. Azenha, M. E. Sarakha, Mohamed Bolte, Michèle |
author_role |
author |
author2 |
Pereira, Mariette M. Burrows, Hugh D. Azenha, M. E. Sarakha, Mohamed Bolte, Michèle |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Silva, Eliana Pereira, Mariette M. Burrows, Hugh D. Azenha, M. E. Sarakha, Mohamed Bolte, Michèle |
description |
The photosensitised degradation of 4-chlorophenol (4-CP) by iron meso-tetrakis(2,6-dichloro-3-sulfophenyl)porphyrin (FeTDCPPS) has been studied in aerated aqueous solution, and is shown to lead to formation of p-benzoquinone (BQ) and p-hydroquinone (HQ) as main photoproducts. In deaerated solution no p-benzoquinone was formed. The photolysis products were identified by high performance liquid chromatography (HPLC) and UV-visible spectroscopy. The photodegradation in aerated solution was also carried out in the presence of sodium azide (NaN3) as a singlet oxygen [1O2(1g)] quencher, and showed a significant decrease in the rate of photolysis, suggesting under these conditions, that Type II sensitisation is one of the dominant mechanisms of 4-CP degradation. Support for this comes from laser flash photolysis and time-resolved singlet oxygen phosphorescence measurements. However, these also show direct reaction between the excited porphyrin and 4-CP, indicating that there are two mechanisms involved in the chlorophenol photodegradation. |
publishDate |
2003 |
dc.date.none.fl_str_mv |
2003-11-25 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10316/10726 http://hdl.handle.net/10316/10726 https://doi.org/10.1039/b308975d |
url |
http://hdl.handle.net/10316/10726 https://doi.org/10.1039/b308975d |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Photochemical & Photobiological Sciences. 3 (2004) 200-204 1474-905X |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.publisher.none.fl_str_mv |
Royal Society of Chemistry |
publisher.none.fl_str_mv |
Royal Society of Chemistry |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799133906957500416 |