Proton Exchange Membrane Based on Sulfonated Poly (Aromatic Imide-Co-Aliphatic Imide) for Direct Methanol Fuel Cell
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Materials research (São Carlos. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392018000100133 |
Resumo: | A new sulfonated poly(aromatic imide-co-aliphatic imide) (SPI) for the use as a polymer electrolyte membrane was successfully synthesized from 4,4'-diaminodiphenylmethane (DDM), 4,4'-diaminodiphenylmethane-2,2'-disulfonic acid disodium salt (S-DDM), hexamethylenediamine, and 3,3',4,4'-benzophenonetetracarboxylic dianhydride in a one-step reaction. S-DDM was prepared by the direct sulfonation of DDM monomer. The degree of sulfonation of the sulfonated copolyimide was varied by using various molar concentrations of S-DDM. The sulfonated copolyimide with the highest degree of sulfonation possessed the proton conductivity of 0.0032 S.cm-1 in a wet state. The highest methanol permeability of the sulfonated copolyimide was 2.75 × 10-8 cm2.s-1 which is ~425 times lower than that of the Nafion 117. The highest membrane selectivity belonged to the membrane with 34% degree of sulfonation with the value of 1.65 × 106 s.S.cm-3 which is three orders of magnitude higher than the commercial Nafion 117. |
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Materials research (São Carlos. Online) |
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Proton Exchange Membrane Based on Sulfonated Poly (Aromatic Imide-Co-Aliphatic Imide) for Direct Methanol Fuel Cellsulfonated poly(aromatic imide-co-aliphatic imide)proton conductivitydirect methanol fuel cellmethanol permeabilityA new sulfonated poly(aromatic imide-co-aliphatic imide) (SPI) for the use as a polymer electrolyte membrane was successfully synthesized from 4,4'-diaminodiphenylmethane (DDM), 4,4'-diaminodiphenylmethane-2,2'-disulfonic acid disodium salt (S-DDM), hexamethylenediamine, and 3,3',4,4'-benzophenonetetracarboxylic dianhydride in a one-step reaction. S-DDM was prepared by the direct sulfonation of DDM monomer. The degree of sulfonation of the sulfonated copolyimide was varied by using various molar concentrations of S-DDM. The sulfonated copolyimide with the highest degree of sulfonation possessed the proton conductivity of 0.0032 S.cm-1 in a wet state. The highest methanol permeability of the sulfonated copolyimide was 2.75 × 10-8 cm2.s-1 which is ~425 times lower than that of the Nafion 117. The highest membrane selectivity belonged to the membrane with 34% degree of sulfonation with the value of 1.65 × 106 s.S.cm-3 which is three orders of magnitude higher than the commercial Nafion 117.ABM, ABC, ABPol2018-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392018000100133Materials Research v.21 n.1 2018reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOL10.1590/1980-5373-mr-2017-0823info:eu-repo/semantics/openAccessUmsarika,PhornpussadeeChangkhamchom,SairungParadee,NophawanSirivat,AnuvatSupaphol,PittHormnirun,Pimpaeng2018-05-11T00:00:00Zoai:scielo:S1516-14392018000100133Revistahttp://www.scielo.br/mrPUBhttps://old.scielo.br/oai/scielo-oai.phpdedz@power.ufscar.br1980-53731516-1439opendoar:2018-05-11T00:00Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR)false |
dc.title.none.fl_str_mv |
Proton Exchange Membrane Based on Sulfonated Poly (Aromatic Imide-Co-Aliphatic Imide) for Direct Methanol Fuel Cell |
title |
Proton Exchange Membrane Based on Sulfonated Poly (Aromatic Imide-Co-Aliphatic Imide) for Direct Methanol Fuel Cell |
spellingShingle |
Proton Exchange Membrane Based on Sulfonated Poly (Aromatic Imide-Co-Aliphatic Imide) for Direct Methanol Fuel Cell Umsarika,Phornpussadee sulfonated poly(aromatic imide-co-aliphatic imide) proton conductivity direct methanol fuel cell methanol permeability |
title_short |
Proton Exchange Membrane Based on Sulfonated Poly (Aromatic Imide-Co-Aliphatic Imide) for Direct Methanol Fuel Cell |
title_full |
Proton Exchange Membrane Based on Sulfonated Poly (Aromatic Imide-Co-Aliphatic Imide) for Direct Methanol Fuel Cell |
title_fullStr |
Proton Exchange Membrane Based on Sulfonated Poly (Aromatic Imide-Co-Aliphatic Imide) for Direct Methanol Fuel Cell |
title_full_unstemmed |
Proton Exchange Membrane Based on Sulfonated Poly (Aromatic Imide-Co-Aliphatic Imide) for Direct Methanol Fuel Cell |
title_sort |
Proton Exchange Membrane Based on Sulfonated Poly (Aromatic Imide-Co-Aliphatic Imide) for Direct Methanol Fuel Cell |
author |
Umsarika,Phornpussadee |
author_facet |
Umsarika,Phornpussadee Changkhamchom,Sairung Paradee,Nophawan Sirivat,Anuvat Supaphol,Pitt Hormnirun,Pimpa |
author_role |
author |
author2 |
Changkhamchom,Sairung Paradee,Nophawan Sirivat,Anuvat Supaphol,Pitt Hormnirun,Pimpa |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Umsarika,Phornpussadee Changkhamchom,Sairung Paradee,Nophawan Sirivat,Anuvat Supaphol,Pitt Hormnirun,Pimpa |
dc.subject.por.fl_str_mv |
sulfonated poly(aromatic imide-co-aliphatic imide) proton conductivity direct methanol fuel cell methanol permeability |
topic |
sulfonated poly(aromatic imide-co-aliphatic imide) proton conductivity direct methanol fuel cell methanol permeability |
description |
A new sulfonated poly(aromatic imide-co-aliphatic imide) (SPI) for the use as a polymer electrolyte membrane was successfully synthesized from 4,4'-diaminodiphenylmethane (DDM), 4,4'-diaminodiphenylmethane-2,2'-disulfonic acid disodium salt (S-DDM), hexamethylenediamine, and 3,3',4,4'-benzophenonetetracarboxylic dianhydride in a one-step reaction. S-DDM was prepared by the direct sulfonation of DDM monomer. The degree of sulfonation of the sulfonated copolyimide was varied by using various molar concentrations of S-DDM. The sulfonated copolyimide with the highest degree of sulfonation possessed the proton conductivity of 0.0032 S.cm-1 in a wet state. The highest methanol permeability of the sulfonated copolyimide was 2.75 × 10-8 cm2.s-1 which is ~425 times lower than that of the Nafion 117. The highest membrane selectivity belonged to the membrane with 34% degree of sulfonation with the value of 1.65 × 106 s.S.cm-3 which is three orders of magnitude higher than the commercial Nafion 117. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392018000100133 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392018000100133 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/1980-5373-mr-2017-0823 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
dc.source.none.fl_str_mv |
Materials Research v.21 n.1 2018 reponame:Materials research (São Carlos. Online) instname:Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
instname_str |
Universidade Federal de São Carlos (UFSCAR) |
instacron_str |
ABM ABC ABPOL |
institution |
ABM ABC ABPOL |
reponame_str |
Materials research (São Carlos. Online) |
collection |
Materials research (São Carlos. Online) |
repository.name.fl_str_mv |
Materials research (São Carlos. Online) - Universidade Federal de São Carlos (UFSCAR) |
repository.mail.fl_str_mv |
dedz@power.ufscar.br |
_version_ |
1754212672152272896 |