Catalytic oxidation of phenol in aqueous media over CuZSM-12 zeolite

Detalhes bibliográficos
Autor(a) principal: Vieira, Rinaldo Antonio de Melo
Data de Publicação: 2006
Outros Autores: Pires, Carlos A. M., Suñé, Leticia S. V. S., Silva, Antonio O. S., Souza, Marcelo José Barros de, Araujo, Antonio S.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFBA
Texto Completo: http://repositorio.ufba.br/ri/handle/ri/13811
Resumo: Texto completo: acesso restrito. p. 119-126
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spelling Vieira, Rinaldo Antonio de MeloPires, Carlos A. M.Suñé, Leticia S. V. S.Silva, Antonio O. S.Souza, Marcelo José Barros deAraujo, Antonio S.Vieira, Rinaldo Antonio de MeloPires, Carlos A. M.Suñé, Leticia S. V. S.Silva, Antonio O. S.Souza, Marcelo José Barros deAraujo, Antonio S.2013-11-19T21:00:33Z20060133-1736http://repositorio.ufba.br/ri/handle/ri/13811v. 88, n. 1Texto completo: acesso restrito. p. 119-126The catalytic oxidation of phenol over CuZSM-12 (SAR = 200) has been studied using a semi-batch slurry reactor at temperatures of 110, 120 and 130oC, and acidic neutral and basic pH. At 130oC, the phenol undergoes total conversion to carbon dioxide and water in 1.5 h. The kinetic parameters were evaluated using a modified homogeneous heterogeneous model for the experimental data. Using this modified model, the activation energy for the catalytic oxidation process was ca. 90 kJ mol-1.Submitted by Edileide Reis (leyde-landy@hotmail.com) on 2013-08-23T12:32:25Z No. of bitstreams: 1 10.1007_s11144-006-0118-z.pdf: 97317 bytes, checksum: 912e0d731d328fab163d9a2f80f6237e (MD5)Approved for entry into archive by Rodrigo Meirelles (rodrigomei@ufba.br) on 2013-11-19T21:00:33Z (GMT) No. of bitstreams: 1 10.1007_s11144-006-0118-z.pdf: 97317 bytes, checksum: 912e0d731d328fab163d9a2f80f6237e (MD5)Made available in DSpace on 2013-11-19T21:00:33Z (GMT). No. of bitstreams: 1 10.1007_s11144-006-0118-z.pdf: 97317 bytes, checksum: 912e0d731d328fab163d9a2f80f6237e (MD5) Previous issue date: 2006http://dx.doi.org/ 10.1007/s11144-006-0118-zreponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBAPhenol oxidationCuZSM-12 zeoliteSlurry reactorKinetic modelCatalytic oxidation of phenol in aqueous media over CuZSM-12 zeoliteReaction Kinetics and Catalysis Lettersinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article10000-01-01info:eu-repo/semantics/openAccessengORIGINAL10.1007_s11144-006-0118-z.pdf10.1007_s11144-006-0118-z.pdfapplication/pdf97317https://repositorio.ufba.br/bitstream/ri/13811/1/10.1007_s11144-006-0118-z.pdf912e0d731d328fab163d9a2f80f6237eMD51LICENSElicense.txtlicense.txttext/plain1762https://repositorio.ufba.br/bitstream/ri/13811/2/license.txt1b89a9a0548218172d7c829f87a0eab9MD52TEXT10.1007_s11144-006-0118-z.pdf.txt10.1007_s11144-006-0118-z.pdf.txtExtracted texttext/plain12225https://repositorio.ufba.br/bitstream/ri/13811/3/10.1007_s11144-006-0118-z.pdf.txt9ac3bf33120393b22befc4f402c66fffMD53ri/138112022-07-05 14:02:49.703oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-07-05T17:02:49Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false
dc.title.pt_BR.fl_str_mv Catalytic oxidation of phenol in aqueous media over CuZSM-12 zeolite
dc.title.alternative.pt_BR.fl_str_mv Reaction Kinetics and Catalysis Letters
title Catalytic oxidation of phenol in aqueous media over CuZSM-12 zeolite
spellingShingle Catalytic oxidation of phenol in aqueous media over CuZSM-12 zeolite
Vieira, Rinaldo Antonio de Melo
Phenol oxidation
CuZSM-12 zeolite
Slurry reactor
Kinetic model
title_short Catalytic oxidation of phenol in aqueous media over CuZSM-12 zeolite
title_full Catalytic oxidation of phenol in aqueous media over CuZSM-12 zeolite
title_fullStr Catalytic oxidation of phenol in aqueous media over CuZSM-12 zeolite
title_full_unstemmed Catalytic oxidation of phenol in aqueous media over CuZSM-12 zeolite
title_sort Catalytic oxidation of phenol in aqueous media over CuZSM-12 zeolite
author Vieira, Rinaldo Antonio de Melo
author_facet Vieira, Rinaldo Antonio de Melo
Pires, Carlos A. M.
Suñé, Leticia S. V. S.
Silva, Antonio O. S.
Souza, Marcelo José Barros de
Araujo, Antonio S.
author_role author
author2 Pires, Carlos A. M.
Suñé, Leticia S. V. S.
Silva, Antonio O. S.
Souza, Marcelo José Barros de
Araujo, Antonio S.
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Vieira, Rinaldo Antonio de Melo
Pires, Carlos A. M.
Suñé, Leticia S. V. S.
Silva, Antonio O. S.
Souza, Marcelo José Barros de
Araujo, Antonio S.
Vieira, Rinaldo Antonio de Melo
Pires, Carlos A. M.
Suñé, Leticia S. V. S.
Silva, Antonio O. S.
Souza, Marcelo José Barros de
Araujo, Antonio S.
dc.subject.por.fl_str_mv Phenol oxidation
CuZSM-12 zeolite
Slurry reactor
Kinetic model
topic Phenol oxidation
CuZSM-12 zeolite
Slurry reactor
Kinetic model
description Texto completo: acesso restrito. p. 119-126
publishDate 2006
dc.date.issued.fl_str_mv 2006
dc.date.accessioned.fl_str_mv 2013-11-19T21:00:33Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://repositorio.ufba.br/ri/handle/ri/13811
dc.identifier.issn.none.fl_str_mv 0133-1736
dc.identifier.number.pt_BR.fl_str_mv v. 88, n. 1
identifier_str_mv 0133-1736
v. 88, n. 1
url http://repositorio.ufba.br/ri/handle/ri/13811
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.pt_BR.fl_str_mv http://dx.doi.org/ 10.1007/s11144-006-0118-z
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFBA
instname:Universidade Federal da Bahia (UFBA)
instacron:UFBA
instname_str Universidade Federal da Bahia (UFBA)
instacron_str UFBA
institution UFBA
reponame_str Repositório Institucional da UFBA
collection Repositório Institucional da UFBA
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