VALORES DE REFERÊNCIA DE QUALIDADE DE METAIS, MACROELEMENTOS E RADIONUCLÍDEOS EM SOLOS DO OESTE DO PARANÁ
Autor(a) principal: | |
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Data de Publicação: | 2019 |
Tipo de documento: | Tese |
Idioma: | por |
Título da fonte: | Biblioteca Digital de Teses e Dissertações do UNICENTRO |
Texto Completo: | http://tede.unicentro.br:8080/jspui/handle/jspui/995 |
Resumo: | The metals and the macroelements of the soils are naturally derived from the decomposition of the rocks of origin, concomitant to the variations in the intensity of the pedogenic processes. In addition, all minerals and raw materials contain radionuclides of natural origin. In this context, the current legislation requires environmental indicators, Quality Reference Values - QRV, with local or regional soil characteristics that can serve as a reference for monitoring studies. The use of values obtained in different areas of the data collection site is inappropriate, since they disregard geological, pedological and climatic differences of each scenario. The objective of this research was to determine the levels of metals, macroelements and radionuclides in preserved Soils of Environmental and Remnant Forest Preservation Units in the Paraná Basin 3 (BP3), in order to obtain natural base levels for these elements and to contribute for state legislation. Inorganic constituents were determined in 73 sampled points, among them metals, macroelements and radionuclides: Ag, Al, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Mo, Ni, P, Pb, Sb, V, Zn, 232Th, 238U and 40K. Inductively Coupled Plasma – Optical Emission Spectrometry (ICP-OES) and Gamma Spectrometry (GRS) techniques were used in the quantification of the elements. The QRV were obtained for metals and radionuclides in the 75th percentile. With the exception of Sb and Cu, the natural contents of all the elements studied are below the Prevention Values suggested by the National Environmental Council (CONAMA, 2009). The correlation study showed several associations between the elements that can be attributed to the origin and pedogenic nature of the soil, similarity in the size and valence of the ions and the geochemical affinities. In general, the BP3 metals, macroelements and radionuclides contents were associated with the level of soil development and basaltic volcanic spills of the Serra Geral Formation. |
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Quináia, Sueli Pérciohttp://lattes.cnpq.br/3256907601004018Pletsch, Adelmo Lowehttp://lattes.cnpq.br/1731491755917260025.274.949-94http://lattes.cnpq.br/5629436606338676Bocardi, Juliane Maria Bergamin2019-04-16T13:34:07Z2019-02-18Bocardi, Juliane Maria Bergamin. VALORES DE REFERÊNCIA DE QUALIDADE DE METAIS, MACROELEMENTOS E RADIONUCLÍDEOS EM SOLOS DO OESTE DO PARANÁ. 2019. 106 f. Tese (Programa de Pós-Graduação em Química (Doutorado) - Universidade Estadual do Centro-Oeste, Guarapuava - PR.http://tede.unicentro.br:8080/jspui/handle/jspui/995The metals and the macroelements of the soils are naturally derived from the decomposition of the rocks of origin, concomitant to the variations in the intensity of the pedogenic processes. In addition, all minerals and raw materials contain radionuclides of natural origin. In this context, the current legislation requires environmental indicators, Quality Reference Values - QRV, with local or regional soil characteristics that can serve as a reference for monitoring studies. The use of values obtained in different areas of the data collection site is inappropriate, since they disregard geological, pedological and climatic differences of each scenario. The objective of this research was to determine the levels of metals, macroelements and radionuclides in preserved Soils of Environmental and Remnant Forest Preservation Units in the Paraná Basin 3 (BP3), in order to obtain natural base levels for these elements and to contribute for state legislation. Inorganic constituents were determined in 73 sampled points, among them metals, macroelements and radionuclides: Ag, Al, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Mo, Ni, P, Pb, Sb, V, Zn, 232Th, 238U and 40K. Inductively Coupled Plasma – Optical Emission Spectrometry (ICP-OES) and Gamma Spectrometry (GRS) techniques were used in the quantification of the elements. The QRV were obtained for metals and radionuclides in the 75th percentile. With the exception of Sb and Cu, the natural contents of all the elements studied are below the Prevention Values suggested by the National Environmental Council (CONAMA, 2009). The correlation study showed several associations between the elements that can be attributed to the origin and pedogenic nature of the soil, similarity in the size and valence of the ions and the geochemical affinities. In general, the BP3 metals, macroelements and radionuclides contents were associated with the level of soil development and basaltic volcanic spills of the Serra Geral Formation.Os metais e os macroelementos dos solos são naturalmente provenientes da decomposição das rochas de origem, concomitante às variações na intensidade dos processos pedogênicos. Além disso, todos os minerais e matérias-primas contêm radionuclídeos de origem natural. Neste contexto, a legislação vigente necessita de indicadores ambientais, Valores de Referência de Qualidade – VRQ, com as características pedológicas locais ou regionais capazes de servir como referência para estudos de monitoramento. O uso de valores obtidos em áreas diferentes do local de obtenção dos dados é inapropriado, já que desconsideram diferenças geológicas, pedológicas e climáticas de cada cenário. Deste modo, essa pesquisa objetivou a determinação dos teores de metais, macroelementos e radionuclídeos em solos preservados de Unidades de Conservação Ambientais e Remanescentes Florestais na Bacia do Paraná 3 (BP3), com o intuito de obter níveis de base naturais para estes elementos e contribuir para a legislação estadual. Foram determinados 23 constituintes inorgânicos em 73 pontos amostrados, entre eles metais, macroelementos e radionuclídeos: Ag, Al, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Mo, Ni, P, Pb, Sb, V, Zn, 232Th, 238U e 40K. Utilizaram-se técnicas de Espectroscopia de Emissão Óptica com Plasma Induzido (ICP-OES) e Espectrometria Gama na quantificação dos elementos. Os VRQ foram obtidos para os metais e para os radionuclídeos no percentil 75. Com exceção de Sb e Cu, os teores naturais de todos os elementos estudados estão abaixo dos Valores de Prevenção sugeridos pelo Conselho Nacional do Meio Ambiente (CONAMA, 2009). O estudo de correlação mostrou diversas associações entre os elementos que podem ser atribuídas à origem e natureza pedogênica do solo, similaridade no tamanho e valência dos íons e às afinidades geoquímicas. Em geral, os teores de metais, macroelementos e radionuclídeos da BP3 foram associados ao nível de desenvolvimento do solo e aos derrames vulcânicos, do tipo basáltico, da Formação Serra Geral.Submitted by Fabiano Jucá (fjuca@unicentro.br) on 2019-04-16T13:34:07Z No. of bitstreams: 1 JULIANE MARIA BERGAMIN BOCARDI.pdf: 4352528 bytes, checksum: eb9a8ece1077a97357f064278b6194aa (MD5)Made available in DSpace on 2019-04-16T13:34:07Z (GMT). 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dc.title.por.fl_str_mv |
VALORES DE REFERÊNCIA DE QUALIDADE DE METAIS, MACROELEMENTOS E RADIONUCLÍDEOS EM SOLOS DO OESTE DO PARANÁ |
title |
VALORES DE REFERÊNCIA DE QUALIDADE DE METAIS, MACROELEMENTOS E RADIONUCLÍDEOS EM SOLOS DO OESTE DO PARANÁ |
spellingShingle |
VALORES DE REFERÊNCIA DE QUALIDADE DE METAIS, MACROELEMENTOS E RADIONUCLÍDEOS EM SOLOS DO OESTE DO PARANÁ Bocardi, Juliane Maria Bergamin Solos Radionuclídeos Metais Valores de Referência Soils, Radionuclides Metals Reference Values CIENCIAS EXATAS E DA TERRA::QUIMICA |
title_short |
VALORES DE REFERÊNCIA DE QUALIDADE DE METAIS, MACROELEMENTOS E RADIONUCLÍDEOS EM SOLOS DO OESTE DO PARANÁ |
title_full |
VALORES DE REFERÊNCIA DE QUALIDADE DE METAIS, MACROELEMENTOS E RADIONUCLÍDEOS EM SOLOS DO OESTE DO PARANÁ |
title_fullStr |
VALORES DE REFERÊNCIA DE QUALIDADE DE METAIS, MACROELEMENTOS E RADIONUCLÍDEOS EM SOLOS DO OESTE DO PARANÁ |
title_full_unstemmed |
VALORES DE REFERÊNCIA DE QUALIDADE DE METAIS, MACROELEMENTOS E RADIONUCLÍDEOS EM SOLOS DO OESTE DO PARANÁ |
title_sort |
VALORES DE REFERÊNCIA DE QUALIDADE DE METAIS, MACROELEMENTOS E RADIONUCLÍDEOS EM SOLOS DO OESTE DO PARANÁ |
author |
Bocardi, Juliane Maria Bergamin |
author_facet |
Bocardi, Juliane Maria Bergamin |
author_role |
author |
dc.contributor.advisor1.fl_str_mv |
Quináia, Sueli Pércio |
dc.contributor.advisor1Lattes.fl_str_mv |
http://lattes.cnpq.br/3256907601004018 |
dc.contributor.advisor-co1.fl_str_mv |
Pletsch, Adelmo Lowe |
dc.contributor.advisor-co1Lattes.fl_str_mv |
http://lattes.cnpq.br/1731491755917260 |
dc.contributor.authorID.fl_str_mv |
025.274.949-94 |
dc.contributor.authorLattes.fl_str_mv |
http://lattes.cnpq.br/5629436606338676 |
dc.contributor.author.fl_str_mv |
Bocardi, Juliane Maria Bergamin |
contributor_str_mv |
Quináia, Sueli Pércio Pletsch, Adelmo Lowe |
dc.subject.por.fl_str_mv |
Solos Radionuclídeos Metais Valores de Referência |
topic |
Solos Radionuclídeos Metais Valores de Referência Soils, Radionuclides Metals Reference Values CIENCIAS EXATAS E DA TERRA::QUIMICA |
dc.subject.eng.fl_str_mv |
Soils, Radionuclides Metals Reference Values |
dc.subject.cnpq.fl_str_mv |
CIENCIAS EXATAS E DA TERRA::QUIMICA |
description |
The metals and the macroelements of the soils are naturally derived from the decomposition of the rocks of origin, concomitant to the variations in the intensity of the pedogenic processes. In addition, all minerals and raw materials contain radionuclides of natural origin. In this context, the current legislation requires environmental indicators, Quality Reference Values - QRV, with local or regional soil characteristics that can serve as a reference for monitoring studies. The use of values obtained in different areas of the data collection site is inappropriate, since they disregard geological, pedological and climatic differences of each scenario. The objective of this research was to determine the levels of metals, macroelements and radionuclides in preserved Soils of Environmental and Remnant Forest Preservation Units in the Paraná Basin 3 (BP3), in order to obtain natural base levels for these elements and to contribute for state legislation. Inorganic constituents were determined in 73 sampled points, among them metals, macroelements and radionuclides: Ag, Al, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Mo, Ni, P, Pb, Sb, V, Zn, 232Th, 238U and 40K. Inductively Coupled Plasma – Optical Emission Spectrometry (ICP-OES) and Gamma Spectrometry (GRS) techniques were used in the quantification of the elements. The QRV were obtained for metals and radionuclides in the 75th percentile. With the exception of Sb and Cu, the natural contents of all the elements studied are below the Prevention Values suggested by the National Environmental Council (CONAMA, 2009). The correlation study showed several associations between the elements that can be attributed to the origin and pedogenic nature of the soil, similarity in the size and valence of the ions and the geochemical affinities. In general, the BP3 metals, macroelements and radionuclides contents were associated with the level of soil development and basaltic volcanic spills of the Serra Geral Formation. |
publishDate |
2019 |
dc.date.accessioned.fl_str_mv |
2019-04-16T13:34:07Z |
dc.date.issued.fl_str_mv |
2019-02-18 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/doctoralThesis |
format |
doctoralThesis |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
Bocardi, Juliane Maria Bergamin. VALORES DE REFERÊNCIA DE QUALIDADE DE METAIS, MACROELEMENTOS E RADIONUCLÍDEOS EM SOLOS DO OESTE DO PARANÁ. 2019. 106 f. Tese (Programa de Pós-Graduação em Química (Doutorado) - Universidade Estadual do Centro-Oeste, Guarapuava - PR. |
dc.identifier.uri.fl_str_mv |
http://tede.unicentro.br:8080/jspui/handle/jspui/995 |
identifier_str_mv |
Bocardi, Juliane Maria Bergamin. VALORES DE REFERÊNCIA DE QUALIDADE DE METAIS, MACROELEMENTOS E RADIONUCLÍDEOS EM SOLOS DO OESTE DO PARANÁ. 2019. 106 f. Tese (Programa de Pós-Graduação em Química (Doutorado) - Universidade Estadual do Centro-Oeste, Guarapuava - PR. |
url |
http://tede.unicentro.br:8080/jspui/handle/jspui/995 |
dc.language.iso.fl_str_mv |
por |
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por |
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3800526532796635565 |
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600 600 600 600 |
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info:eu-repo/semantics/openAccess |
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openAccess |
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application/pdf |
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Universidade Estadual do Centro-Oeste |
dc.publisher.program.fl_str_mv |
Programa de Pós-Graduação em Química (Doutorado) |
dc.publisher.initials.fl_str_mv |
UNICENTRO |
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Brasil |
dc.publisher.department.fl_str_mv |
Unicentro::Departamento de Ciências Exatas e de Tecnologia |
publisher.none.fl_str_mv |
Universidade Estadual do Centro-Oeste |
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