Synthesis and properties of collagen-g-poly(sodium acrylate-co-2-hydroxyethylacrylate) superabsorbent hydrogels
Autor(a) principal: | |
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Data de Publicação: | 2013 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Brazilian Journal of Chemical Engineering |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322013000200015 |
Resumo: | Novel biopolymer-based superabsorbent hydrogels were prepared by grafting crosslinked poly(acrylic acid-co-2-hydroxyethyl acrylate) (PAA-co-PHEA) chains onto collagen backbones through a free radical polymerization method. The graft copolymerization reaction was carried out in a homogeneous medium and in the presence of ammonium persulfate (APS) as initiator and N,N '-methylene bisacrylamide (MBA) as crosslinker. A proposed mechanism for collagen-g-(PAA-co-PHEA) formation was suggested and the hydrogel structure was confirmed using FTIR spectroscopy and TGA thermal analysis. Moreover, the morphology of the samples was examined by scanning electron microscopy (SEM). The effect of concentration of MBA as well as AA/HEA weight ratio on the swelling capacity of the hydrogel was also studied. Furthermore, the water absorbency of hydrogels was measured in solutions with pH ranging 1 to 13. The collagen-based hydrogel exhibited a pH-responsive character, so that a swelling-deswelling pulsatile behavior was recorded at pHs 2 and 8. Preliminary swelling and deswelling behaviors of the hydrogels were also studied. Additionally, the hydrogels exhibited salt-sensitivity and cation exchange properties. |
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Brazilian Journal of Chemical Engineering |
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Synthesis and properties of collagen-g-poly(sodium acrylate-co-2-hydroxyethylacrylate) superabsorbent hydrogelsCollagenHydrogelsSwellingAcrylic acid2-hydroxyethyl acrylateNovel biopolymer-based superabsorbent hydrogels were prepared by grafting crosslinked poly(acrylic acid-co-2-hydroxyethyl acrylate) (PAA-co-PHEA) chains onto collagen backbones through a free radical polymerization method. The graft copolymerization reaction was carried out in a homogeneous medium and in the presence of ammonium persulfate (APS) as initiator and N,N '-methylene bisacrylamide (MBA) as crosslinker. A proposed mechanism for collagen-g-(PAA-co-PHEA) formation was suggested and the hydrogel structure was confirmed using FTIR spectroscopy and TGA thermal analysis. Moreover, the morphology of the samples was examined by scanning electron microscopy (SEM). The effect of concentration of MBA as well as AA/HEA weight ratio on the swelling capacity of the hydrogel was also studied. Furthermore, the water absorbency of hydrogels was measured in solutions with pH ranging 1 to 13. The collagen-based hydrogel exhibited a pH-responsive character, so that a swelling-deswelling pulsatile behavior was recorded at pHs 2 and 8. Preliminary swelling and deswelling behaviors of the hydrogels were also studied. Additionally, the hydrogels exhibited salt-sensitivity and cation exchange properties.Brazilian Society of Chemical Engineering2013-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322013000200015Brazilian Journal of Chemical Engineering v.30 n.2 2013reponame:Brazilian Journal of Chemical Engineeringinstname:Associação Brasileira de Engenharia Química (ABEQ)instacron:ABEQ10.1590/S0104-66322013000200015info:eu-repo/semantics/openAccessSadeghi,M.Hosseinzadeh,H.eng2013-05-08T00:00:00Zoai:scielo:S0104-66322013000200015Revistahttps://www.scielo.br/j/bjce/https://old.scielo.br/oai/scielo-oai.phprgiudici@usp.br||rgiudici@usp.br1678-43830104-6632opendoar:2013-05-08T00:00Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ)false |
dc.title.none.fl_str_mv |
Synthesis and properties of collagen-g-poly(sodium acrylate-co-2-hydroxyethylacrylate) superabsorbent hydrogels |
title |
Synthesis and properties of collagen-g-poly(sodium acrylate-co-2-hydroxyethylacrylate) superabsorbent hydrogels |
spellingShingle |
Synthesis and properties of collagen-g-poly(sodium acrylate-co-2-hydroxyethylacrylate) superabsorbent hydrogels Sadeghi,M. Collagen Hydrogels Swelling Acrylic acid 2-hydroxyethyl acrylate |
title_short |
Synthesis and properties of collagen-g-poly(sodium acrylate-co-2-hydroxyethylacrylate) superabsorbent hydrogels |
title_full |
Synthesis and properties of collagen-g-poly(sodium acrylate-co-2-hydroxyethylacrylate) superabsorbent hydrogels |
title_fullStr |
Synthesis and properties of collagen-g-poly(sodium acrylate-co-2-hydroxyethylacrylate) superabsorbent hydrogels |
title_full_unstemmed |
Synthesis and properties of collagen-g-poly(sodium acrylate-co-2-hydroxyethylacrylate) superabsorbent hydrogels |
title_sort |
Synthesis and properties of collagen-g-poly(sodium acrylate-co-2-hydroxyethylacrylate) superabsorbent hydrogels |
author |
Sadeghi,M. |
author_facet |
Sadeghi,M. Hosseinzadeh,H. |
author_role |
author |
author2 |
Hosseinzadeh,H. |
author2_role |
author |
dc.contributor.author.fl_str_mv |
Sadeghi,M. Hosseinzadeh,H. |
dc.subject.por.fl_str_mv |
Collagen Hydrogels Swelling Acrylic acid 2-hydroxyethyl acrylate |
topic |
Collagen Hydrogels Swelling Acrylic acid 2-hydroxyethyl acrylate |
description |
Novel biopolymer-based superabsorbent hydrogels were prepared by grafting crosslinked poly(acrylic acid-co-2-hydroxyethyl acrylate) (PAA-co-PHEA) chains onto collagen backbones through a free radical polymerization method. The graft copolymerization reaction was carried out in a homogeneous medium and in the presence of ammonium persulfate (APS) as initiator and N,N '-methylene bisacrylamide (MBA) as crosslinker. A proposed mechanism for collagen-g-(PAA-co-PHEA) formation was suggested and the hydrogel structure was confirmed using FTIR spectroscopy and TGA thermal analysis. Moreover, the morphology of the samples was examined by scanning electron microscopy (SEM). The effect of concentration of MBA as well as AA/HEA weight ratio on the swelling capacity of the hydrogel was also studied. Furthermore, the water absorbency of hydrogels was measured in solutions with pH ranging 1 to 13. The collagen-based hydrogel exhibited a pH-responsive character, so that a swelling-deswelling pulsatile behavior was recorded at pHs 2 and 8. Preliminary swelling and deswelling behaviors of the hydrogels were also studied. Additionally, the hydrogels exhibited salt-sensitivity and cation exchange properties. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-06-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322013000200015 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322013000200015 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0104-66322013000200015 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Brazilian Society of Chemical Engineering |
publisher.none.fl_str_mv |
Brazilian Society of Chemical Engineering |
dc.source.none.fl_str_mv |
Brazilian Journal of Chemical Engineering v.30 n.2 2013 reponame:Brazilian Journal of Chemical Engineering instname:Associação Brasileira de Engenharia Química (ABEQ) instacron:ABEQ |
instname_str |
Associação Brasileira de Engenharia Química (ABEQ) |
instacron_str |
ABEQ |
institution |
ABEQ |
reponame_str |
Brazilian Journal of Chemical Engineering |
collection |
Brazilian Journal of Chemical Engineering |
repository.name.fl_str_mv |
Brazilian Journal of Chemical Engineering - Associação Brasileira de Engenharia Química (ABEQ) |
repository.mail.fl_str_mv |
rgiudici@usp.br||rgiudici@usp.br |
_version_ |
1754213173924200448 |