One-Step Synthesis of AuCu/TiO2 Catalysts for CO Preferential Oxidation
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392020000500207 |
Resumo: | Abstract Au/TiO2 (1wt% Au), Cu/TiO2 (1wt% Cu) and AuCu/TiO2 (1wt% AuCu) catalysts with different Au:Cu mass ratios were prepared in one-step synthesis using sodium borohydride as reducing agent. The resulting catalysts were characterized by X-ray diffraction (XRD), X-ray Dispersive Energy (EDX), Transmission Electron Microscopy (TEM) and Temperature Programmed Reduction (TPR) and tested for the preferential oxidation of carbon monoxide (CO-PROX reaction) in H2-rich gases. EDS analysis showed that the Au contents are close to the nominal values whereas for Cu these values are always lower. X-ray diffractograms showed only the peaks of TiO2 phase; no peaks of metallic Au and Cu species or oxides phases were observed. TPR and high-resolution TEM analysis showed that AuCu/TiO2 catalysts exhibited most of Au in the metallic form with particles sizes in the range of 3-5 nm and that Cu was found in the form of oxide in close contact with the Au nanoparticles and well spread over the TiO2 surface. The AuCu/TiO2 catalysts exhibited good performance in the range of 75-100 °C and presented a better catalytic activity when compared to the monometallic ones. A maximum CO conversion of 98.4% with a CO2 selectivity of 47% was obtained for Au0.50Cu0.50/TiO2 catalyst at 100oC. |
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One-Step Synthesis of AuCu/TiO2 Catalysts for CO Preferential OxidationAuCu/TiO2 catalystcarbon monoxidepreferential oxidationhydrogenAbstract Au/TiO2 (1wt% Au), Cu/TiO2 (1wt% Cu) and AuCu/TiO2 (1wt% AuCu) catalysts with different Au:Cu mass ratios were prepared in one-step synthesis using sodium borohydride as reducing agent. The resulting catalysts were characterized by X-ray diffraction (XRD), X-ray Dispersive Energy (EDX), Transmission Electron Microscopy (TEM) and Temperature Programmed Reduction (TPR) and tested for the preferential oxidation of carbon monoxide (CO-PROX reaction) in H2-rich gases. EDS analysis showed that the Au contents are close to the nominal values whereas for Cu these values are always lower. X-ray diffractograms showed only the peaks of TiO2 phase; no peaks of metallic Au and Cu species or oxides phases were observed. TPR and high-resolution TEM analysis showed that AuCu/TiO2 catalysts exhibited most of Au in the metallic form with particles sizes in the range of 3-5 nm and that Cu was found in the form of oxide in close contact with the Au nanoparticles and well spread over the TiO2 surface. The AuCu/TiO2 catalysts exhibited good performance in the range of 75-100 °C and presented a better catalytic activity when compared to the monometallic ones. A maximum CO conversion of 98.4% with a CO2 selectivity of 47% was obtained for Au0.50Cu0.50/TiO2 catalyst at 100oC.ABM, ABC, ABPol2020-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392020000500207Materials Research v.23 n.5 2020reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-mr-2020-0181info:eu-repo/semantics/openAccessAlencar,Catarine Santos LopesPaiva,Ana Rita NoborikawaSilva,Julio Cesar Martins daVaz,Jorge MoreiraSpinacé,Estevam Vitorioeng2020-10-21T00:00:00Zoai:scielo:S1516-14392020000500207Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2020-10-21T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
One-Step Synthesis of AuCu/TiO2 Catalysts for CO Preferential Oxidation |
title |
One-Step Synthesis of AuCu/TiO2 Catalysts for CO Preferential Oxidation |
spellingShingle |
One-Step Synthesis of AuCu/TiO2 Catalysts for CO Preferential Oxidation Alencar,Catarine Santos Lopes AuCu/TiO2 catalyst carbon monoxide preferential oxidation hydrogen |
title_short |
One-Step Synthesis of AuCu/TiO2 Catalysts for CO Preferential Oxidation |
title_full |
One-Step Synthesis of AuCu/TiO2 Catalysts for CO Preferential Oxidation |
title_fullStr |
One-Step Synthesis of AuCu/TiO2 Catalysts for CO Preferential Oxidation |
title_full_unstemmed |
One-Step Synthesis of AuCu/TiO2 Catalysts for CO Preferential Oxidation |
title_sort |
One-Step Synthesis of AuCu/TiO2 Catalysts for CO Preferential Oxidation |
author |
Alencar,Catarine Santos Lopes |
author_facet |
Alencar,Catarine Santos Lopes Paiva,Ana Rita Noborikawa Silva,Julio Cesar Martins da Vaz,Jorge Moreira Spinacé,Estevam Vitorio |
author_role |
author |
author2 |
Paiva,Ana Rita Noborikawa Silva,Julio Cesar Martins da Vaz,Jorge Moreira Spinacé,Estevam Vitorio |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Alencar,Catarine Santos Lopes Paiva,Ana Rita Noborikawa Silva,Julio Cesar Martins da Vaz,Jorge Moreira Spinacé,Estevam Vitorio |
dc.subject.por.fl_str_mv |
AuCu/TiO2 catalyst carbon monoxide preferential oxidation hydrogen |
topic |
AuCu/TiO2 catalyst carbon monoxide preferential oxidation hydrogen |
description |
Abstract Au/TiO2 (1wt% Au), Cu/TiO2 (1wt% Cu) and AuCu/TiO2 (1wt% AuCu) catalysts with different Au:Cu mass ratios were prepared in one-step synthesis using sodium borohydride as reducing agent. The resulting catalysts were characterized by X-ray diffraction (XRD), X-ray Dispersive Energy (EDX), Transmission Electron Microscopy (TEM) and Temperature Programmed Reduction (TPR) and tested for the preferential oxidation of carbon monoxide (CO-PROX reaction) in H2-rich gases. EDS analysis showed that the Au contents are close to the nominal values whereas for Cu these values are always lower. X-ray diffractograms showed only the peaks of TiO2 phase; no peaks of metallic Au and Cu species or oxides phases were observed. TPR and high-resolution TEM analysis showed that AuCu/TiO2 catalysts exhibited most of Au in the metallic form with particles sizes in the range of 3-5 nm and that Cu was found in the form of oxide in close contact with the Au nanoparticles and well spread over the TiO2 surface. The AuCu/TiO2 catalysts exhibited good performance in the range of 75-100 °C and presented a better catalytic activity when compared to the monometallic ones. A maximum CO conversion of 98.4% with a CO2 selectivity of 47% was obtained for Au0.50Cu0.50/TiO2 catalyst at 100oC. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392020000500207 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392020000500207 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/1980-5373-mr-2020-0181 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.23 n.5 2020 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212677787320320 |