Desidratação de etanol sobre material nanoestruturado do tipo LaSBA-15

Detalhes bibliográficos
Autor(a) principal: Luz Jr,Geraldo E.
Data de Publicação: 2010
Outros Autores: Melo,Ana C. R., Lima,Stevie H., Araujo,Antônio S., Fernandes Jr.,Valter J.
Tipo de documento: Artigo
Idioma: por
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000800005
Resumo: La-incorporated SBA-15 mesopourous molecular sieves (LaSBA-15) were directly synthesized with aim to convert ethanol to ethylene. The samples were characterized by XRD, XRF, nitrogen sorption and acidity, by thermodesorption of n-buthylamine. The results have indicated that all the samples have showed high ordered mesostructure with a large average pore size, and that the lanthanum incorporation has caused an increase in the acidity of the SBA-15. The LaSBA-15 samples have improved, with low deactivation rate, the conversion of the ethanol to water, ether, acetaldehyde and ethylene. In addition, they have increased the ethylene selectivity.
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spelling Desidratação de etanol sobre material nanoestruturado do tipo LaSBA-15ethanol dehydrationLaSBA-15ethyleneLa-incorporated SBA-15 mesopourous molecular sieves (LaSBA-15) were directly synthesized with aim to convert ethanol to ethylene. The samples were characterized by XRD, XRF, nitrogen sorption and acidity, by thermodesorption of n-buthylamine. The results have indicated that all the samples have showed high ordered mesostructure with a large average pore size, and that the lanthanum incorporation has caused an increase in the acidity of the SBA-15. The LaSBA-15 samples have improved, with low deactivation rate, the conversion of the ethanol to water, ether, acetaldehyde and ethylene. In addition, they have increased the ethylene selectivity.Sociedade Brasileira de Química2010-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000800005Química Nova v.33 n.8 2010reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0100-40422010000800005info:eu-repo/semantics/openAccessLuz Jr,Geraldo E.Melo,Ana C. R.Lima,Stevie H.Araujo,Antônio S.Fernandes Jr.,Valter J.por2010-10-25T00:00:00Zoai:scielo:S0100-40422010000800005Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2010-10-25T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Desidratação de etanol sobre material nanoestruturado do tipo LaSBA-15
title Desidratação de etanol sobre material nanoestruturado do tipo LaSBA-15
spellingShingle Desidratação de etanol sobre material nanoestruturado do tipo LaSBA-15
Luz Jr,Geraldo E.
ethanol dehydration
LaSBA-15
ethylene
title_short Desidratação de etanol sobre material nanoestruturado do tipo LaSBA-15
title_full Desidratação de etanol sobre material nanoestruturado do tipo LaSBA-15
title_fullStr Desidratação de etanol sobre material nanoestruturado do tipo LaSBA-15
title_full_unstemmed Desidratação de etanol sobre material nanoestruturado do tipo LaSBA-15
title_sort Desidratação de etanol sobre material nanoestruturado do tipo LaSBA-15
author Luz Jr,Geraldo E.
author_facet Luz Jr,Geraldo E.
Melo,Ana C. R.
Lima,Stevie H.
Araujo,Antônio S.
Fernandes Jr.,Valter J.
author_role author
author2 Melo,Ana C. R.
Lima,Stevie H.
Araujo,Antônio S.
Fernandes Jr.,Valter J.
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Luz Jr,Geraldo E.
Melo,Ana C. R.
Lima,Stevie H.
Araujo,Antônio S.
Fernandes Jr.,Valter J.
dc.subject.por.fl_str_mv ethanol dehydration
LaSBA-15
ethylene
topic ethanol dehydration
LaSBA-15
ethylene
description La-incorporated SBA-15 mesopourous molecular sieves (LaSBA-15) were directly synthesized with aim to convert ethanol to ethylene. The samples were characterized by XRD, XRF, nitrogen sorption and acidity, by thermodesorption of n-buthylamine. The results have indicated that all the samples have showed high ordered mesostructure with a large average pore size, and that the lanthanum incorporation has caused an increase in the acidity of the SBA-15. The LaSBA-15 samples have improved, with low deactivation rate, the conversion of the ethanol to water, ether, acetaldehyde and ethylene. In addition, they have increased the ethylene selectivity.
publishDate 2010
dc.date.none.fl_str_mv 2010-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000800005
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000800005
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv 10.1590/S0100-40422010000800005
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.33 n.8 2010
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
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