A practical toolset for TERS experiments and analysis
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Tipo de documento: | Tese |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFMG |
Texto Completo: | http://hdl.handle.net/1843/34709 |
Resumo: | This work proposes a set of hardware and software tools to improve the usability of tip-enhanced Raman spectroscopy (TERS) systems. TERS is capable of providing optical images with resolution beyond the light’s diffraction limit while also providing chemical and structural information, which makes it a technique of interest for nanoscience and nanotechnology applications. Specifically, this work aims to develop hardware and software solutions to better understand the TERS probe’s interaction with an electromagnetic field, providing insights on: optical probe alignment methods, optimization of probe’s constructive parameters and super-resolution. Aside from the development of the necessary instruments, this task also comprehends the study of TERS probe’s interaction with light via Finite Element Method simulations in addition to TERS experiments with graphene under a series of environmental conditions that affect the local electromagnetic field in a controlled manner. Furthermore, the work also comprehends the use of data analysis techniques, specifically Spectral Unmixing and Principal Component Analysis (PCA), with the objective of efficiently extracting information from hyperspectral images in a non supervised manner via dimensionality reduction. |
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Ado Jorio de Vasconceloshttp://lattes.cnpq.br/0034894070455412Jaime Arturo RamirezDavies William de Lima MonteiroLeandro Malard MoreiraEduardo Bedê BarrosBráulio Soares Arcanjohttp://lattes.cnpq.br/0605662802625493Hudson Luiz Silva de Miranda2021-01-14T21:07:29Z2021-01-14T21:07:29Z2020-11-06http://hdl.handle.net/1843/347090000-0002-9946-5224This work proposes a set of hardware and software tools to improve the usability of tip-enhanced Raman spectroscopy (TERS) systems. TERS is capable of providing optical images with resolution beyond the light’s diffraction limit while also providing chemical and structural information, which makes it a technique of interest for nanoscience and nanotechnology applications. Specifically, this work aims to develop hardware and software solutions to better understand the TERS probe’s interaction with an electromagnetic field, providing insights on: optical probe alignment methods, optimization of probe’s constructive parameters and super-resolution. Aside from the development of the necessary instruments, this task also comprehends the study of TERS probe’s interaction with light via Finite Element Method simulations in addition to TERS experiments with graphene under a series of environmental conditions that affect the local electromagnetic field in a controlled manner. Furthermore, the work also comprehends the use of data analysis techniques, specifically Spectral Unmixing and Principal Component Analysis (PCA), with the objective of efficiently extracting information from hyperspectral images in a non supervised manner via dimensionality reduction.Este trabalho propõe um conjunto de ferramentas de hardware e software para melhorar a usabilidade de sistemas de espectroscopia Raman aprimorada por ponta (TERS, do inglês Tip Enhanced Raman Spectroscopy). O TERS é capaz de fornecer imagens ópticas com resolução além do limite de difração da luz, além de fornecer informações químicas e estruturais, o que o torna uma técnica de interesse para aplicações em nanociência e nanotecnologia. Especificamente, este trabalho visa desenvolver soluções de hardware e software para melhor compreender a interação da sonda TERS com um campo eletromagnético, fornecendo informações sobre: métodos de alinhamento óptico de sonda, otimização dos parâmetros construtivos da sonda e super-resolução. Além do desenvolvimento dos instrumentos necessários, esta tarefa também compreende o estudo da interação da sonda TERS com a luz via simulações do Método dos Elementos Finitos, além de experimentos de TERS com grafeno sob uma série de condições ambientais que afetam o campo eletromagnético local de forma controlada. Além disso, o trabalho também compreende a utilização de técnicas de análise de dados, especificamente Decomposição Espectral (Spectral Unmixing) e Análise de Componentes Principais (PCA, do inglês Principal Component Analysis), com o objetivo de extrair informações de imagens hiperespectrais de forma eficiente e não supervisionada via redução de dimensionalidade.CNPq - Conselho Nacional de Desenvolvimento Científico e TecnológicoengUniversidade Federal de Minas GeraisPrograma de Pós-Graduação em Engenharia ElétricaUFMGBrasilENG - DEPARTAMENTO DE ENGENHARIA ELÉTRICAhttp://creativecommons.org/licenses/by-nc-nd/3.0/pt/info:eu-repo/semantics/openAccessEngenharia elétricaNanotecnologiaGrafenoRaman, Espectroscopia deScientific instrumentationRaman spectroscopyTip enhanced Raman spectroscopyNanotechnologyGrapheneFinite element methodA practical toolset for TERS experiments and analysisUm conjunto de ferramentas prático para experimentos e análises TERSinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesisreponame:Repositório Institucional da UFMGinstname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGORIGINALA_Practical_Toolset_for_TERS_Experiments_and_Analysis_Hudson_Miranda_completa_anexos.pdfA_Practical_Toolset_for_TERS_Experiments_and_Analysis_Hudson_Miranda_completa_anexos.pdfapplication/pdf5264274https://repositorio.ufmg.br/bitstream/1843/34709/5/A_Practical_Toolset_for_TERS_Experiments_and_Analysis_Hudson_Miranda_completa_anexos.pdfa05478693844c71f6013fe0db8864188MD55CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8811https://repositorio.ufmg.br/bitstream/1843/34709/3/license_rdfcfd6801dba008cb6adbd9838b81582abMD53LICENSElicense.txtlicense.txttext/plain; charset=utf-82119https://repositorio.ufmg.br/bitstream/1843/34709/6/license.txt34badce4be7e31e3adb4575ae96af679MD561843/347092021-01-14 18:07:29.582oai:repositorio.ufmg.br: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Repositório de PublicaçõesPUBhttps://repositorio.ufmg.br/oaiopendoar:2021-01-14T21:07:29Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)false |
dc.title.pt_BR.fl_str_mv |
A practical toolset for TERS experiments and analysis |
dc.title.alternative.pt_BR.fl_str_mv |
Um conjunto de ferramentas prático para experimentos e análises TERS |
title |
A practical toolset for TERS experiments and analysis |
spellingShingle |
A practical toolset for TERS experiments and analysis Hudson Luiz Silva de Miranda Scientific instrumentation Raman spectroscopy Tip enhanced Raman spectroscopy Nanotechnology Graphene Finite element method Engenharia elétrica Nanotecnologia Grafeno Raman, Espectroscopia de |
title_short |
A practical toolset for TERS experiments and analysis |
title_full |
A practical toolset for TERS experiments and analysis |
title_fullStr |
A practical toolset for TERS experiments and analysis |
title_full_unstemmed |
A practical toolset for TERS experiments and analysis |
title_sort |
A practical toolset for TERS experiments and analysis |
author |
Hudson Luiz Silva de Miranda |
author_facet |
Hudson Luiz Silva de Miranda |
author_role |
author |
dc.contributor.advisor1.fl_str_mv |
Ado Jorio de Vasconcelos |
dc.contributor.advisor1Lattes.fl_str_mv |
http://lattes.cnpq.br/0034894070455412 |
dc.contributor.referee1.fl_str_mv |
Jaime Arturo Ramirez |
dc.contributor.referee2.fl_str_mv |
Davies William de Lima Monteiro |
dc.contributor.referee3.fl_str_mv |
Leandro Malard Moreira |
dc.contributor.referee4.fl_str_mv |
Eduardo Bedê Barros |
dc.contributor.referee5.fl_str_mv |
Bráulio Soares Arcanjo |
dc.contributor.authorLattes.fl_str_mv |
http://lattes.cnpq.br/0605662802625493 |
dc.contributor.author.fl_str_mv |
Hudson Luiz Silva de Miranda |
contributor_str_mv |
Ado Jorio de Vasconcelos Jaime Arturo Ramirez Davies William de Lima Monteiro Leandro Malard Moreira Eduardo Bedê Barros Bráulio Soares Arcanjo |
dc.subject.por.fl_str_mv |
Scientific instrumentation Raman spectroscopy Tip enhanced Raman spectroscopy Nanotechnology Graphene Finite element method |
topic |
Scientific instrumentation Raman spectroscopy Tip enhanced Raman spectroscopy Nanotechnology Graphene Finite element method Engenharia elétrica Nanotecnologia Grafeno Raman, Espectroscopia de |
dc.subject.other.pt_BR.fl_str_mv |
Engenharia elétrica Nanotecnologia Grafeno Raman, Espectroscopia de |
description |
This work proposes a set of hardware and software tools to improve the usability of tip-enhanced Raman spectroscopy (TERS) systems. TERS is capable of providing optical images with resolution beyond the light’s diffraction limit while also providing chemical and structural information, which makes it a technique of interest for nanoscience and nanotechnology applications. Specifically, this work aims to develop hardware and software solutions to better understand the TERS probe’s interaction with an electromagnetic field, providing insights on: optical probe alignment methods, optimization of probe’s constructive parameters and super-resolution. Aside from the development of the necessary instruments, this task also comprehends the study of TERS probe’s interaction with light via Finite Element Method simulations in addition to TERS experiments with graphene under a series of environmental conditions that affect the local electromagnetic field in a controlled manner. Furthermore, the work also comprehends the use of data analysis techniques, specifically Spectral Unmixing and Principal Component Analysis (PCA), with the objective of efficiently extracting information from hyperspectral images in a non supervised manner via dimensionality reduction. |
publishDate |
2020 |
dc.date.issued.fl_str_mv |
2020-11-06 |
dc.date.accessioned.fl_str_mv |
2021-01-14T21:07:29Z |
dc.date.available.fl_str_mv |
2021-01-14T21:07:29Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/doctoralThesis |
format |
doctoralThesis |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/1843/34709 |
dc.identifier.orcid.pt_BR.fl_str_mv |
0000-0002-9946-5224 |
url |
http://hdl.handle.net/1843/34709 |
identifier_str_mv |
0000-0002-9946-5224 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.rights.driver.fl_str_mv |
http://creativecommons.org/licenses/by-nc-nd/3.0/pt/ info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by-nc-nd/3.0/pt/ |
eu_rights_str_mv |
openAccess |
dc.publisher.none.fl_str_mv |
Universidade Federal de Minas Gerais |
dc.publisher.program.fl_str_mv |
Programa de Pós-Graduação em Engenharia Elétrica |
dc.publisher.initials.fl_str_mv |
UFMG |
dc.publisher.country.fl_str_mv |
Brasil |
dc.publisher.department.fl_str_mv |
ENG - DEPARTAMENTO DE ENGENHARIA ELÉTRICA |
publisher.none.fl_str_mv |
Universidade Federal de Minas Gerais |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UFMG instname:Universidade Federal de Minas Gerais (UFMG) instacron:UFMG |
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Universidade Federal de Minas Gerais (UFMG) |
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UFMG |
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UFMG |
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Repositório Institucional da UFMG |
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