Modeling and simulation of an industrial slaker reactor
Autor(a) principal: | |
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Data de Publicação: | 2008 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Acta scientiarum. Technology (Online) |
Texto Completo: | http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/3051 |
Resumo: | White liquor used in cellulose digesters is produced by the causticizing process that employs a reactor system composed of two main parts: a mixing slaker reactor followed by causticizing reactors. At the slaker reactor, calcium hydroxide is produced, according to the reaction: CaO(s) + H2O(1) → Ca(OH) 2 (s). Simultaneously a causticizing reaction occurs with the formation of sodium hydroxide: Na2CO3 (aq) + Ca(OH) 2 (s) → 2 NaOH(aq) + CaCO3 (s). The latter takes place along several mixing reactors connected in series. An initial step towards building this dynamic mathematic model was taken and tested for the Klabin Paraná Papéis mill slaker reactor, established in Brazil, for modeling purposes. Simulations of the dynamic model at process conditions show that it was able to reproduce the main characteristics of the process. Close agreement with plant measurements was obtained by adjusting one kinetic parameter. |
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Modeling and simulation of an industrial slaker reactorModelagem e simulação de um reator industrial de apagamentocaustificaçãoapagamentomodelagem3.06.00.00-6 Engenharia QuímicaWhite liquor used in cellulose digesters is produced by the causticizing process that employs a reactor system composed of two main parts: a mixing slaker reactor followed by causticizing reactors. At the slaker reactor, calcium hydroxide is produced, according to the reaction: CaO(s) + H2O(1) → Ca(OH) 2 (s). Simultaneously a causticizing reaction occurs with the formation of sodium hydroxide: Na2CO3 (aq) + Ca(OH) 2 (s) → 2 NaOH(aq) + CaCO3 (s). The latter takes place along several mixing reactors connected in series. An initial step towards building this dynamic mathematic model was taken and tested for the Klabin Paraná Papéis mill slaker reactor, established in Brazil, for modeling purposes. Simulations of the dynamic model at process conditions show that it was able to reproduce the main characteristics of the process. Close agreement with plant measurements was obtained by adjusting one kinetic parameter.O sistema de reatores de caustificação é responsável pela geração do licor branco e é composto, basicamente, por um reator de apagamento, seguido por vários reatores de caustificação. No reator de apagamento, ocorre a formação de hidróxido de cálcio, segundo a reação: CaO(s) + H2O(1) → Ca(OH) 2 (s), e, simultaneamente, a reação de caustificação com a formação de hidróxido de sódio: Na2CO3 (aq) + Ca(OH) 2 (s) → 2 NaOH(aq) + CaCO3 (s), estendendo-se ao longo de vários reatores de mistura, dispostos em série. Neste sentido, como primeira etapa, foi elaborado e testado um modelo matemático fenomenológico do reator de apagamento em regime transiente, da indústria Klabin Paraná Papéis. O modelo foi obtido a partir de balanços de massa e de energia no reator, resultando num sistema de oito equações diferenciais ordinárias, que foram resolvidas numericamente. As simulações deste modelo, nas condições operacionais da planta, revelam que este é capaz de representar as principais tendências do processo.Universidade Estadual De Maringá2008-05-13info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/305110.4025/actascitechnol.v22i0.3051Acta Scientiarum. Technology; Vol 22 (2000); 1219-1224Acta Scientiarum. Technology; v. 22 (2000); 1219-12241806-25631807-8664reponame:Acta scientiarum. Technology (Online)instname:Universidade Estadual de Maringá (UEM)instacron:UEMporhttp://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/3051/2211Andreola, RicardoVieira, OsvaldoSantos, Onélia Aparecida Andreo dosJorge, Luiz Mario de Matosinfo:eu-repo/semantics/openAccess2024-05-17T13:02:53Zoai:periodicos.uem.br/ojs:article/3051Revistahttps://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/indexPUBhttps://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/oai||actatech@uem.br1807-86641806-2563opendoar:2024-05-17T13:02:53Acta scientiarum. Technology (Online) - Universidade Estadual de Maringá (UEM)false |
dc.title.none.fl_str_mv |
Modeling and simulation of an industrial slaker reactor Modelagem e simulação de um reator industrial de apagamento |
title |
Modeling and simulation of an industrial slaker reactor |
spellingShingle |
Modeling and simulation of an industrial slaker reactor Andreola, Ricardo caustificação apagamento modelagem 3.06.00.00-6 Engenharia Química |
title_short |
Modeling and simulation of an industrial slaker reactor |
title_full |
Modeling and simulation of an industrial slaker reactor |
title_fullStr |
Modeling and simulation of an industrial slaker reactor |
title_full_unstemmed |
Modeling and simulation of an industrial slaker reactor |
title_sort |
Modeling and simulation of an industrial slaker reactor |
author |
Andreola, Ricardo |
author_facet |
Andreola, Ricardo Vieira, Osvaldo Santos, Onélia Aparecida Andreo dos Jorge, Luiz Mario de Matos |
author_role |
author |
author2 |
Vieira, Osvaldo Santos, Onélia Aparecida Andreo dos Jorge, Luiz Mario de Matos |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Andreola, Ricardo Vieira, Osvaldo Santos, Onélia Aparecida Andreo dos Jorge, Luiz Mario de Matos |
dc.subject.por.fl_str_mv |
caustificação apagamento modelagem 3.06.00.00-6 Engenharia Química |
topic |
caustificação apagamento modelagem 3.06.00.00-6 Engenharia Química |
description |
White liquor used in cellulose digesters is produced by the causticizing process that employs a reactor system composed of two main parts: a mixing slaker reactor followed by causticizing reactors. At the slaker reactor, calcium hydroxide is produced, according to the reaction: CaO(s) + H2O(1) → Ca(OH) 2 (s). Simultaneously a causticizing reaction occurs with the formation of sodium hydroxide: Na2CO3 (aq) + Ca(OH) 2 (s) → 2 NaOH(aq) + CaCO3 (s). The latter takes place along several mixing reactors connected in series. An initial step towards building this dynamic mathematic model was taken and tested for the Klabin Paraná Papéis mill slaker reactor, established in Brazil, for modeling purposes. Simulations of the dynamic model at process conditions show that it was able to reproduce the main characteristics of the process. Close agreement with plant measurements was obtained by adjusting one kinetic parameter. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-05-13 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/3051 10.4025/actascitechnol.v22i0.3051 |
url |
http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/3051 |
identifier_str_mv |
10.4025/actascitechnol.v22i0.3051 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/3051/2211 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Estadual De Maringá |
publisher.none.fl_str_mv |
Universidade Estadual De Maringá |
dc.source.none.fl_str_mv |
Acta Scientiarum. Technology; Vol 22 (2000); 1219-1224 Acta Scientiarum. Technology; v. 22 (2000); 1219-1224 1806-2563 1807-8664 reponame:Acta scientiarum. Technology (Online) instname:Universidade Estadual de Maringá (UEM) instacron:UEM |
instname_str |
Universidade Estadual de Maringá (UEM) |
instacron_str |
UEM |
institution |
UEM |
reponame_str |
Acta scientiarum. Technology (Online) |
collection |
Acta scientiarum. Technology (Online) |
repository.name.fl_str_mv |
Acta scientiarum. Technology (Online) - Universidade Estadual de Maringá (UEM) |
repository.mail.fl_str_mv |
||actatech@uem.br |
_version_ |
1799315332567924736 |