Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluents
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Matéria (Rio de Janeiro. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000400312 |
Resumo: | ABSTRACT The textile industry produces dye-rich effluents that when released in hydric bodies hamper the penetration of sunlight, impairing photosynthetic processes. Besides that, dyes have been indicated as potentially toxic substances. In general, the processes of removing of these contaminants have been much studied, with the technique of adsorption standing out for its high efficiency, in addition to operational advantages and the possibility of reuse agricultural waste as adsorbents, benefiting the environment and reducing costs. The present work had as objective to study the performance of coconut mesocarp utilized as adsorbent in the bleaching process of synthetic effluent containing 25 g.L-1 of reactive red 195 dye. The adsorbent were characterized by granulometry, thermogravimetric analysis and zero point charge. Kinetic and balance study was realized, applying kinetic models and adsorption isotherms. The adsorbent exhibited removal efficiency of 89.92 % in 120 min. The maximum adsorption capacity was 24.04 g.g-1 at 30 °C. The kinetic study showed that the data was better adjusted by an Elovich equation, indicating slow chemisorption. The thermodynamic study exhibited that the adsorption process is exothermic and spontaneous for all the temperatures evaluated. |
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Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluentsAdsorptionCoconut mesocarpDyeABSTRACT The textile industry produces dye-rich effluents that when released in hydric bodies hamper the penetration of sunlight, impairing photosynthetic processes. Besides that, dyes have been indicated as potentially toxic substances. In general, the processes of removing of these contaminants have been much studied, with the technique of adsorption standing out for its high efficiency, in addition to operational advantages and the possibility of reuse agricultural waste as adsorbents, benefiting the environment and reducing costs. The present work had as objective to study the performance of coconut mesocarp utilized as adsorbent in the bleaching process of synthetic effluent containing 25 g.L-1 of reactive red 195 dye. The adsorbent were characterized by granulometry, thermogravimetric analysis and zero point charge. Kinetic and balance study was realized, applying kinetic models and adsorption isotherms. The adsorbent exhibited removal efficiency of 89.92 % in 120 min. The maximum adsorption capacity was 24.04 g.g-1 at 30 °C. The kinetic study showed that the data was better adjusted by an Elovich equation, indicating slow chemisorption. The thermodynamic study exhibited that the adsorption process is exothermic and spontaneous for all the temperatures evaluated.Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiroem cooperação com a Associação Brasileira do Hidrogênio, ABH22020-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000400312Matéria (Rio de Janeiro) v.25 n.4 2020reponame:Matéria (Rio de Janeiro. Online)instname:Matéria (Rio de Janeiro. Online)instacron:RLAM10.1590/s1517-707620200004.1152info:eu-repo/semantics/openAccessDantas Filho,Antonio do NascimentoAroucha,Edna Maria MendesLeite,Ricardo Henrique de LimaSantos,Francisco Klebson Gomes doseng2020-12-08T00:00:00Zoai:scielo:S1517-70762020000400312Revistahttp://www.materia.coppe.ufrj.br/https://old.scielo.br/oai/scielo-oai.php||materia@labh2.coppe.ufrj.br1517-70761517-7076opendoar:2020-12-08T00:00Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online)false |
dc.title.none.fl_str_mv |
Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluents |
title |
Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluents |
spellingShingle |
Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluents Dantas Filho,Antonio do Nascimento Adsorption Coconut mesocarp Dye |
title_short |
Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluents |
title_full |
Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluents |
title_fullStr |
Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluents |
title_full_unstemmed |
Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluents |
title_sort |
Evaluation of adsortive potential of coconut mesocarp in the removal of reactive red dye 195 in aqueous effluents |
author |
Dantas Filho,Antonio do Nascimento |
author_facet |
Dantas Filho,Antonio do Nascimento Aroucha,Edna Maria Mendes Leite,Ricardo Henrique de Lima Santos,Francisco Klebson Gomes dos |
author_role |
author |
author2 |
Aroucha,Edna Maria Mendes Leite,Ricardo Henrique de Lima Santos,Francisco Klebson Gomes dos |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Dantas Filho,Antonio do Nascimento Aroucha,Edna Maria Mendes Leite,Ricardo Henrique de Lima Santos,Francisco Klebson Gomes dos |
dc.subject.por.fl_str_mv |
Adsorption Coconut mesocarp Dye |
topic |
Adsorption Coconut mesocarp Dye |
description |
ABSTRACT The textile industry produces dye-rich effluents that when released in hydric bodies hamper the penetration of sunlight, impairing photosynthetic processes. Besides that, dyes have been indicated as potentially toxic substances. In general, the processes of removing of these contaminants have been much studied, with the technique of adsorption standing out for its high efficiency, in addition to operational advantages and the possibility of reuse agricultural waste as adsorbents, benefiting the environment and reducing costs. The present work had as objective to study the performance of coconut mesocarp utilized as adsorbent in the bleaching process of synthetic effluent containing 25 g.L-1 of reactive red 195 dye. The adsorbent were characterized by granulometry, thermogravimetric analysis and zero point charge. Kinetic and balance study was realized, applying kinetic models and adsorption isotherms. The adsorbent exhibited removal efficiency of 89.92 % in 120 min. The maximum adsorption capacity was 24.04 g.g-1 at 30 °C. The kinetic study showed that the data was better adjusted by an Elovich equation, indicating slow chemisorption. The thermodynamic study exhibited that the adsorption process is exothermic and spontaneous for all the temperatures evaluated. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000400312 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762020000400312 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/s1517-707620200004.1152 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro em cooperação com a Associação Brasileira do Hidrogênio, ABH2 |
publisher.none.fl_str_mv |
Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro em cooperação com a Associação Brasileira do Hidrogênio, ABH2 |
dc.source.none.fl_str_mv |
Matéria (Rio de Janeiro) v.25 n.4 2020 reponame:Matéria (Rio de Janeiro. Online) instname:Matéria (Rio de Janeiro. Online) instacron:RLAM |
instname_str |
Matéria (Rio de Janeiro. Online) |
instacron_str |
RLAM |
institution |
RLAM |
reponame_str |
Matéria (Rio de Janeiro. Online) |
collection |
Matéria (Rio de Janeiro. Online) |
repository.name.fl_str_mv |
Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online) |
repository.mail.fl_str_mv |
||materia@labh2.coppe.ufrj.br |
_version_ |
1752126693470896128 |