Characterization of palladium nanoparticles anchored on graphene oxide obtained by electron beam
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo de conferência |
Título da fonte: | Repositório Institucional do IPEN |
Texto Completo: | http://repositorio.ipen.br/handle/123456789/28354 |
Resumo: | Fuel Cells (FCs) are devices that convert chemical energy directly in electrical and thermal energy. There are two disadvantages in the process that difficult the implementation of these new power supply. The fuel, hydrogen, is highly flammable and it is difficult to transport and the catalyst is costly. FCs have been attracting worldwide attention because they are environmental friendly and potential as clean and efficient power source. However, their durability and cost have being identified as important issues in this power supply. The objective of this work is to provide a new material based on incorporation of palladium graphene oxide as catalyst. Graphene Oxide (GO) was synthesized from graphite by the modified Hummers method, in water/alcohol medium. The one-step method to incorporate nanoparticles on this nanomaterial was developed using by electron beam (EB). Additionally, this method also reduces the Graphene Oxide (GO). This nanocomposite were characterized by thermogravimetry (TG), Fourier transform infrared (FT-IR), transmission electron microscopy (TEM), x-rays diffraction (XRD) and its potential for electro catalysis were performed by cyclic voltammetry (CV) and amperometry (CA). The results showed that the incorporation of Pd on reduced GO (rGO) by electron beam was 20-40 % in mass. The process using EB and Pd nanoparticles supported on graphene oxide as a support are an alternative, in substitution of conventional methods to the production of electrodes for fuel cells. |
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2018-01-17T17:20:09Z2018-01-17T17:20:09ZOctober 22-27, 2017http://repositorio.ipen.br/handle/123456789/28354Fuel Cells (FCs) are devices that convert chemical energy directly in electrical and thermal energy. There are two disadvantages in the process that difficult the implementation of these new power supply. The fuel, hydrogen, is highly flammable and it is difficult to transport and the catalyst is costly. FCs have been attracting worldwide attention because they are environmental friendly and potential as clean and efficient power source. However, their durability and cost have being identified as important issues in this power supply. The objective of this work is to provide a new material based on incorporation of palladium graphene oxide as catalyst. Graphene Oxide (GO) was synthesized from graphite by the modified Hummers method, in water/alcohol medium. The one-step method to incorporate nanoparticles on this nanomaterial was developed using by electron beam (EB). Additionally, this method also reduces the Graphene Oxide (GO). This nanocomposite were characterized by thermogravimetry (TG), Fourier transform infrared (FT-IR), transmission electron microscopy (TEM), x-rays diffraction (XRD) and its potential for electro catalysis were performed by cyclic voltammetry (CV) and amperometry (CA). The results showed that the incorporation of Pd on reduced GO (rGO) by electron beam was 20-40 % in mass. The process using EB and Pd nanoparticles supported on graphene oxide as a support are an alternative, in substitution of conventional methods to the production of electrodes for fuel cells.Submitted by Marco Antonio Oliveira da Silva (maosilva@ipen.br) on 2018-01-17T17:20:09Z No. of bitstreams: 1 24189.pdf: 719912 bytes, checksum: 32ee5fb8934ab2408bffacaf8fd4a4b8 (MD5)Made available in DSpace on 2018-01-17T17:20:09Z (GMT). No. of bitstreams: 1 24189.pdf: 719912 bytes, checksum: 32ee5fb8934ab2408bffacaf8fd4a4b8 (MD5)Associa????o Brasileira de Energia Nuclearcatalystselectrodeselectron beamsfourier transformationfuel cellsgrapheneinfrared spectrananoparticlespalladiumsynthesisthermal gravimetric analysistransmission electron microscopyCharacterization of palladium nanoparticles anchored on graphene oxide obtained by electron beaminfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/conferenceObjectINACIRio de Janeiro, RJBelo Horizonte, MGSOBRINHO, LUIZA F.GARCIA, RAFAEL H.L.SILVA, FLAVIA R.O.NETO, ALMIR O.SAKATA, SOLANGE K.INTERNATIONAL NUCLEAR ATLANTIC CONFERENCEinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional do IPENinstname:Instituto de Pesquisas Energéticas e Nucleares (IPEN)instacron:IPEN241892017SOBRINHO, LUIZA F.GARCIA, RAFAEL H.L.SILVA, FLAVIA R.O.NETO, ALMIR O.SAKATA, SOLANGE K.18-01Proceedings101563498591035417038SOBRINHO, LUIZA F.:10156:220:SGARCIA, RAFAEL H.L.:3498:730:NSILVA, FLAVIA R.O.:5910:711:NNETO, ALMIR O.:3541:610:NSAKATA, SOLANGE K.:7038:220:NORIGINAL24189.pdf24189.pdfapplication/pdf719912http://repositorio.ipen.br/bitstream/123456789/28354/1/24189.pdf32ee5fb8934ab2408bffacaf8fd4a4b8MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://repositorio.ipen.br/bitstream/123456789/28354/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52123456789/283542022-08-10 12:08:00.202oai:repositorio.ipen.br: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Repositório InstitucionalPUBhttp://repositorio.ipen.br/oai/requestbibl@ipen.bropendoar:45102022-08-10T12:08Repositório Institucional do IPEN - Instituto de Pesquisas Energéticas e Nucleares (IPEN)false |
dc.title.pt_BR.fl_str_mv |
Characterization of palladium nanoparticles anchored on graphene oxide obtained by electron beam |
title |
Characterization of palladium nanoparticles anchored on graphene oxide obtained by electron beam |
spellingShingle |
Characterization of palladium nanoparticles anchored on graphene oxide obtained by electron beam SOBRINHO, LUIZA F. catalysts electrodes electron beams fourier transformation fuel cells graphene infrared spectra nanoparticles palladium synthesis thermal gravimetric analysis transmission electron microscopy |
title_short |
Characterization of palladium nanoparticles anchored on graphene oxide obtained by electron beam |
title_full |
Characterization of palladium nanoparticles anchored on graphene oxide obtained by electron beam |
title_fullStr |
Characterization of palladium nanoparticles anchored on graphene oxide obtained by electron beam |
title_full_unstemmed |
Characterization of palladium nanoparticles anchored on graphene oxide obtained by electron beam |
title_sort |
Characterization of palladium nanoparticles anchored on graphene oxide obtained by electron beam |
author |
SOBRINHO, LUIZA F. |
author_facet |
SOBRINHO, LUIZA F. GARCIA, RAFAEL H.L. SILVA, FLAVIA R.O. NETO, ALMIR O. SAKATA, SOLANGE K. INTERNATIONAL NUCLEAR ATLANTIC CONFERENCE |
author_role |
author |
author2 |
GARCIA, RAFAEL H.L. SILVA, FLAVIA R.O. NETO, ALMIR O. SAKATA, SOLANGE K. INTERNATIONAL NUCLEAR ATLANTIC CONFERENCE |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
SOBRINHO, LUIZA F. GARCIA, RAFAEL H.L. SILVA, FLAVIA R.O. NETO, ALMIR O. SAKATA, SOLANGE K. INTERNATIONAL NUCLEAR ATLANTIC CONFERENCE |
dc.subject.por.fl_str_mv |
catalysts electrodes electron beams fourier transformation fuel cells graphene infrared spectra nanoparticles palladium synthesis thermal gravimetric analysis transmission electron microscopy |
topic |
catalysts electrodes electron beams fourier transformation fuel cells graphene infrared spectra nanoparticles palladium synthesis thermal gravimetric analysis transmission electron microscopy |
description |
Fuel Cells (FCs) are devices that convert chemical energy directly in electrical and thermal energy. There are two disadvantages in the process that difficult the implementation of these new power supply. The fuel, hydrogen, is highly flammable and it is difficult to transport and the catalyst is costly. FCs have been attracting worldwide attention because they are environmental friendly and potential as clean and efficient power source. However, their durability and cost have being identified as important issues in this power supply. The objective of this work is to provide a new material based on incorporation of palladium graphene oxide as catalyst. Graphene Oxide (GO) was synthesized from graphite by the modified Hummers method, in water/alcohol medium. The one-step method to incorporate nanoparticles on this nanomaterial was developed using by electron beam (EB). Additionally, this method also reduces the Graphene Oxide (GO). This nanocomposite were characterized by thermogravimetry (TG), Fourier transform infrared (FT-IR), transmission electron microscopy (TEM), x-rays diffraction (XRD) and its potential for electro catalysis were performed by cyclic voltammetry (CV) and amperometry (CA). The results showed that the incorporation of Pd on reduced GO (rGO) by electron beam was 20-40 % in mass. The process using EB and Pd nanoparticles supported on graphene oxide as a support are an alternative, in substitution of conventional methods to the production of electrodes for fuel cells. |
publishDate |
2018 |
dc.date.evento.pt_BR.fl_str_mv |
October 22-27, 2017 |
dc.date.accessioned.fl_str_mv |
2018-01-17T17:20:09Z |
dc.date.available.fl_str_mv |
2018-01-17T17:20:09Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/conferenceObject |
format |
conferenceObject |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://repositorio.ipen.br/handle/123456789/28354 |
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http://repositorio.ipen.br/handle/123456789/28354 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
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openAccess |
dc.coverage.pt_BR.fl_str_mv |
I |
dc.publisher.none.fl_str_mv |
Associa????o Brasileira de Energia Nuclear |
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Associa????o Brasileira de Energia Nuclear |
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