Application of chemical precipitation, metallic exchange and Fenton’s reagent in photographic wastewaters treatment
Autor(a) principal: | |
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Data de Publicação: | 2007 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Acta scientiarum. Technology (Online) |
Texto Completo: | http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/82 |
Resumo: | Photographic, graphic and radiographic wastewaters contain, in its composition, silver and organic compounds that confer a high organic content. Those wastewaters are, commonly, treated for silver removal, but the organic matter also needs to be reduced, since the chemical oxygen demand (COD) is close to 120,000 mg O2 L-1.Therefore, the objective of this work is to study some processes capable of reducing the silver and COD photographic wastewaters concentrations. The precipitation with sodium sulfide (Na2S) and sodium chloride (NaCl), metallic replacement and advanced oxidation with Fenton’s reagent were studied The results showed that the Na2S precipitation and metallic replacement promoted the best silver removal, close to 100%, and the COD removal was around 10%. The experiments with NaCl did not promote satisfactory silver and COD removal and the Fenton’s reagent removed 40 and 70% of COD and silver concentrations, respectively. |
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Application of chemical precipitation, metallic exchange and Fenton’s reagent in photographic wastewaters treatmentAplicação de precipitação química, troca metálica e reagente Fenton no tratamento de efluentes fotográficos - DOI: 10.4025/actascitechnol.v29i1.82remoção de pratadegradação da matéria orgânicatratamento de efluentesprocessos químicosreagente FentonPhotographic, graphic and radiographic wastewaters contain, in its composition, silver and organic compounds that confer a high organic content. Those wastewaters are, commonly, treated for silver removal, but the organic matter also needs to be reduced, since the chemical oxygen demand (COD) is close to 120,000 mg O2 L-1.Therefore, the objective of this work is to study some processes capable of reducing the silver and COD photographic wastewaters concentrations. The precipitation with sodium sulfide (Na2S) and sodium chloride (NaCl), metallic replacement and advanced oxidation with Fenton’s reagent were studied The results showed that the Na2S precipitation and metallic replacement promoted the best silver removal, close to 100%, and the COD removal was around 10%. The experiments with NaCl did not promote satisfactory silver and COD removal and the Fenton’s reagent removed 40 and 70% of COD and silver concentrations, respectively.Efluentes fotográficos, gráficos e radiográficos apresentam, em sua composição, prata e compostos orgânicos que conferem elevada carga orgânica. Esses efluentes são, freqüentemente tratados com o objetivo de remoção da prata. Porém, a matéria orgânica também precisa ser reduzida, uma vez que a demanda química de oxigênio (DQO) é de aproximadamente 120.000 mg O2 L-1. Assim, o presente trabalho objetivou o estudo de processos capazes de reduzir as concentrações de prata e DQO de efluentes fotográficos. Foram estudados os processos de precipitação com sulfeto de sódio (Na2S) e cloreto de sódio (NaCl), troca metálica e oxidação avançada com reagente Fenton. Os resultados indicaram que os processos de precipitação com Na2S e troca metálica promoveram remoções de prata de aproximadamente 100% e de DQO em torno de 10%. Os testes com NaCl promoveram remoções pouco satisfatórias de prata e DQO e o reagente Fenton removeu 40 e 70% de DQO e prata, respectivamente.Universidade Estadual De Maringá2007-12-18info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/8210.4025/actascitechnol.v29i1.82Acta Scientiarum. Technology; Vol 29 No 1 (2007); 29-35Acta Scientiarum. Technology; v. 29 n. 1 (2007); 29-351806-25631807-8664reponame:Acta scientiarum. Technology (Online)instname:Universidade Estadual de Maringá (UEM)instacron:UEMporhttp://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/82/49Rizk, Maria CrisitnaGimenes, Marcelino LuizLenzi, Erviminfo:eu-repo/semantics/openAccess2024-05-17T13:02:25Zoai:periodicos.uem.br/ojs:article/82Revistahttps://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/indexPUBhttps://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/oai||actatech@uem.br1807-86641806-2563opendoar:2024-05-17T13:02:25Acta scientiarum. Technology (Online) - Universidade Estadual de Maringá (UEM)false |
dc.title.none.fl_str_mv |
Application of chemical precipitation, metallic exchange and Fenton’s reagent in photographic wastewaters treatment Aplicação de precipitação química, troca metálica e reagente Fenton no tratamento de efluentes fotográficos - DOI: 10.4025/actascitechnol.v29i1.82 |
title |
Application of chemical precipitation, metallic exchange and Fenton’s reagent in photographic wastewaters treatment |
spellingShingle |
Application of chemical precipitation, metallic exchange and Fenton’s reagent in photographic wastewaters treatment Rizk, Maria Crisitna remoção de prata degradação da matéria orgânica tratamento de efluentes processos químicos reagente Fenton |
title_short |
Application of chemical precipitation, metallic exchange and Fenton’s reagent in photographic wastewaters treatment |
title_full |
Application of chemical precipitation, metallic exchange and Fenton’s reagent in photographic wastewaters treatment |
title_fullStr |
Application of chemical precipitation, metallic exchange and Fenton’s reagent in photographic wastewaters treatment |
title_full_unstemmed |
Application of chemical precipitation, metallic exchange and Fenton’s reagent in photographic wastewaters treatment |
title_sort |
Application of chemical precipitation, metallic exchange and Fenton’s reagent in photographic wastewaters treatment |
author |
Rizk, Maria Crisitna |
author_facet |
Rizk, Maria Crisitna Gimenes, Marcelino Luiz Lenzi, Ervim |
author_role |
author |
author2 |
Gimenes, Marcelino Luiz Lenzi, Ervim |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Rizk, Maria Crisitna Gimenes, Marcelino Luiz Lenzi, Ervim |
dc.subject.por.fl_str_mv |
remoção de prata degradação da matéria orgânica tratamento de efluentes processos químicos reagente Fenton |
topic |
remoção de prata degradação da matéria orgânica tratamento de efluentes processos químicos reagente Fenton |
description |
Photographic, graphic and radiographic wastewaters contain, in its composition, silver and organic compounds that confer a high organic content. Those wastewaters are, commonly, treated for silver removal, but the organic matter also needs to be reduced, since the chemical oxygen demand (COD) is close to 120,000 mg O2 L-1.Therefore, the objective of this work is to study some processes capable of reducing the silver and COD photographic wastewaters concentrations. The precipitation with sodium sulfide (Na2S) and sodium chloride (NaCl), metallic replacement and advanced oxidation with Fenton’s reagent were studied The results showed that the Na2S precipitation and metallic replacement promoted the best silver removal, close to 100%, and the COD removal was around 10%. The experiments with NaCl did not promote satisfactory silver and COD removal and the Fenton’s reagent removed 40 and 70% of COD and silver concentrations, respectively. |
publishDate |
2007 |
dc.date.none.fl_str_mv |
2007-12-18 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/82 10.4025/actascitechnol.v29i1.82 |
url |
http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/82 |
identifier_str_mv |
10.4025/actascitechnol.v29i1.82 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/82/49 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Estadual De Maringá |
publisher.none.fl_str_mv |
Universidade Estadual De Maringá |
dc.source.none.fl_str_mv |
Acta Scientiarum. Technology; Vol 29 No 1 (2007); 29-35 Acta Scientiarum. Technology; v. 29 n. 1 (2007); 29-35 1806-2563 1807-8664 reponame:Acta scientiarum. Technology (Online) instname:Universidade Estadual de Maringá (UEM) instacron:UEM |
instname_str |
Universidade Estadual de Maringá (UEM) |
instacron_str |
UEM |
institution |
UEM |
reponame_str |
Acta scientiarum. Technology (Online) |
collection |
Acta scientiarum. Technology (Online) |
repository.name.fl_str_mv |
Acta scientiarum. Technology (Online) - Universidade Estadual de Maringá (UEM) |
repository.mail.fl_str_mv |
||actatech@uem.br |
_version_ |
1799315331409248256 |