O sistema quimiluminescente peróxi-oxalato
Autor(a) principal: | |
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Data de Publicação: | 1999 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Química Nova (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40421999000500015 |
Resumo: | The peroxyoxalate system is still one of the most efficient chemiluminescence reactions and the only one supposed to involve the "Chemically Initiated Electron Exchange Luminescence - CIEEL" mechanism, with proved high efficiency. Besides the academic interest in the elucidation of the mechanism of this complex reaction, the peroxyoxalate system has found a variety of applications in analytical chemistry. This review contains (i) a short introduction to basic concepts in chemiluminescence, (ii) a critical summary of mechanistic studies on the peroxyoxalate reaction, (iii) and some examples of analytical applications. Although there are some recent reviews on chemiluminescence, no specific critical revision on mechanistic and analytical features of the peroxyoxalate system has been published. |
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O sistema quimiluminescente peróxi-oxalatochemiluminescenceperoxyoxalate systemCIEELThe peroxyoxalate system is still one of the most efficient chemiluminescence reactions and the only one supposed to involve the "Chemically Initiated Electron Exchange Luminescence - CIEEL" mechanism, with proved high efficiency. Besides the academic interest in the elucidation of the mechanism of this complex reaction, the peroxyoxalate system has found a variety of applications in analytical chemistry. This review contains (i) a short introduction to basic concepts in chemiluminescence, (ii) a critical summary of mechanistic studies on the peroxyoxalate reaction, (iii) and some examples of analytical applications. Although there are some recent reviews on chemiluminescence, no specific critical revision on mechanistic and analytical features of the peroxyoxalate system has been published.Sociedade Brasileira de Química1999-09-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40421999000500015Química Nova v.22 n.5 1999reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0100-40421999000500015info:eu-repo/semantics/openAccessStevani,Cassius ViniciusBaader,Wilhelm Josefpor2000-02-04T00:00:00Zoai:scielo:S0100-40421999000500015Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2000-02-04T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
O sistema quimiluminescente peróxi-oxalato |
title |
O sistema quimiluminescente peróxi-oxalato |
spellingShingle |
O sistema quimiluminescente peróxi-oxalato Stevani,Cassius Vinicius chemiluminescence peroxyoxalate system CIEEL |
title_short |
O sistema quimiluminescente peróxi-oxalato |
title_full |
O sistema quimiluminescente peróxi-oxalato |
title_fullStr |
O sistema quimiluminescente peróxi-oxalato |
title_full_unstemmed |
O sistema quimiluminescente peróxi-oxalato |
title_sort |
O sistema quimiluminescente peróxi-oxalato |
author |
Stevani,Cassius Vinicius |
author_facet |
Stevani,Cassius Vinicius Baader,Wilhelm Josef |
author_role |
author |
author2 |
Baader,Wilhelm Josef |
author2_role |
author |
dc.contributor.author.fl_str_mv |
Stevani,Cassius Vinicius Baader,Wilhelm Josef |
dc.subject.por.fl_str_mv |
chemiluminescence peroxyoxalate system CIEEL |
topic |
chemiluminescence peroxyoxalate system CIEEL |
description |
The peroxyoxalate system is still one of the most efficient chemiluminescence reactions and the only one supposed to involve the "Chemically Initiated Electron Exchange Luminescence - CIEEL" mechanism, with proved high efficiency. Besides the academic interest in the elucidation of the mechanism of this complex reaction, the peroxyoxalate system has found a variety of applications in analytical chemistry. This review contains (i) a short introduction to basic concepts in chemiluminescence, (ii) a critical summary of mechanistic studies on the peroxyoxalate reaction, (iii) and some examples of analytical applications. Although there are some recent reviews on chemiluminescence, no specific critical revision on mechanistic and analytical features of the peroxyoxalate system has been published. |
publishDate |
1999 |
dc.date.none.fl_str_mv |
1999-09-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40421999000500015 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40421999000500015 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
10.1590/S0100-40421999000500015 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Química Nova v.22 n.5 1999 reponame:Química Nova (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Química Nova (Online) |
collection |
Química Nova (Online) |
repository.name.fl_str_mv |
Química Nova (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
quimicanova@sbq.org.br |
_version_ |
1750318101227896832 |