HIDRÓXISSAIS LAMELARES (Cu2+ ou Zn2+) COMO AGENTES DE REFORÇO EM FILMES FINOS DE ALGINATO
Autor(a) principal: | |
---|---|
Data de Publicação: | 2018 |
Tipo de documento: | Dissertação |
Idioma: | por |
Título da fonte: | Biblioteca Digital de Teses e Dissertações do UNICENTRO |
Texto Completo: | http://tede.unicentro.br:8080/jspui/handle/jspui/1013 |
Resumo: | The environmental problems are growing up in the last decades because of the increase in solid waste generation around the world. This fact has alerted entities and researchers in several areas to the search for the development of new materials that provide alternatives to mitigate these impacts, use of polymeric matrices derived from renewable sources began to gain prominence in this scenario. Among them, the alginate has been studied and shows promise for the development of these new materials. Also, to improve the performance of these matrices, there is the possibility of incorporating reinforcing agents, such as plasticizers, which act to provide greater flexibility, and the layered compounds, which give to the polymer matrices better characteristics in mechanical, chemical, optical, among other properties. From this, in this study, alginate composites, containing glycerol and layered hydroxides salts (with and without dyes molecules intercalated in the structure) were synthesized as reinforcing agents. The materials were characterized by X-ray diffractometry, ultraviolet and mid-infrared spectroscopy, colorimetry, scanning electron microscopy, traction resistance test and cryogenic break. The analysis of the hydroxide salts has shown that the HSL's was obtained and the intercalation process are effective, especially the zinc hydroxynitrate and the dye Orange G. As for the composites, it can be said that, in general, there was interaction between the phases (load-matrix), with emphasis on the load contents set at 4%. |
id |
UCEN_128751fc5b923163b45b4dad1dc1a2c8 |
---|---|
oai_identifier_str |
oai:localhost:jspui/1013 |
network_acronym_str |
UCEN |
network_name_str |
Biblioteca Digital de Teses e Dissertações do UNICENTRO |
repository_id_str |
|
spelling |
Marangoni, Rafaelhttp://lattes.cnpq.br/2308700333314623395.129.968-12http://lattes.cnpq.br/4220715189606232Passos, Elthon Ferreira2019-04-26T13:08:10Z2018-02-20Passos, Elthon Ferreira. HIDRÓXISSAIS LAMELARES (Cu2+ ou Zn2+) COMO AGENTES DE REFORÇO EM FILMES FINOS DE ALGINATO. 2018. 86 f. Dissertação (Programa de Pós-Graduação em Química - Mestrado) - Universidade Estadual do Centro-Oeste, Guarapuava - PR.http://tede.unicentro.br:8080/jspui/handle/jspui/1013The environmental problems are growing up in the last decades because of the increase in solid waste generation around the world. This fact has alerted entities and researchers in several areas to the search for the development of new materials that provide alternatives to mitigate these impacts, use of polymeric matrices derived from renewable sources began to gain prominence in this scenario. Among them, the alginate has been studied and shows promise for the development of these new materials. Also, to improve the performance of these matrices, there is the possibility of incorporating reinforcing agents, such as plasticizers, which act to provide greater flexibility, and the layered compounds, which give to the polymer matrices better characteristics in mechanical, chemical, optical, among other properties. From this, in this study, alginate composites, containing glycerol and layered hydroxides salts (with and without dyes molecules intercalated in the structure) were synthesized as reinforcing agents. The materials were characterized by X-ray diffractometry, ultraviolet and mid-infrared spectroscopy, colorimetry, scanning electron microscopy, traction resistance test and cryogenic break. The analysis of the hydroxide salts has shown that the HSL's was obtained and the intercalation process are effective, especially the zinc hydroxynitrate and the dye Orange G. As for the composites, it can be said that, in general, there was interaction between the phases (load-matrix), with emphasis on the load contents set at 4%.O crescimento dos problemas ambientais nas últimas décadas, consequentes do forte aumento na geração de resíduos sólidos em todo o mundo, alertou entidades e pesquisadores de diversas áreas para a busca pelo desenvolvimento de novos materiais, que proporcionem alternativas de mitigar estes impactos, assim, a utilização de matrizes poliméricas oriundas de fontes renováveis passou a ganhar destaque neste cenário. Dentre elas, o alginato vem sendo estudado e se mostra promissor para o desenvolvimento destes novos materiais. Ainda, como forma de melhorar a performance destas matrizes, há a possibilidade de incorporação de agentes reforçadores, como os plastificantes, que atuam fornecendo maior flexibilidade aos mesmos, e os compostos lamelares, que dão às matrizes poliméricas melhores características em propriedades mecânicas, físico-químicas, ópticas entre outras. A partir disto, neste trabalho foram sintetizados compósitos de alginato, contendo glicerol e hidroxissais lamelares (com e sem moléculas de corantes intercaladas na estrutura) como agentes de reforço. Os materiais foram caracterizados por Difratometria de raios X, Espectroscopia na região do ultravioleta e infravermelho médio, Colorimetria, Microscopia eletrônica de varredura, Ensaio mecânico de tração e Quebra criogênica. As análises dos hidroxissais, mostram que os HSL’s foram obtidos e que os processos de intercalação foram efetivos, com destaque para o Hidróxinitrato de Zinco e o corante Alaranjado G. Quanto aos compósitos, pode-se dizer que, de modo geral, houve interação entre as fases (carga-matriz), com destaque para os teores de carga fixados em 4%.Submitted by Fabiano Jucá (fjuca@unicentro.br) on 2019-04-26T13:08:10Z No. of bitstreams: 1 Elthon Ferreira Passos.pdf: 4543368 bytes, checksum: 213aeb4c4a0470b2921cf317eede9db1 (MD5)Made available in DSpace on 2019-04-26T13:08:10Z (GMT). No. of bitstreams: 1 Elthon Ferreira Passos.pdf: 4543368 bytes, checksum: 213aeb4c4a0470b2921cf317eede9db1 (MD5) Previous issue date: 2018-02-20Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPESapplication/pdfhttp://tede.unicentro.br:8080/jspui/retrieve/4488/Elthon%20Ferreira%20Passos.pdf.jpgporUniversidade Estadual do Centro-OestePrograma de Pós-Graduação em Química (Mestrado)UNICENTROBrasilUnicentro::Departamento de QuímicaUnicentro::Departamento de Ciências Exatas e de TecnologiaBiopolímerosReforçoHSLFilmesCorantesBiopolymersReinforcementHSLFilmsDyesCIENCIAS EXATAS E DA TERRA::QUIMICAHIDRÓXISSAIS LAMELARES (Cu2+ ou Zn2+) COMO AGENTES DE REFORÇO EM FILMES FINOS DE ALGINATOinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesis-5600948132407545169600600600600600-7583084308588456361-433806549027752903315717003253031171952075167498588264571info:eu-repo/semantics/openAccessreponame:Biblioteca Digital de Teses e Dissertações do UNICENTROinstname:Universidade Estadual do Centro-Oeste (UNICENTRO)instacron:UNICENTROTHUMBNAILElthon Ferreira Passos.pdf.jpgElthon Ferreira Passos.pdf.jpgimage/jpeg1943http://localhost:8080/tede/bitstream/jspui/1013/4/Elthon+Ferreira+Passos.pdf.jpgcc73c4c239a4c332d642ba1e7c7a9fb2MD54TEXTElthon Ferreira Passos.pdf.txtElthon Ferreira Passos.pdf.txttext/plain118596http://localhost:8080/tede/bitstream/jspui/1013/3/Elthon+Ferreira+Passos.pdf.txt7dddfb12028a70391f7146ac5398f8f7MD53ORIGINALElthon Ferreira Passos.pdfElthon Ferreira Passos.pdfapplication/pdf4543368http://localhost:8080/tede/bitstream/jspui/1013/2/Elthon+Ferreira+Passos.pdf213aeb4c4a0470b2921cf317eede9db1MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-82165http://localhost:8080/tede/bitstream/jspui/1013/1/license.txtbd3efa91386c1718a7f26a329fdcb468MD51jspui/10132020-07-08 01:08:47.011oai:localhost: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Biblioteca Digital de Teses e Dissertaçõeshttp://tede.unicentro.br:8080/jspui/PUBhttp://tede.unicentro.br/tde_oai/oai3.phprepositorio@unicentro.br||fabianoqueiroz@yahoo.com.bropendoar:2020-07-08T04:08:47Biblioteca Digital de Teses e Dissertações do UNICENTRO - Universidade Estadual do Centro-Oeste (UNICENTRO)false |
dc.title.por.fl_str_mv |
HIDRÓXISSAIS LAMELARES (Cu2+ ou Zn2+) COMO AGENTES DE REFORÇO EM FILMES FINOS DE ALGINATO |
title |
HIDRÓXISSAIS LAMELARES (Cu2+ ou Zn2+) COMO AGENTES DE REFORÇO EM FILMES FINOS DE ALGINATO |
spellingShingle |
HIDRÓXISSAIS LAMELARES (Cu2+ ou Zn2+) COMO AGENTES DE REFORÇO EM FILMES FINOS DE ALGINATO Passos, Elthon Ferreira Biopolímeros Reforço HSL Filmes Corantes Biopolymers Reinforcement HSL Films Dyes CIENCIAS EXATAS E DA TERRA::QUIMICA |
title_short |
HIDRÓXISSAIS LAMELARES (Cu2+ ou Zn2+) COMO AGENTES DE REFORÇO EM FILMES FINOS DE ALGINATO |
title_full |
HIDRÓXISSAIS LAMELARES (Cu2+ ou Zn2+) COMO AGENTES DE REFORÇO EM FILMES FINOS DE ALGINATO |
title_fullStr |
HIDRÓXISSAIS LAMELARES (Cu2+ ou Zn2+) COMO AGENTES DE REFORÇO EM FILMES FINOS DE ALGINATO |
title_full_unstemmed |
HIDRÓXISSAIS LAMELARES (Cu2+ ou Zn2+) COMO AGENTES DE REFORÇO EM FILMES FINOS DE ALGINATO |
title_sort |
HIDRÓXISSAIS LAMELARES (Cu2+ ou Zn2+) COMO AGENTES DE REFORÇO EM FILMES FINOS DE ALGINATO |
author |
Passos, Elthon Ferreira |
author_facet |
Passos, Elthon Ferreira |
author_role |
author |
dc.contributor.advisor1.fl_str_mv |
Marangoni, Rafael |
dc.contributor.advisor1Lattes.fl_str_mv |
http://lattes.cnpq.br/2308700333314623 |
dc.contributor.authorID.fl_str_mv |
395.129.968-12 |
dc.contributor.authorLattes.fl_str_mv |
http://lattes.cnpq.br/4220715189606232 |
dc.contributor.author.fl_str_mv |
Passos, Elthon Ferreira |
contributor_str_mv |
Marangoni, Rafael |
dc.subject.por.fl_str_mv |
Biopolímeros Reforço HSL Filmes Corantes |
topic |
Biopolímeros Reforço HSL Filmes Corantes Biopolymers Reinforcement HSL Films Dyes CIENCIAS EXATAS E DA TERRA::QUIMICA |
dc.subject.eng.fl_str_mv |
Biopolymers Reinforcement HSL Films Dyes |
dc.subject.cnpq.fl_str_mv |
CIENCIAS EXATAS E DA TERRA::QUIMICA |
description |
The environmental problems are growing up in the last decades because of the increase in solid waste generation around the world. This fact has alerted entities and researchers in several areas to the search for the development of new materials that provide alternatives to mitigate these impacts, use of polymeric matrices derived from renewable sources began to gain prominence in this scenario. Among them, the alginate has been studied and shows promise for the development of these new materials. Also, to improve the performance of these matrices, there is the possibility of incorporating reinforcing agents, such as plasticizers, which act to provide greater flexibility, and the layered compounds, which give to the polymer matrices better characteristics in mechanical, chemical, optical, among other properties. From this, in this study, alginate composites, containing glycerol and layered hydroxides salts (with and without dyes molecules intercalated in the structure) were synthesized as reinforcing agents. The materials were characterized by X-ray diffractometry, ultraviolet and mid-infrared spectroscopy, colorimetry, scanning electron microscopy, traction resistance test and cryogenic break. The analysis of the hydroxide salts has shown that the HSL's was obtained and the intercalation process are effective, especially the zinc hydroxynitrate and the dye Orange G. As for the composites, it can be said that, in general, there was interaction between the phases (load-matrix), with emphasis on the load contents set at 4%. |
publishDate |
2018 |
dc.date.issued.fl_str_mv |
2018-02-20 |
dc.date.accessioned.fl_str_mv |
2019-04-26T13:08:10Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/masterThesis |
format |
masterThesis |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
Passos, Elthon Ferreira. HIDRÓXISSAIS LAMELARES (Cu2+ ou Zn2+) COMO AGENTES DE REFORÇO EM FILMES FINOS DE ALGINATO. 2018. 86 f. Dissertação (Programa de Pós-Graduação em Química - Mestrado) - Universidade Estadual do Centro-Oeste, Guarapuava - PR. |
dc.identifier.uri.fl_str_mv |
http://tede.unicentro.br:8080/jspui/handle/jspui/1013 |
identifier_str_mv |
Passos, Elthon Ferreira. HIDRÓXISSAIS LAMELARES (Cu2+ ou Zn2+) COMO AGENTES DE REFORÇO EM FILMES FINOS DE ALGINATO. 2018. 86 f. Dissertação (Programa de Pós-Graduação em Química - Mestrado) - Universidade Estadual do Centro-Oeste, Guarapuava - PR. |
url |
http://tede.unicentro.br:8080/jspui/handle/jspui/1013 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.program.fl_str_mv |
-5600948132407545169 |
dc.relation.confidence.fl_str_mv |
600 600 600 600 600 |
dc.relation.department.fl_str_mv |
-7583084308588456361 -4338065490277529033 |
dc.relation.cnpq.fl_str_mv |
1571700325303117195 |
dc.relation.sponsorship.fl_str_mv |
2075167498588264571 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Estadual do Centro-Oeste |
dc.publisher.program.fl_str_mv |
Programa de Pós-Graduação em Química (Mestrado) |
dc.publisher.initials.fl_str_mv |
UNICENTRO |
dc.publisher.country.fl_str_mv |
Brasil |
dc.publisher.department.fl_str_mv |
Unicentro::Departamento de Química Unicentro::Departamento de Ciências Exatas e de Tecnologia |
publisher.none.fl_str_mv |
Universidade Estadual do Centro-Oeste |
dc.source.none.fl_str_mv |
reponame:Biblioteca Digital de Teses e Dissertações do UNICENTRO instname:Universidade Estadual do Centro-Oeste (UNICENTRO) instacron:UNICENTRO |
instname_str |
Universidade Estadual do Centro-Oeste (UNICENTRO) |
instacron_str |
UNICENTRO |
institution |
UNICENTRO |
reponame_str |
Biblioteca Digital de Teses e Dissertações do UNICENTRO |
collection |
Biblioteca Digital de Teses e Dissertações do UNICENTRO |
bitstream.url.fl_str_mv |
http://localhost:8080/tede/bitstream/jspui/1013/4/Elthon+Ferreira+Passos.pdf.jpg http://localhost:8080/tede/bitstream/jspui/1013/3/Elthon+Ferreira+Passos.pdf.txt http://localhost:8080/tede/bitstream/jspui/1013/2/Elthon+Ferreira+Passos.pdf http://localhost:8080/tede/bitstream/jspui/1013/1/license.txt |
bitstream.checksum.fl_str_mv |
cc73c4c239a4c332d642ba1e7c7a9fb2 7dddfb12028a70391f7146ac5398f8f7 213aeb4c4a0470b2921cf317eede9db1 bd3efa91386c1718a7f26a329fdcb468 |
bitstream.checksumAlgorithm.fl_str_mv |
MD5 MD5 MD5 MD5 |
repository.name.fl_str_mv |
Biblioteca Digital de Teses e Dissertações do UNICENTRO - Universidade Estadual do Centro-Oeste (UNICENTRO) |
repository.mail.fl_str_mv |
repositorio@unicentro.br||fabianoqueiroz@yahoo.com.br |
_version_ |
1801859373507543040 |