Improvements in Methyl-Bambus[6]uril Synthesis Yield

Detalhes bibliográficos
Autor(a) principal: Carvalho,Julio C. C. de
Data de Publicação: 2020
Outros Autores: Cicolani,Renato S., Demets,Grégoire J.-F.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532020001102232
Resumo: Bambus[n]uril synthesis may be challenging, and it is frequently achieved with low purity and low yields. We have studied the effect of different anions on the synthesis of bambus[6]uril, especially in terms of yield, exploring template effects driven by anions in the reaction medium. The influence of the anions is evident on such syntheses and ClO4− particularly led to unprecedented synthesis yields. Computational calculations have also been used to elucidate the influence of anions on cyclization process.
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spelling Improvements in Methyl-Bambus[6]uril Synthesis Yieldbambusurilanion-templatecaviplexesBambus[n]uril synthesis may be challenging, and it is frequently achieved with low purity and low yields. We have studied the effect of different anions on the synthesis of bambus[6]uril, especially in terms of yield, exploring template effects driven by anions in the reaction medium. The influence of the anions is evident on such syntheses and ClO4− particularly led to unprecedented synthesis yields. Computational calculations have also been used to elucidate the influence of anions on cyclization process.Sociedade Brasileira de Química2020-11-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532020001102232Journal of the Brazilian Chemical Society v.31 n.11 2020reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.21577/0103-5053.20200074info:eu-repo/semantics/openAccessCarvalho,Julio C. C. deCicolani,Renato S.Demets,Grégoire J.-F.eng2020-10-27T00:00:00Zoai:scielo:S0103-50532020001102232Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2020-10-27T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Improvements in Methyl-Bambus[6]uril Synthesis Yield
title Improvements in Methyl-Bambus[6]uril Synthesis Yield
spellingShingle Improvements in Methyl-Bambus[6]uril Synthesis Yield
Carvalho,Julio C. C. de
bambusuril
anion-template
caviplexes
title_short Improvements in Methyl-Bambus[6]uril Synthesis Yield
title_full Improvements in Methyl-Bambus[6]uril Synthesis Yield
title_fullStr Improvements in Methyl-Bambus[6]uril Synthesis Yield
title_full_unstemmed Improvements in Methyl-Bambus[6]uril Synthesis Yield
title_sort Improvements in Methyl-Bambus[6]uril Synthesis Yield
author Carvalho,Julio C. C. de
author_facet Carvalho,Julio C. C. de
Cicolani,Renato S.
Demets,Grégoire J.-F.
author_role author
author2 Cicolani,Renato S.
Demets,Grégoire J.-F.
author2_role author
author
dc.contributor.author.fl_str_mv Carvalho,Julio C. C. de
Cicolani,Renato S.
Demets,Grégoire J.-F.
dc.subject.por.fl_str_mv bambusuril
anion-template
caviplexes
topic bambusuril
anion-template
caviplexes
description Bambus[n]uril synthesis may be challenging, and it is frequently achieved with low purity and low yields. We have studied the effect of different anions on the synthesis of bambus[6]uril, especially in terms of yield, exploring template effects driven by anions in the reaction medium. The influence of the anions is evident on such syntheses and ClO4− particularly led to unprecedented synthesis yields. Computational calculations have also been used to elucidate the influence of anions on cyclization process.
publishDate 2020
dc.date.none.fl_str_mv 2020-11-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
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status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532020001102232
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532020001102232
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.21577/0103-5053.20200074
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.31 n.11 2020
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
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instname_str Sociedade Brasileira de Química (SBQ)
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institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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