fac-[RuCl2(DMSO-S)3(n-butylamine)]: Synthesis, structural characterization and dual catalytic performance

• Autor(a) principal: Silva, Tiago B.
• Data de Publicação: 2020
• Outros Autores: Martins, Daniele M., Gois, Patrik D.S. [UNESP], Borim, Patrícia, Maia, Pedro I.S., Carvalho, Valdemiro P. [UNESP], Lima-Neto, Benedito S.
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Institucional da UNESP
• Texto Completo: http://dx.doi.org/10.1016/j.inoche.2019.107749; http://hdl.handle.net/11449/198313
• topic: Ancillary ligand; ATRP; Crystal structure; Dimethylsulfoxide; ROMP; Ruthenium

The synthesis, spectroscopic properties and crystal structure of the novel complex fac-[RuCl2(DMSO-S)3(n-butylamine)] (DMSO-S = sulfur-bonded dimethylsulfoxide) have been reported. The coordination environment of the ruthenium atom is best described as a distorted octahedral, where three DMSO ligands occupy one face of the octahedron, while the two chlorido and the amine ligand occupy the other one. The catalytic activity of fac-[RuCl2(DMSO-S)3(n-butylamine)] was probed in two processes, ring-opening metathesis polymerization (ROMP) and atom-transfer radical polymerization (ATRP). The ROMP of norbornene (NBE) was carried out in the presence of ethyl diazoacetate (EDA) for 5 min at 50 °C which afforded yields around 80%. Poly(norbornadiene) was only produced by photoinduced ROMP leading to 27% yield. The catalytic activity for ATRP of methyl methacrylate (MMA) and styrene (St) for 8 h resulted in 88 and 33%, respectively.