Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluents

Detalhes bibliográficos
Autor(a) principal: Dantas Filho,Antonio do Nascimento
Data de Publicação: 2020
Outros Autores: Aroucha,Edna Maria Mendes, Leite,Ricardo Henrique de Lima, Santos,Francisco Klebson Gomes dos
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Matéria (Rio de Janeiro. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000400312
Resumo: ABSTRACT The textile industry produces dye-rich effluents that when released in hydric bodies hamper the penetration of sunlight, impairing photosynthetic processes. Besides that, dyes have been indicated as potentially toxic substances. In general, the processes of removing of these contaminants have been much studied, with the technique of adsorption standing out for its high efficiency, in addition to operational advantages and the possibility of reuse agricultural waste as adsorbents, benefiting the environment and reducing costs. The present work had as objective to study the performance of coconut mesocarp utilized as adsorbent in the bleaching process of synthetic effluent containing 25 g.L-1 of reactive red 195 dye. The adsorbent were characterized by granulometry, thermogravimetric analysis and zero point charge. Kinetic and balance study was realized, applying kinetic models and adsorption isotherms. The adsorbent exhibited removal efficiency of 89.92 % in 120 min. The maximum adsorption capacity was 24.04 g.g-1 at 30 °C. The kinetic study showed that the data was better adjusted by an Elovich equation, indicating slow chemisorption. The thermodynamic study exhibited that the adsorption process is exothermic and spontaneous for all the temperatures evaluated.
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spelling Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluentsAdsorptionCoconut mesocarpDyeABSTRACT The textile industry produces dye-rich effluents that when released in hydric bodies hamper the penetration of sunlight, impairing photosynthetic processes. Besides that, dyes have been indicated as potentially toxic substances. In general, the processes of removing of these contaminants have been much studied, with the technique of adsorption standing out for its high efficiency, in addition to operational advantages and the possibility of reuse agricultural waste as adsorbents, benefiting the environment and reducing costs. The present work had as objective to study the performance of coconut mesocarp utilized as adsorbent in the bleaching process of synthetic effluent containing 25 g.L-1 of reactive red 195 dye. The adsorbent were characterized by granulometry, thermogravimetric analysis and zero point charge. Kinetic and balance study was realized, applying kinetic models and adsorption isotherms. The adsorbent exhibited removal efficiency of 89.92 % in 120 min. The maximum adsorption capacity was 24.04 g.g-1 at 30 °C. The kinetic study showed that the data was better adjusted by an Elovich equation, indicating slow chemisorption. The thermodynamic study exhibited that the adsorption process is exothermic and spontaneous for all the temperatures evaluated.Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiroem cooperação com a Associação Brasileira do Hidrogênio, ABH22020-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000400312Matéria (Rio de Janeiro) v.25 n.4 2020reponame:Matéria (Rio de Janeiro. Online)instname:Matéria (Rio de Janeiro. Online)instacron:RLAM10.1590/s1517-707620200004.1152info:eu-repo/semantics/openAccessDantas Filho,Antonio do NascimentoAroucha,Edna Maria MendesLeite,Ricardo Henrique de LimaSantos,Francisco Klebson Gomes doseng2020-12-08T00:00:00Zoai:scielo:S1517-70762020000400312Revistahttp://www.materia.coppe.ufrj.br/https://old.scielo.br/oai/scielo-oai.php||materia@labh2.coppe.ufrj.br1517-70761517-7076opendoar:2020-12-08T00:00Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online)false
dc.title.none.fl_str_mv Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluents
title Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluents
spellingShingle Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluents
Dantas Filho,Antonio do Nascimento
Adsorption
Coconut mesocarp
Dye
title_short Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluents
title_full Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluents
title_fullStr Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluents
title_full_unstemmed Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluents
title_sort Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluents
author Dantas Filho,Antonio do Nascimento
author_facet Dantas Filho,Antonio do Nascimento
Aroucha,Edna Maria Mendes
Leite,Ricardo Henrique de Lima
Santos,Francisco Klebson Gomes dos
author_role author
author2 Aroucha,Edna Maria Mendes
Leite,Ricardo Henrique de Lima
Santos,Francisco Klebson Gomes dos
author2_role author
author
author
dc.contributor.author.fl_str_mv Dantas Filho,Antonio do Nascimento
Aroucha,Edna Maria Mendes
Leite,Ricardo Henrique de Lima
Santos,Francisco Klebson Gomes dos
dc.subject.por.fl_str_mv Adsorption
Coconut mesocarp
Dye
topic Adsorption
Coconut mesocarp
Dye
description ABSTRACT The textile industry produces dye-rich effluents that when released in hydric bodies hamper the penetration of sunlight, impairing photosynthetic processes. Besides that, dyes have been indicated as potentially toxic substances. In general, the processes of removing of these contaminants have been much studied, with the technique of adsorption standing out for its high efficiency, in addition to operational advantages and the possibility of reuse agricultural waste as adsorbents, benefiting the environment and reducing costs. The present work had as objective to study the performance of coconut mesocarp utilized as adsorbent in the bleaching process of synthetic effluent containing 25 g.L-1 of reactive red 195 dye. The adsorbent were characterized by granulometry, thermogravimetric analysis and zero point charge. Kinetic and balance study was realized, applying kinetic models and adsorption isotherms. The adsorbent exhibited removal efficiency of 89.92 % in 120 min. The maximum adsorption capacity was 24.04 g.g-1 at 30 °C. The kinetic study showed that the data was better adjusted by an Elovich equation, indicating slow chemisorption. The thermodynamic study exhibited that the adsorption process is exothermic and spontaneous for all the temperatures evaluated.
publishDate 2020
dc.date.none.fl_str_mv 2020-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000400312
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000400312
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/s1517-707620200004.1152
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro
em cooperação com a Associação Brasileira do Hidrogênio, ABH2
publisher.none.fl_str_mv Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro
em cooperação com a Associação Brasileira do Hidrogênio, ABH2
dc.source.none.fl_str_mv Matéria (Rio de Janeiro) v.25 n.4 2020
reponame:Matéria (Rio de Janeiro. Online)
instname:Matéria (Rio de Janeiro. Online)
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reponame_str Matéria (Rio de Janeiro. Online)
collection Matéria (Rio de Janeiro. Online)
repository.name.fl_str_mv Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online)
repository.mail.fl_str_mv ||materia@labh2.coppe.ufrj.br
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