Fine tuning of the properties of organically modified heteropolymetalates

Detalhes bibliográficos
Autor(a) principal: Perez,F.
Data de Publicação: 1997
Outros Autores: Bayle,J. P., Lafontaine,E., Judeinstein,P.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531997000100015
Resumo: Keggin-type" organically modified oxopolymetalates of formula [R]4[SiW11O40(SiR')2], (R=Bu4N+, R' = -C2H5, -C10H21, -CH=CH2, -CH2CH=CH2, -OH, -C6H5, -C10H7, -C6H4NH2 (o, p), -C6H4NMe2 (p), -C6H4CH=CH2, -C6H4CF3, -C6H4CH=CHC6H5) were synthesized. The oxide core presented reversible redox properties which were tuned by the choice of the organic modifier. Parallel variations of the 183W NMR chemical shifts were measured and both effects might be related to the electronic donor-acceptor properties of the organic radical. The magnitudes of these effects are compared with those coming from the electrolyte itself.
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spelling Fine tuning of the properties of organically modified heteropolymetalatesorganically modified oxopolymetalatesredox properties183W NMR spectroscopyKeggin-type" organically modified oxopolymetalates of formula [R]4[SiW11O40(SiR')2], (R=Bu4N+, R' = -C2H5, -C10H21, -CH=CH2, -CH2CH=CH2, -OH, -C6H5, -C10H7, -C6H4NH2 (o, p), -C6H4NMe2 (p), -C6H4CH=CH2, -C6H4CF3, -C6H4CH=CHC6H5) were synthesized. The oxide core presented reversible redox properties which were tuned by the choice of the organic modifier. Parallel variations of the 183W NMR chemical shifts were measured and both effects might be related to the electronic donor-acceptor properties of the organic radical. The magnitudes of these effects are compared with those coming from the electrolyte itself.Sociedade Brasileira de Química1997-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531997000100015Journal of the Brazilian Chemical Society v.8 n.1 1997reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50531997000100015info:eu-repo/semantics/openAccessPerez,F.Bayle,J. P.Lafontaine,E.Judeinstein,P.eng2011-10-04T00:00:00Zoai:scielo:S0103-50531997000100015Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2011-10-04T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Fine tuning of the properties of organically modified heteropolymetalates
title Fine tuning of the properties of organically modified heteropolymetalates
spellingShingle Fine tuning of the properties of organically modified heteropolymetalates
Perez,F.
organically modified oxopolymetalates
redox properties
183W NMR spectroscopy
title_short Fine tuning of the properties of organically modified heteropolymetalates
title_full Fine tuning of the properties of organically modified heteropolymetalates
title_fullStr Fine tuning of the properties of organically modified heteropolymetalates
title_full_unstemmed Fine tuning of the properties of organically modified heteropolymetalates
title_sort Fine tuning of the properties of organically modified heteropolymetalates
author Perez,F.
author_facet Perez,F.
Bayle,J. P.
Lafontaine,E.
Judeinstein,P.
author_role author
author2 Bayle,J. P.
Lafontaine,E.
Judeinstein,P.
author2_role author
author
author
dc.contributor.author.fl_str_mv Perez,F.
Bayle,J. P.
Lafontaine,E.
Judeinstein,P.
dc.subject.por.fl_str_mv organically modified oxopolymetalates
redox properties
183W NMR spectroscopy
topic organically modified oxopolymetalates
redox properties
183W NMR spectroscopy
description Keggin-type" organically modified oxopolymetalates of formula [R]4[SiW11O40(SiR')2], (R=Bu4N+, R' = -C2H5, -C10H21, -CH=CH2, -CH2CH=CH2, -OH, -C6H5, -C10H7, -C6H4NH2 (o, p), -C6H4NMe2 (p), -C6H4CH=CH2, -C6H4CF3, -C6H4CH=CHC6H5) were synthesized. The oxide core presented reversible redox properties which were tuned by the choice of the organic modifier. Parallel variations of the 183W NMR chemical shifts were measured and both effects might be related to the electronic donor-acceptor properties of the organic radical. The magnitudes of these effects are compared with those coming from the electrolyte itself.
publishDate 1997
dc.date.none.fl_str_mv 1997-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531997000100015
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531997000100015
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50531997000100015
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.8 n.1 1997
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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